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71.
Ching Hsuan Lin Yu Ren Feng Kang Hong Dai Hou Chien Chang Tzong Yuan Juang 《Journal of polymer science. Part A, Polymer chemistry》2013,51(12):2686-2694
A phenolic OH‐containing benzoxazine ( F‐ap ), which cannot be directly synthesized from the condensation of bisphenol F, aminophenol, and formaldehyde by traditional procedures, has been successfully prepared in our alternative synthetic approach. F‐ap was prepared by three steps including (a) condensation of 4‐aminophenol and 5,5'‐methylenebis(2‐hydroxybenzaldehyde) (1) , (b) reduction of the resulting imine linkage by sodium borohydride, and (c) ring closure condensation by formaldehyde. The key starting material, (1) , was prepared from 2‐hydroxybenzaldehyde and s‐trioxane in the presence of sulfuric acid. F‐ap is structurally similar to bis(3,4‐dihydro‐2H‐3‐phenyl‐1,3‐benzoxazinyl)methane ( F‐a, a commercial benzoxazine based on bisphenol F/aniline/formaldehyde) except for two phenolic OHs. The phenolic OHs can provide reaction sites with epoxy and 1,1'‐(methylenedi‐p‐phenylene)bismaleimide (BMI). The structure–property relationships between the thermosets of F‐ap /epoxy, F‐a /epoxy, F‐ap /BMI, and F‐a /BMI were discussed. Experimental data showed that thermosets based on F‐ap /epoxy and F‐ap /BMI provided much better thermal properties than those based on F‐a /epoxy and F‐a /BMI. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 2686–2694 相似文献
72.
73.
Chang‐Ching Chan Mark S. Bolgar Dilusha Dalpathado David K. Lloyd 《Rapid communications in mass spectrometry : RCM》2012,26(12):1507-1514
A method has been developed to reduce the mass spectrometric ion signal suppression associated with the use of TFA as an additive in LC mobile phases. Through post‐column infusion of diluted NH4OH solution to LC eluents, the ammonium ion introduced causes the neutral analyte‐TFA ion pair to dissociate which consequently releases the protonated analyte as free ions into the gas phase (through regular electrospray ionization mechanisms). An ion signal improvement from 1.2 to 20 times for a variety of compounds had been achieved through the application of this method. The molar ratios of NH4OH:TFA which result in a reduction of signal suppression were determined to be between 0.5:1 and 50:1. In addition, it was shown that this NH4OH infusion method could reduce the level of doubly‐charged species and the product ions formed via in‐source collision. The use of diluted NH4OH solution is favorable since it is compatible with mass spectrometry analysis, and it is applicable in both positive and negative‐ion generation mode. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
74.
Hong‐Juan Deng Yu‐Jing Fang Gao‐Wei Chen Miao‐Chang Liu Hua‐Yue Wu Jiu‐Xi Chen 《应用有机金属化学》2012,26(4):164-167
An efficient and convenient copper‐catalyzed Clauson–Kass reaction of 2,5‐dimethoxytetrahydrofuran with amines in aqueous media has been developed, providing a wide range of N‐substituted pyrroles in good yields. It is noteworthy that the Clauson–Kass reaction of 2,5‐dimethoxytetrahydrofuran with p‐phenylenediamine or m‐phenylenediamine proceeds smoothly to afford the corresponding monopyrroles and bispyrroles with high selectivity in impressive yields. A plausible mechanism for the formation of N‐substituted pyrroles has been proposed. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
75.
The cyclopalladated ferrocenylimine adducts Ia , Ib , Ic were evaluated in the Suzuki cross‐coupling reaction of benzyl halides with arylboronic acids. The tricyclohexylphosphine adduct Ia exhibited highly catalytic activity for the coupling of aryl and heteroaryl boronic acids containing various functional groups with benzylic bromides and chlorides (up to 99% yield), furnishing diarylmethane derivatives with low catalyst loading (1 mol%). It is worth noting that catalyst Ia can be reused eight times without losing its catalytic activity. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
76.
Kai Zhao Yulong Xiao Chunxiang Guo Qing Chang Hongfei Gao Xiaohong Cheng 《Tetrahedron》2019,75(3):409-415
Using Suzuki coupling reactions as key steps, a series of fluorenone-based polycatenars, consisting of a central 2,7-diphenyl-9-fluorenone core connected with the 3,4,5-trialkoxybenzoate unit via –COO- linkage at each side have been synthesized. Upon elongation of the terminal alkyl chain, these compounds self-assembled into mesophase sequence of Colhex/p6mm - CubI/ in solid states as well as organogels with interesting morphologies varied from 3D helical fibers to spherical structures in solvents. 相似文献
77.
Using two-colour visible (Vis)–ultraviolet (UV) photoionisation and pulsed field ionisation–photoelectron (PFI–PE) methods, we have obtained cleanly rotationally resolved photoelectron spectra for ZrO+(X 2Δ3/2,5/2; v+ = 0, 1, and 2). The rotation assignment of these state-to-state Vis–UV–PFI–PE spectra has allowed the unambiguous determination of the ground state term symmetry for ZrO+(X) to be 2Δ3/2, and the adiabatic ionisation energy of 90Zr16O, IE(90Zr16O) = 54,948.3(8) cm?1 [6.81272(10) eV]. The symmetry of the ionic ZrO+(X 2Δ3/2) ground state determined here disagrees with that reported in previous experiments. The rotational and vibrational constants determined in this experiment for the ionic 90Zr16O+(X 2Δ3/2) ground state are: Be+ = 0.4343(8) cm?1 and αe+ = 0.0019(5) cm?1, and ωe+ = 991.2(8) cm?1 and ωe+xe+ = 3.5(8) cm?1; and those for the ionic 90Zr16O+(X 2Δ5/2) excited spin-orbit state are: Be+ = 0.4357(6) cm?1 and αe+ = 0.0022(4) cm?1, and ωe+ = 991.9(8) cm?1 and ωe+xe+ = 3.6(8) cm?1, respectively. Based on the latter Be+ value, the equilibrium bond distances are determined to be re+ = 1.691(2) Å for 90Zr16O+(X 2Δ3/2) and re+ = 1.688(1) Å for 90Zr16O+(X 2Δ5/2). The IE(ZrO) along with the spectroscopic constants obtained here are valuable for benchmarking the ab initio quantum chemical calculations for energetic and structural predictions of ZrO/ZrO+. 相似文献
78.
79.
G. F. D'alelio W. A. Fessler Y. Giza D. M. Feigl A. Chang M. Saha 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(1):159-185
Transamidation reactions of nonpolymerizing systems involving benzamides, phthalimides, arylsulfonamides, benzenedisulfonamides and -disulfonim-ides, and saccharins are described. The study includes reactions of both N-substituted and unsubstituted amides and imides with anilines and aniline hydrochlorides. An evaluation of the results of these reactions, aimed at establishing the optimum conditions for transamidations in polymerizing systems, is also presented. 相似文献
80.
Sou-Jen Chang 《合成通讯》2013,43(9):673-680
In the course of our investigation of the chemistry of diazoacenaphthene, we needed 2-benzylidene-1-diazoacenaphthene (2). As a possible precursor to 2, benzylideneacenaphthenone (1) was treated with one equivalent of tosylhydrazine with the expectation that 2 would be formed following basic decomposition. Surprisingly, acenaphthenequinone bistosylhydrazone (3) was produced instead (Eq. 1). 相似文献