GaN-nanowire-based dye-sensitized solar cells

GaN nanowires typically exhibit high electron mobility and excellent chemical stability. However, stability of GaN is detrimental for successful attachment of dye molecules and its application in dye-sensitized solar cells (DSSCs). Here we demonstrate DSSCs based on GaN/gallium oxide and GaN/TiO _x core–shell structures, and we show that coating of GaN nanowires with a TiO _x shell significantly increases dye adsorption and consequently photovoltaic performance. The best cells exhibited short circuit current density of 1.83 mA/cm² and power conversion efficiency of 0.44% under AM 1.5 simulated solar illumination.     

Light propagation and oscillations in two-dimensional graded square photonic lattices

We have studied the optical oscillations and transitions in two-dimensional graded square photonic lattices (GSPL) formed by evanescently coupled optical waveguide arrays with parabolic confinements in all transverse directions. When we retain only the orthogonal couplings, decoupled one-dimensional models can be used to obtain the various normal modes, which correspond to a variety of optical oscillations. Six different combinations of Bloch oscillation (BO), dipole oscillation (DO), and reflections from the boundaries of finite lattice are classified on the phase diagram. If we include the diagonal couplings, transitions among various oscillations are obtained with the Hamiltonian optics approach and confirmed by the field-evolution analysis. We studied in detail a typical example in which a switching occurs from the constituent BO and DO to both DOs in the two orthogonal directions. The method to analyze the complex field evolution in GSPL can be extended to similar systems with different types of lattices and/or confinements.     

动态光谱的单拍提取

为了提高动态光谱(dynamic spectrum,DS)数据处理方法的效率与精度,采用单拍提取技术,即对所采集全部波长对应的光电容积脉搏波(photoelectric plethysmography,PPG)叠加平均所得到的全波段PPG,以单个脉搏为周期,提取其上升沿作为模板;用该模板校正各个波长PPG的上升沿,再以...     

Parallel synthesis of natural product-like polyhydroxylated pyrrolidine and piperidine alkaloids

The preparation of natural product-like polyhydroxylated pyrrolidine and piperidine alkaloids using a combination of solid– and solution-phase organic synthesis is described. The key intermediates, enantiopure five- or six-membered tri-O-benzyl cyclic nitrones, were efficiently prepared on solid support from accessible chiral furanosides and pyranosides, respectively. The substituent diversity was achieved by a diastereoselective addition of a variety of Grignard reagents to the cyclic nitrones in solution-phase synthesis. All reaction steps and work-up procedures were modified to allow the use of automated equipment. A 36-membered demonstration library with three diversity elements (core, configuration, and substituent) was prepared in good yield and purity.     

Photonic gap vanishing in one-dimensional photonic crystals with single-negative metamaterials

The properties of photonic band gap in one-dimensional photonic crystals composed of single-negative metamaterials are studied theoretically. Our study shows that the photonic gap will vanish at a certain incident angle when both the phase-match and impedance-match conditions are satisfied simultaneously, suggesting that the bandwidth and location of the photonic gap are strongly dependent on the incident angle and polarization. However, the photonic gap will not vanish and may become insensitive to the incident angle when the two match conditions cannot be met. Our study also shows that losses in metamaterials have little effect on the properties of the photonic gap.     

Leakage current and pyroelectric properties of compositionally graded (Pb,Ca)TiO<Subscript>3</Subscript> films

Highly (100)-oriented, compositionally graded (Pb,Ca)TiO₃ (PCT) thin films with a Ca content from 0 to 24 mol% on Pt/Ti/SiO₂/Si substrates were prepared by a sol-gel process. The graded structure of the Au/PCT/Pt film capacitor showed a well-saturated hysteresis loop at an applied field of 500 kV/cm with remanent polarization (P_r), and coercive electric field (E_c) values of 9.35 C/cm² and 130 kV/cm, respectively. At 100 kHz, the dielectric constant and dielectric loss of the film were 129 and 0.024, respectively. The leakage current density of the graded PCT film was less than 1.0×10^-7 A/cm² over a voltage range from 0 to 4 V. The conduction current depended on the voltage polarity. At low electric field (110 and 180 kV/cm, respectively, for Pt and Au electrodes biased negatively), the Au/PCT and PCT/Pt interfaces form a Schottky barrier. At high electric field (>110 kV/cm), the Au electrode biased negatively shows space-charge-limited current (SCLC) behavior. The temperature dependencies of the pyroelectric coefficients of the graded PCT film were measured by a dynamic technique. From 20 to 82 °C, the pyroelectric coefficients of graded PCT film remain steady in the range 106 to 118 C/m²K. The detectivity figure of merit (F_D) of the graded PCT film was 6.7×10^-6 Pa^-0.5. PACS 77.80.-s; 77.70.+a; 77.22.-d; 51.50.+v; 68.37.-d     

Novel photonic applications of nonlinear semiconductor laser dynamics

With a proper perturbation, even a single-mode semiconductor laser can exhibit highly complex dynamical characteristics ranging from stable, narrow-linewidth oscillation to broadband chaos. In recent years, three approaches to invoke complex nonlinear dynamical states in a single-mode semiconductor laser have been thoroughly studied: optical injection, optical feedback, and optoelectronic feedback. In each case, the nonlinear dynamics of the semiconductor laser depends on five intrinsic laser parameters and three operational parameters. The dynamical state of a given laser can be precisely controlled by properly adjusting the three operational parameters. This ability to control the dynamical behavior of a laser, combined with the understanding of its characteristics, opens up the opportunity for a wide range of novel applications. This paper illustrates the utilization of the rich nonlinear dynamics of single-mode semiconductor lasers by focusing on the period-one oscillation for its applications in tunable photonic microwave generation, AM-to-FM conversion, and dual-frequency precision Doppler lidar.     

In beam gamma spectroscopy of62Zn

The decay scheme of⁶²Zn has been investigated by studying the yield functions, angular distributions and coincidence relation-ships of theγ-rays emitted in the⁶³Cu(p, 2nγ) and⁶⁰Ni(α, 2nγ) reactions. Spins up to7? were assigned to the observed states. Nuclear Reactions ⁶⁰Ni(α, 2nγ)⁶²Zn,E _α=28–35 MeV and⁶³Cu(p, 2nγ)⁶²Zn,E _p = 22–31 MeV; measuredE _γ,I _γ(θ),I _γ(E _p , andI _γ,E _α-γ coincidences,⁶²Zn deduced decay scheme. Enriched target, Ge(Li) detectors.     

The DC Arc in a Supersonic Nozzle Flow

The boundary layer integral method at its second level of approximation has been used to study the DC arc in a supersonic nozzle flow. It is shown that with the inclusion of the arc momentum balance, the critical point of the flow is, generally, not the sonic point of the external flow. The speed, at which a disturbance propagates relative to the external flow, is in general supersonic and is dependent on the arc conditions. The arc model is capable of predicting the axial electric field, the arc size and the axial pressure distribution as a function of current. For affinely related nozzles, the solution is determined by a parameter N, which is related to zt, the stagnation condition and the nominal current density at the throat (I/At). Numerical results are given for a particular nozzle shape although the method of analysis is general. Practical implications as regards nozzle design for a gas blast circuit breaker are briefly discussed.