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151.
单重态氧O2 (a1Δg)是迄今唯一能用纯化学反应高效产生的具有长寿命的亚稳激发态分子 .为了考察提出的用两个O2 (1Δ)能量汇集反应生成氧第二单重激发态O2 (b1Σ+ g)以实现近可见短波长化学激光方案的现实性 ,设计和实验了一个氯流量为 3~ 10mmol/s的射流式单重态氧发生器 (JSOG) .考察了三种具有不同孔径和孔数目的喷头、氯气流量和脱水冷阱温度等对JSOG出口的O2 (1Δ)浓度、O2 (1Δ)分压、氯利用率及水蒸气含量的影响 .发现用聚氯乙烯管作冷阱时 ,最佳冷阱介质温度为 - 140~ - 15 0℃ ,对此提出了O2 (1Δ)表面脱活与脱水互相竞争的解释 .在最佳条件下 ,可将O2 (1Δ)气中水分压降低至 4Pa ,这一结果是首次报导 相似文献
152.
153.
Study on the in—plane electrical resistivity and thermoelectric power in single crystals of La2—xBaxCuO4 下载免费PDF全文
The in-plane electrical resistivity and thermoelectric power have been measured on single crystals of La2-xBaxCuO4 at around x=0.125. The room temperature resistivity and thermopower have their maximum values at x=0.125, indicating that the carrier concentration is the minimum and the carriers are most strongly localized at x=0.125. The observed semiconductor-like behaviour can be well described by the weak-localized quasi-two-dimensional state. The steep rise in electric resistivity of the sample at x=0.125 below 70K is attributed to the formation of static stripe-order of holes and spins, which are pinned by the low-temperature tetragonal (LTT) structure, as discovered in La1.48Nd0.4Sr0.12CuO4. The temperature dependence of electric resistivity below 70K is still well described by the formula ρ∝ lnT. A definite change in the slope of thermopower is observed at the low-temperature orthorhombic-LTT structural phase transition temperature. The origin of the 1/8 anomaly is discussed in the text. 相似文献
154.
许多乙酰芳胺类化合物具有优异的生物活性,例如除草剂苯噻草胺,可抑制细胞生长和分裂,防除稻田中禾本科杂草[1];杀菌剂甲霜灵可防治作物霜霉病[2]。本文将具有多种生物活性的嘧啶基团引入到乙酰芳胺结构中[3],合成下列10个未见文献报道的标题化合物Ⅰ,通... 相似文献
155.
本文以fp 同伦方法为工具,借助于一些适当的变换,研究有序的(B)空间中的集值映象方程的多正解问题;在文中的有关工作中,还使用了集值映象的拟导数的某些性质. 相似文献
157.
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159.
In theory, both polarity and steric hindrance are basic factors which affect molecular interactions. To investigate the optical properties and steric structures of chiral compounds having different chiral moieties which affect the wavelength of light reflection in liquid crystal (LC) cells, a series of novel chiral compounds and azobenzene derivatives were synthesized. The liquid crystalline phases of the compounds were identified using small angle X-ray diffraction, differential scanning calorimetry and polarizing optical microscopy. Cholesteric LC cells with various synthesized chiral dopants which selectively reflect visible light were first prepared, the photochemical switching behaviour of colours was then investigated, with special reference to the change in transmittance in cholesteric LC cells containing an azobenzene derivative as a photoisomerizable guest molecule. Reversible isomerization of azobenzene molecules occurred in the cholesteric systems, resulting in a depression of TChI and a shift of the selectively reflected wavelength. We discuss the photochemically driven change in the helical pitch of the cholesteric LCs with respect to structural effects involving the chiral moieties. Molecular interactions caused by the added dopants, reliability and stability of the photoisomerization, and UV irradiation effects on the cholesteric LC cells were also investigated. A real image was recorded through a mask on a cholesteric LC cell fabricated in this investigation. 相似文献
160.
Observation of spontaneous pattern with six-fold symmetry in disk-shaped ZnO complex microstructures
L.W. Yang Y.J. Gao X.L. Wu Y.M. Yang G.S. Huang Z.Y. Zhang P.K. Chu 《Applied Physics A: Materials Science & Processing》2007,89(1):173-176
Using a simple vapor phase transport technique, we have fabricated unique complex disk-shaped ZnO microstructures comprising
a small disk coaxially grown on a large one and observed spatially perfect six-fold symmetric patterns. The observed results
can be explained based on the spontaneous nanoindentation (NI) effect under the geometric constraints and the explanation
can be extended to fathom the growth mechanism of other highly symmetrical ZnO nanostructures. Our results indicate that NI
not only can elucidate the mechanical properties of surfaces and thin films but also is an effective approach to fabricate
ordered nanostructures with high precision on the location of the building blocks.
PACS 81.16.Rf; 81.07.-b; 81.05.Dz 相似文献