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121.
W. L. Liang B. K. A. Ngoi L. E. N. Lim K. Venkatakrishnan C. W. Hee 《Optics & Laser Technology》2003,35(4):285-290
In this paper, integration of interference phenomenon into femtosecond laser micromachining was reported as the femtosecond laser pulses were reshaped spatially to perform ablation. The generation of circular interference pattern was demonstrated by overlapping infrared femtosecond laser pulses. The interference pattern was subsequently focused on a copper substrate to ablate microstructures of concentric circular rings. The present technique is expected to open up new applications in the areas of rapid fabrication of micro-Fresnel lenses, hybrid microlenses and lens arrays. 相似文献
122.
Jae Ik Kim Dae-Ryong Jung Jongmin Kim Changwoo Nahm Sujin Byun Sungjun Lee Byungwoo Park 《Solid State Communications》2012,152(18):1767-1770
The enhancement of surface–plasmon-coupled photoluminescence from CdS nanoparticles was examined for various thicknesses of sputtered Au films. The improved luminescence with thickness control of Au correlated well with the increased density of surface–plasmon states, which was modified by the plasmon-dispersion relation at the planar Au/PMMA interface. By annealing the Au films to form a rough surface morphology, the emission in the CdS nanoparticles was further enhanced by the improved excitation and coupling of the surface–plasmon modes. 相似文献
123.
Chang Sung Lim 《Journal of luminescence》2012,132(7):1774-1780
MMoO4 (M=Ca, Ba) particles were synthesized by a metathetic reaction in ethylene glycol assisted by cyclic microwave irradiation followed by further heat-treatment. The MMoO4 (M=Ca, Ba) particles were well crystallized after heat-treatment at 400–600 °C for 3 h. The microstructures exhibited fine morphologies with sizes of 0.5–1 μm and 1.5–2 μm for the CaMoO4 and BaMoO4 particles, respectively. The synthesized MMoO4 (M=Ca, Ba) particles were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy and transmission electron microscopy. The optical properties were examined by photoluminescence emission and Raman spectroscopy. 相似文献
124.
Sung Hwan Koo Dong Jun Li Taeyeong Yun Dong Sung Choi Kyung Eun Lee Gil Yong Lee Youngtak Oh Joonwon Lim Suchithra Padmajan Sasikala Ho Jin Lee In Ho Kim Hong Ju Jung Rishabh Jain Sang Ouk Kim 《Particle & Particle Systems Characterization》2019,36(7)
Efficient water electrolysis catalyst is highly demanded for the production of hydrogen as a sustainable energy fuel. It is reported that cobalt derived nanoparticle (CoS2, CoP, CoS|P) decorated reduced graphene oxide (rGO) composite aerogel catalysts for highly active and reliable hydrogen evolution reaction electrocatalysts. 7 nm level cobalt derived nanoparticles are synthesized over graphene aerogel surfaces with excellent surface coverage and maximal expose of active sites. CoS|P/rGO hybrid aerogel composites show an excellent catalytic activity with overpotential of ≈169 mV at a current density of ≈10 mA cm?2. Accordingly, efficient charge transfer is attained with Tafel slope of ≈52 mV dec?1 and a charge transfer resistance (Rct) of ≈12 Ω. This work suggests a viable route toward ultrasmall, uniform nanoparticles decorated graphene surfaces with well‐controlled chemical compositions, which can be generally useful for various applications commonly requiring large exposure of active surface area as well as robust interparticle charger transfer. 相似文献
125.
S.-S. Bae D.K. Lim J.-I. Park J. Cheon I.C. Jeon S. Kim 《Applied Physics A: Materials Science & Processing》2005,80(6):1305-1310
We present a new strategy to fabricate a monolayer assembly of Br-terminated Co nanoparticles on functionalized Si surfaces by using chemical covalent bonding and microcontact printing method. Self-assembled monolayers (SAMs) of the Co nanoparticles formed on the hydroxyl-terminated Si surface exhibit two-dimensional island networks with locally ordered arrays via covalent linkage between nanoparticles and surface. On the other hand, SAMs of the nanoparticles on the aminopropyl-terminated Si surface show an individual and random distribution over an entire surface. Furthermore, we have fabricated striped architectures of Co nanoparticles using a combination of microcontact printing and covalent linkage. Microcontact printing of octadecyltrichlorosilane and selective covalent linkage between nanoparticles and functionalized Si surfaces lead to a hybrid nanostructure with selectively assembled nanoparticles stripes on the patterned functionalized Si surfaces. PACS 81.07.Ta; 61.46.+w; 81.16.Dn; 81.16.Be; 68.37.Hk; 82.80.Pv 相似文献
126.
