首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   93572篇
  免费   17560篇
  国内免费   9949篇
化学   64599篇
晶体学   1074篇
力学   6045篇
综合类   624篇
数学   10702篇
物理学   38037篇
  2024年   241篇
  2023年   2098篇
  2022年   2535篇
  2021年   3318篇
  2020年   4180篇
  2019年   3750篇
  2018年   3341篇
  2017年   3005篇
  2016年   4792篇
  2015年   4531篇
  2014年   5520篇
  2013年   7109篇
  2012年   8631篇
  2011年   8989篇
  2010年   5981篇
  2009年   5746篇
  2008年   6140篇
  2007年   5402篇
  2006年   5019篇
  2005年   4077篇
  2004年   3142篇
  2003年   2460篇
  2002年   2290篇
  2001年   1959篇
  2000年   1688篇
  1999年   1908篇
  1998年   1646篇
  1997年   1616篇
  1996年   1598篇
  1995年   1339篇
  1994年   1175篇
  1993年   1018篇
  1992年   883篇
  1991年   798篇
  1990年   666篇
  1989年   517篇
  1988年   387篇
  1987年   319篇
  1986年   335篇
  1985年   276篇
  1984年   162篇
  1983年   136篇
  1982年   112篇
  1981年   73篇
  1980年   54篇
  1979年   25篇
  1978年   11篇
  1977年   8篇
  1974年   10篇
  1957年   32篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
41.
42.

A Savitzky–Golay filtering for smoothing and peak search written in Python is presented in this paper alongside its applications in the list-mode digital data acquisition dual gamma–gamma coincidence bismuth germanate (BGO) detector. The study has demonstrated that the software provides a reliable and effective way to quantify trace amounts of 22Na and 7Be in aerosol samples collected at Resolute Bay, Canada with a critical limit of 3 mBq and 5 Bq respectively for a 20 h counting interval, which are believed to be the inherent limitations of the dual-BGO system.

  相似文献   
43.
44.
Journal of Sol-Gel Science and Technology - A novel gas sensing material, La–Y co-doped TiO2 nanoparticles, was synthesized by sol–gel method and applied to detect organic pollutants...  相似文献   
45.
46.
Xu  Jiuping  Tang  Weiyao  Zhang  Yi  Wang  Fengjuan 《Nonlinear dynamics》2020,99(2):1269-1293
Nonlinear Dynamics - With an increasing number of people sharing feelings and opinions online, the online platforms have become one of the most important channels for public opinion dissemination....  相似文献   
47.
Novel pyrene‐fused unsymmetrical phthalocyanine derivatives 2,3,9,10,16,17‐hexakis(2,6‐dimethylphenoxy)‐22,25‐diaza(2,7‐di‐tert‐butylpyrene)[4,5]phthalocyaninato zinc complex Zn[Pc(Pz‐pyrene)(OC8H9)6] ( 1 ) and 2,3,9,10‐tra(2,6‐dimethylphenoxy)‐15,18,22,25‐traza(2,7‐di‐tert‐butylpyrene)[4,5]phthalocyaninato zinc compound Zn[Pc(Pz‐pyrene)2(OC8H9)4] ( 2 ) were isolated for the first time. These unsymmetrical pyrene‐fused phthalocyanine derivatives have been characterized by a wide range of spectroscopic and electrochemical methods. In particular, the pyrene‐fused phthalocyanine structure was unambiguously revealed on the basis of single crystal X‐ray diffraction analysis of 1 , representing the first structurally characterized phthalocyanine derivative fused with an aromatic moiety larger than benzene.  相似文献   
48.
王海军 《高分子科学》2015,33(6):823-829
The effects of PEA on the γ-phase PVDF crystal structure and the crystallization of PEA within the pre-existing γ-phase PVDF spherulites have been investigated by optical microscopy(OM), infrared spectroscopy(IR) and scanning electron microscopy(SEM). The results demonstrate that the γ-phase PVDF spherulites consist of the lamellae exhibiting a highly curved scroll-like morphology and develop preferentially in PEA-rich blend. With increasing PEA concentration, the scroll diameter increases and the scrolls are better separated from each other. PEA crystallizes first in the interspherulitic region and transcrystalline layer develops. Subsequently, the transcrystalline layer of PEA continues to grow within the γ-phase PVDF spherulites, e.g., in the region between the scrolls, until impinging on other PEA transcrystalline layers or spherulites. The crystallization kinetics results indicate that the growth rate of PEA crystals in the intraspherulitic region of γ-phase PVDF shows a positive correlation with content of PEA, but a negative one with the crystallization temperature of γ-phase PVDF.  相似文献   
49.
Albomycin δ2 is a sulfur-containing sideromycin natural product that shows potent antibacterial activity against clinically important pathogens. The l -serine-thioheptose dipeptide partial structure, known as SB-217452, has been found to be the active seryl-tRNA synthetase inhibitor component of albomycin δ2. Herein, it is demonstrated that AbmF catalyzes condensation between the 6′-amino-4′-thionucleoside with the d -ribo configuration and seryl-adenylate supplied by the serine adenylation activity of AbmK. Formation of the dipeptide is followed by C3′-epimerization to produce SB-217452 with the d -xylo configuration, which is catalyzed by the radical S-adenosyl-l -methionine enzyme AbmJ. Gene deletion suggests that AbmC is involved in peptide assembly linking SB-217452 with the siderophore moiety. This study establishes how the albomycin biosynthetic machinery generates its antimicrobial component SB-217452.  相似文献   
50.
Hierarchically porous metal–organic frameworks (HP-MOFs) are promising in various applications. Most reported HP-MOFs are prepared based on the generation of mesopores in microporous frameworks, and the formed mesopores are connected by microporous channels, limiting the accessibility of mesopores for bulky molecules. A hierarchical structure is formed by constructing microporous MOFs in uninterrupted mesoporous tunnels. Using the confined space in as-prepared mesoporous silica, highly dispersed metal precursors for MOFs are coated on the internal surface of mesoporous tunnels. Ligand vapor-induced crystallization is employed to enable quantitative formation of MOFs in situ, in which sublimated ligands diffuse into mesoporous tunnels and react with metal precursors. The obtained hierarchically porous composites exhibit record-high adsorption capacity for the bulky molecule trypsin. The thermal and storage stability of trypsin is improved upon immobilization on the composites.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号