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141.
Timothy J. Fuhrer Matthew Houck Rachel M. Chapman Scott T. Iacono 《Molecules (Basel, Switzerland)》2021,26(24)
Perfluoroaromatics, such as perfluoropyridine and perfluorobenzene, are privileged synthetic scaffolds in organofluorine methodology, undergoing a series of regioselective substitution reactions with a variety of nucleophiles. This unique chemical behavior allows for the synthesis of many perfluoroaromatic derived molecules with unique and diverse architectures. Recently, it has been demonstrated that perfluoropyridine and perfluorobenzene can be utilized as precursors for a variety of materials, ranging from high performance polyaryl ethers to promising drug scaffolds. In this work, using density functional theory, we investigate the possibility of perfluoropyrimidine, perfluoropyridazine, and perfluoropyrazine participating in similar substitution reactions. We have found that the first nucleophilic addition of a phenoxide group substitution on perfluoropyrimidine and on perfluoropyridazine would happen at a site para to one of the nitrogen atoms. While previous literature points to mesomeric effects as the primary cause of this phenomenon, our work demonstrates that this effect is enhanced by the fact that the transition states for these reactions result in bond angles that allow the phenoxide to π-complex with the electron-deficient diazine ring. The second substitution on perfluoropyrimidine and on perfluoropyridazine is most likely to happen at the site para to the other nitrogen. The second substitution on perfluoropyrazine is most likely to happen at the site para to the first substitution. The activation energies for these reactions are in line with those reported for perfluoropyridine and suggest that these platforms may also be worth investigation in the lab as possible monomers for high performance polymers. 相似文献
142.
Daniel O'Nolan Haiyan Zhao Zhihengyu Chen Antonin Grenier Michelle L. Beauvais Mark A. Newton Tina M. Nenoff Peter J. Chupas Karena W. Chapman 《Chemical science》2021,12(41):13836
Unraveling the complex, competing pathways that can govern reactions in multicomponent systems is an experimental and technical challenge. We outline and apply a novel analytical toolkit that fully leverages the synchronicity of multimodal experiments to deconvolute causal from correlative relationships and resolve structural and chemical changes in complex materials. Here, simultaneous multimodal measurements combined diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and angular dispersive X-ray scattering suitable for pair distribution function (PDF), X-ray diffraction (XRD) and small angle X-ray scattering (SAXS) analyses. The multimodal experimental data was interpreted via multi-level analysis; conventional analyses of each data series were integrated through meta-analysis involving non-negative matrix factorization (NMF) as a dimensional reduction algorithm and correlation analysis. We apply this toolkit to build a cohesive mechanistic picture of the pathways governing silver nanoparticle formation in zeolite A (LTA), which is key to designing catalytic and separations-based applications. For this Ag-LTA system, the mechanisms of zeolite dehydration, framework flexing, ion reduction, and cluster and nanoparticle formation and transport through the zeolite are elucidated. We note that the advanced analytical approach outline here can be applied generally to multimodal experiments, to take full advantage of the efficiencies and self-consistencies in understanding complex materials and go beyond what can be achieved by conventional approaches to data analysis.Multimodal in situ experimental data probing a complex reaction have been integrated via a multi-level analysis involving non-negative matrix factorization and correlation analysis. This strategy can be applied generally to multimodal experiments. 相似文献
143.
Janine M. Orban Toby M. Chapman William R. Wagner Ron Jankowski 《Journal of polymer science. Part A, Polymer chemistry》1999,37(17):3441-3448
A novel synthesis of poly(ethylene glycol) (PEG)-grafted poly(urethanes) (PURs) is described based on a precursor PUR containing free amino groups in the main chain. Three different poly(urethane) backbones were prepared: a homopoly(urethane) comprised of N-Bocdiethanolamine (BDA) and 4,4′-methylenebis(phenyl isocyanate) (MDI), a copoly(urethane) (COPUR) consisting of BDA, N-benzyldiethanolamine and MDI, and a poly(urethane urea) (PUU) that was prepared from BDA, MDI, and ethylenediamine as the chain extender. The Mn of these poly(urethanes) ranged from 32,000 to 72,000 g/mol. PEG (750, 1,900, and 5,000 g/mol) was grafted onto the boc-deprotected poly(urethanes) via the chloroformate. Films of the polymers were spin cast from dilute solutions, annealed, and the surfaces analyzed by goniometry. Water contact angle data indicates increasing PEG surface coverage of the poly(urethanes) with increasing PEG molecular weight. Reorientation of the polymer films is evidenced by contact angle hysteresis. Polymer thrombogenicity, which was studied using blood perfusion experiments, shows that COPUR-g-PEG5000 and PUU-g-PEG5000 exhibit very little platelet adhesion. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 3441–3448, 1999 相似文献
144.
