The Effect of Surface Roughness on Immiscible Displacement Using Pore Scale Simulation

Transport in Porous Media - Pore scale immiscible displacement is crucial in oil industry. The surface roughness of throat is an important factor affecting water–oil interface movement. In...     

Invariant torus and its destruction for an oscillator with dry friction

Nonlinear Dynamics - Mechanical systems with dry friction are typical Filippov systems. Such class of systems have complicated dynamical behaviors due to the existence of sliding motion. In this...     

基于空间视角下产业协同集聚对区域创新的影响

选取2009-2018年中国30个省(市、自治区)的数据,运用区位商相对差异指数和熵权TOPSIS法分别测算其产业协同集聚度和区域创新水平,研究二三产业协同集聚对区域创新的影响.研究表明:产业集聚通过"知识技术、劳动力、物力"等外部规模经济增加创新产出;2009-2018年,两产业协同集聚水平由中西部向东部递减,区域创新水平东部明显高于中西部,空间溢出效应显著;两产业协同集聚对创新的影响呈现"倒U型"特征;最后基于计量结果提出相关建议.     

基于收益共享机制的干支线衔接运输联合定价模型

在班轮运输网络中,支线运输与干线运输具有互补性,干线承运人与支线承运人之间的合作能够为托运人提供更高的便利度和更完善的运输服务。本文在考虑可替代运输路径之间竞争关系的基础上,研究干支线衔接路径的定价问题,在运输链纵向一体化和分散化两种结构下,构建Bertrand博弈模型研究上下游承运人的均衡运价。同时,设计合理的收益共享机制,使承运人在分散结构的运输系统中仍能实现运输链的协调。     

Homogeneous Einstein-like metrics on symmetric spaces

In this paper, we study homogeneous Einstein-like metrics on the compact irreducible symmetric space M, which is not isometric to a compact Lie group and has rank greater than 1. Whenever there exists a closed proper subgroup G′ of G = Isom_0(M) acting transitively on M, we find all the G′-invariant A-metrics and B-metrics on M. More precisely, we prove that G′-invariant metrics on M must be A-metrics, and G′-invariant B-metrics on M are always Einstein.     

卷烟主流烟气中巴豆醛在线光谱分析方法研究

卷烟主流烟气是卷烟燃烧时被人体吸食到体内的主要气体,其减焦降害已成为全社会高度关注的问题。在各种卷烟主流烟气组分中,巴豆醛以其强烈的基因毒性,成为国家规定的卷烟中七种主要有害指标物之一。传统的巴豆醛分析方法大都采用高效液相色谱法等实验室分析方法,需繁琐的样品前处理过程,无法测量巴豆醛的实时浓度,难以准确评估巴豆醛对人体健康的影响。为了快速、准确地检测卷烟主流烟气中的巴豆醛组分,本研究搭建了一套可以直接与吸烟机耦合的傅里叶红外光谱分析系统（FTIR）,并创新性开发过采样数据驱动光谱分析方法（ODDSA）,从复杂、变动的卷烟主流烟气中准确提取巴豆醛的光谱组分信息。ODDSA方法从实验设计入手,采用随机设计的思路尽可能模拟实际卷烟样品的分布范围,以构建具备良好光谱数据结构的样品集。在此基础上,创新性地将高密度小波变换引入红外光谱数据的处理过程中,以时/频双域过采样的方式提升了光谱解析分辨率,进而降低了其他基质组分对巴豆醛光谱信息的干扰。最后,发展改良竞争自适应重加权采样方法,从多倍冗余的高密度小波系数中准确提取待测物质的最佳变量组合,由此构建高质量的巴豆醛光谱定量分析模型。为了验证ODDSA方法的有效性,实验中采集了15种典型市售卷烟品牌,每个品牌在线采集8支样品的主流烟气红外光谱,随后采用随机挑选的25个验证集样本对ODDSA方法进行验证。结果表明,检验集的线性拟合系数为0.971,相对均方根误差为5.5%,其预测精度能有效满足卷烟主流烟气中巴豆醛的在线分析需求,并可拓展到环境二手烟气中其他组分的在线监测,进而为吸烟与健康评估提供全新手段。     

基于2,6-吡啶酰胺及三嗪结构单元的[1+1]及[2+2]型Schiff碱大环的合成及表征

前体二醛2-二乙胺基-4,6-二(2-甲氧基-4-醛基苯氧基)-1,3,5-三嗪(A)分别与前体二胺N,N'-(2-氨基苯基)-2,6-二甲酰亚胺吡啶(B1),及N,N'-(3-氨基苯基)-2,6-二甲酰亚胺吡啶(B2)发生脱水缩合反应合成了Schiff碱大环M1和M2。采用1H NMR、 FT-IR、 MS、 UV-...     

A method for calibrating the position error of phase retrieval with transverse translation diversity in optical wavefront measurement

We present a method for calibrating the position error of phase retrieval with transverse translation diversity in optical wavefront in situation where the position error sharply influences algorithm precision. This method involves testifying that the essence of the position error in phase retrieval is the translation in frequency domain and the minimum of iterative error against position error reaches when there is no position error. Then the least square method is used for fitting the relationship between the iterative error and the assumed position error in polynomial function. The computer simulations used to prove the validity of this method are described. The results indicated that this method can calibrate the position error to approximately 1/500 mm which nearly has no influence on the phase retrieval.     

Interaction of Moxifloxacin with Bovine Hemoglobin and Effect of the Coexistent Drugs on the Reaction

The interaction between moxifloxacin (MXFX) and Bovine Hemoglobin (BHb) was investigated at different temperatures by fluorescence spectroscopy. Results showed that the quenching mechanism of MXFX on BHb was a static quenching process with Förester spectroscopy energy transfer. The primary binding for MXFX was located at β-37 Tryptophan residue in hydrophobic cavity of BHb. Besides, weak negative cooperativity was found in drug's binding with BHb. Synchronous spectra revealed that the microenvironment and the conformation of serum albumin were changed during the reaction. Most antibiotics had no effect on the system of BHb-MXFX, except quinolone antibiotics. The system had good stability.     

Wavelength modulation diode laser absorption spectroscopy for high-pressure gas sensing

A general model for 1f-normalized wavelength modulation absorption spectroscopy with nf detection (i.e., WMS-nf) is presented that considers the performance of injection-current-tuned diode lasers and the reflective interference produced by other optical components on the line-of-sight (LOS) transmission intensity. This model explores the optimization of sensitive detection of optical absorption by species with structured spectra at elevated pressures. Predictions have been validated by comparison with measurements of the 1f-normalized WMS-nf (for n = 2–6) lineshape of the R(11) transition in the 1st overtone band of CO near 2.3 μm at four different pressures ranging from 5 to 20 atm, all at room temperature. The CO mole fractions measured by 1f-normalized WMS-2f, 3f, and 4f techniques agree with calibrated mixtures within 2.0 %. At conditions where absorption features are significantly broadened and large modulation depths are required, uncertainties in the WMS background signals due to reflective interference in the optical path can produce significant error in gas mole fraction measurements by 1f-normalized WMS-2f. However, such potential errors can be greatly reduced by using the higher harmonics, i.e., 1f-normalized WMS-nf with n > 2. In addition, less interference from pressure-broadened neighboring transitions has been observed for WMS with higher harmonics than for WMS-2f.