Assume that we have iid observations on the random vector X = (X
,...,X
) following a multivariate normal distribution N
(,) where both R
and (p.d.) are unknown. Let
denote the multiple correlation coefficient between X
and (X
,...,X
). The parameter =
, called the multiple coefficient of determination, indicates the proportion of variability in X
explained by its best linear fit based on (X
,..., X
). In this paper we consider the point estimation of under the ordinary squared error loss function. The usual estimators (MLE, UMVUE) have complicated risk expressions and hence it is quite difficult to get exact decision-theoretic results. We therefore follow the asymptotic decision theoretic approach (as done by Ghosh and Sinha (1981, Ann. Statist., 9, 1334-1338)) and study Second Order Admissibility of various estimators including the usual ones. 相似文献
127.
Fourier transform infrared spectroscopy studies have been conducted to investigate the interaction among components in a system
of high molecular weight polyvinylchloride (PVC)–lithium trifluoromethanesulfonate (LiCF3SO3) incorporated with different type of plasticizers, namely, ethylene carbonate (EC), propylene carbonate (PC), and dibutylphthalate
(DBP). Interaction between PVC and LiCF3SO3 was confirmed by C–H rocking mode at 1,255 cm−1 for PVC shift to 1,252 cm−1 in PVC–LiCF3SO3. The plasticizers’ carbonyl (C=O) oxygen atom which carries lone pair electrons interact with Li+ of LiCF3SO3 and methine hydrogen of PVC in LiCF3SO3–plasticizer system and PVC–plasticizer system, respectively. Changes in peaks assigned to 1,264 cm−1 (ν
as(SO3)), 1,033 cm−1 (ν
s(SO3)), 1,181 cm−1 (ν
as(CF3)), 1,230 cm−1 (ν
s(CF3)), 765 cm−1 (δ
s(CF3)), 644 cm−1 (δ
s(SO3)), 578 cm−1 (δ
as(CF3)), and 519 cm−1 (δ
as(SO3)) indicate the occurrence of complexation in the PVC–LiCF3SO3 system, LiCF3SO3–plasticizer system, and PVC–LiCF3SO3–plasticizer system. 相似文献
128.
Z. C. Chen M. H. Hong H. Dong Y. D. Gong C. S. Lim L. P. Shi T. C. Chong 《Applied Physics A: Materials Science & Processing》2010,101(1):33-36
Large-area split ring resonator (SRR) array was fabricated by femtosecond laser micro-lens array lithography at a fast speed.
Transmission spectra of the SRR arrays at different incident terahertz wave polarization states were characterized by terahertz
time domain spectroscopy. A polarization-dependent transmission property of the SRR array was observed. Polarization-dependent
loss (PDL) spectrum was characterized to investigate the polarization properties of the terahertz metamaterials. The PDL characterization
can eliminate the substrate effect and provide a flexible platform to study the characteristics of free-standing terahertz
metamaterials. 相似文献
129.
Eichler and Zagier developed a theory of Jacobi forms to understand and extend Maass' work on the Saito‐Kurokawa conjecture. Later Skoruppa introduced skew‐holomorphic Jacobi forms, which play an important role in understanding liftings of modular forms and Jacobi forms. In this paper, we explain a relation between Jacobi forms and skew‐holomorphic Jacobi forms in terms of a group cohomology. More precisely, we introduce an isomorphism from the direct sum of the space of Jacobi cusp forms on and the space of skew‐holomorphic Jacobi cusp forms on with the same half‐integral weight to the Eichler cohomology group of with a coefficient module coming from polynomials. 相似文献
130.
Yu Na Lim Soo Kyung Chae Woongbin Yim Ji‐Yong Park Woojin Yoon Hoseop Yun Eunha Kim Seung Uk Son Hye‐Young Jang 《应用有机金属化学》2019,33(3)
The reaction of [(domppp) Pd (OAc)2] [domppp = 1,3‐bis (di‐o‐methoxyphenylphosphino)propane] and imidazolium‐functionalized carboxylic acids containing various anions (Br?, PF6?, SbF6? and BF4?) resulted in the formation of nano‐sized Pd (II) aggregates under template‐free conditions. The rate of formation of aggregates can be modulated by changing the anion, affecting the rate of polymerization of CO and olefins without fouling. Herein, we describe the analysis of Pd (II) catalysts by dynamic light scattering, atomic force microscopy, X‐ray photoelectron spectroscopy and X‐ray crystallography, and co‐ and terpolymerization results including the catalytic activity, and bulk density and molecular weight of polymers. 相似文献