This paper describes a detailed experimental study of the thermoluminescence (TL) properties of four binary lead-silicate glasses, with PbO concentrations ranging from 32% to 62% in mole percent. The TL glow peaks between room temperature and 300 °C were analyzed using a systematic thermal cleaning technique. The Tmax-Tstop and E-Tstop methods of analysis were used to identify the number of peaks under the glow curves, and to obtain the activation energy E for each TL trap. A computerized glow curve fitting analysis is used to fit the experimental data to four first-order peaks with maxima at temperatures of 54, 80, 110 and 210 °C, as measured with a heating rate of 2 °C/s. The kinetic parameters of the glow-peak at 210 °C were confirmed by using phosphorescence decay methods of analysis. The TL traps associated with the low-temperature TL peak at 54 °C are found to depend strongly on the PbO concentration of the samples, while the higher-temperature TL peaks show a behavior independent of the PbO concentration. The activation energy E and frequency factor s of the low-temperature TL trap associated with the peak at 54 °C are consistent with a trap involving a delocalized transition through the conduction band. However, the activation energies and frequency factors for the higher-temperature TL traps are consistent with traps involving localized transitions via an excited state below the conduction band. The data suggest that these higher-temperature TL traps are associated with the common silicate matrix in these binary silicate glasses. 相似文献
145.
Martin B. Duriska Dr. Suzanne M. Neville Dr. Boujemaa Moubaraki Dr. John D. Cashion Assoc. Prof Gregory J. Halder Dr. Karena W. Chapman Dr. Chérif Balde Jean‐François Létard Dr. Keith S. Murray Prof. Cameron J. Kepert Prof. Stuart R. Batten Assoc. Prof. 《Angewandte Chemie (International ed. in English)》2009,48(14):2549-2552
Bottoms up! A discrete metallo‐supramolecular nanoball (see picture), synthesized by using “bottom‐up” methodologies, uniquely undergoes a solvent‐sensitive, physically addressable electronic spin switching. The switching occurs by thermal, light, or solvent perturbation, where importantly it can be switched “on” or “off” by green or red laser irradiation, respectively.
146.
Martin B. Duriska Dr. Suzanne M. Neville Dr. Boujemaa Moubaraki Dr. John D. Cashion Assoc. Prof Gregory J. Halder Dr. Karena W. Chapman Dr. Chérif Balde Jean‐François Létard Dr. Keith S. Murray Prof. Cameron J. Kepert Prof. Stuart R. Batten Assoc. Prof. 《Angewandte Chemie (International ed. in English)》2009,48(14):2428-2428
Continuous switching between high‐spin and low‐spin magnetic states can be accomplished by irradiation with red and green laser light, respectively. In their Communication on page 2549 ff., S. R. Batten and co‐workers report a metallo‐supramolecule that undergoes spin crossover (SCO) switching induced by temperature change or light irradiation. The SCO behavior is also dependent on the presence and nature of intercalated solvent molecules within the porous crystal structure.
147.
Robin J. Chapman Amit Khetan Robert J. Waters 《Journal of Combinatorial Theory, Series A》2009,116(1):205-214
There is a strikingly simple classical formula for the number of lattice paths avoiding the line x=ky when k is a positive integer. We show that the natural generalization of this simple formula continues to hold when the line x=ky is replaced by certain periodic staircase boundaries—but only under special conditions. The simple formula fails in general, and it remains an open question to what extent our results can be further generalized. 相似文献
148.
149.
High‐power‐load DCLM monochromator for a computed tomography program at BMIT at energies of 25–150 keV 下载免费PDF全文
Tomasz W. Wysokinski Michel Renier Pekka Suortti George Belev Léo Rousset Madison Adam Denise Miller Norman Huber L. Dean Chapman 《Journal of synchrotron radiation》2018,25(5):1548-1555
The research program at the biomedical imaging facility requires a high‐flux hard‐X‐ray monochromator that can also provide a wide beam. A wide energy range is needed for standard radiography, phase‐contrast imaging, K‐edge subtraction imaging and monochromatic beam therapy modalities. The double‐crystal Laue monochromator, developed for the BioMedical Imaging and Therapy facility, is optimized for the imaging of medium‐ and large‐scale samples at high energies with the resolution reaching 4 µm. A pair of 2 mm‐thick Si(111) bent Laue‐type crystals were used in fixed‐exit beam mode with a 16 mm vertical beam offset and the first crystal water‐cooled. The monochromator operates at energies from 25 to 150 keV, and the measured size of the beam is 189 mm (H) × 8.6 mm (V) at 55 m from the source. This paper presents our approach in developing a complete focusing model of the monochromator. The model uses mechanical properties of crystals and benders to obtain a finite‐element analysis of the complete assembly. The modeling results are compared and calibrated with experimental measurements. Using the developed analysis, a rough estimate of the bending radius and virtual focus (image) position of the first crystal can be made, which is also the real source for the second crystal. On the other hand, by measuring the beam height in several points in the SOE‐1 hutch, the virtual focus of the second crystal can be estimated. The focusing model was then calibrated with measured mechanical properties, the values for the force and torque applied to the crystals were corrected, and the actual operating parameters of the monochromator for fine‐tuning were provided. 相似文献
150.
A hierarchy of high-order theories for symmetric modes in an infinitely long elastic layer of the constant thickness is derived by means of the inertia-corrected polynomial approximations. For each member of the hierarchy, boundary conditions for layers of the finite length are formulated. The forcing problems at several approximation levels are solved with the use of the bi-orthogonality conditions. Accuracy of these approximations is assessed by comparison of results with the exact solution of the Rayleigh–Lamb problem. Special attention is paid to the power flow analysis in alternative modal excitation cases and to the applicability of the Saint-Venant?s principle in stationary elasto-dynamics. 相似文献