A novel selenization technique for fabrication of superconducting FeSex thin film

A combinative method with reactive sputtering deposition and selenization technique was applied to prepare superconducting FeSe_x films on LaAlO₃ substrates successfully. The influence of selenizing temperature on film components was studied. FeSe_0.96 and FeSe films had similar and good performances in transport measurement but little difference in magnetic property. The critical onset temperature got to 11.2 K and T_c,0 got to 4 K approximately. X-ray diffraction, energy dispersive spectroscopy and scanning electron microscopy were used to analyze the ratio of constituents and morphology of several selenized films. FeSe_x film had a porous structure on surface and no well preferred orientation, which were confirmed to have little influence on superconducting properties.     

考虑空洞效应的共晶钎料合金粘塑性-损伤本构模型

在温度298K～398K和恒应变率10-5/s～10-3/s范围内进行一系列的拉伸实验,研究共晶焊料的力学行为,揭示空洞成核和生长变形机理的存在.提出一种考虑孔洞效应的粘塑性-损伤模型,基于Guron-Tvergaard-Needleman思想和正交法则,引入孔洞体积分数作为损伤变量以描述共晶钎料的力学特性.与实验数据比较,验证粘塑性-损伤模型对锡铅合金在恒应变率和稳态塑性流动条件下应力应变行为的预测能力.结果表明,该模型能够有效描述共晶焊料的本构行为:非线性、应变率敏感性、空洞损伤演化,并可用于分析电子封装中焊点的可靠性问题.     

Highly Efficient Decomposition of Perfluorocarbons for over 1000 Hours via Active Site Regeneration

Tetrafluoromethane (CF₄), the simplest perfluorocarbon (PFC), has the potential to exacerbate global warming. Catalytic hydrolysis is a viable method to degrade CF₄, but fluorine poisoning severely restricts both the catalytic performance and catalyst lifetime. In this study, Ga is introduced to effectively assists the defluorination of poisoned Al active sites, leading to highly efficient CF₄ decomposition at 600 °C with a catalytic lifetime exceeding 1,000 hours. ²⁷Al and ⁷¹Ga magic-angle spinning nuclear magnetic resonance spectroscopy (MAS NMR) showed that the introduced Ga exists as tetracoordinated Ga sites (Ga_IV), which readily dissociate water to form Ga−OH. In situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and density function theory (DFT) calculations confirmed that Ga−OH assists the defluorination of poisoned Al active sites via a dehydration-like process. As a result, the Ga/Al₂O₃ catalyst achieved 100 % CF₄ decomposition keeping an ultra-long catalytic lifetime and outperforming reported results. This work proposes a new approach for efficient and long-term CF₄ decomposition by promoting the regeneration of active sites.     

Influence of a Fe/activated carbon catalyst and reaction parameters on methane decomposition during the synthesis of carbon nanotubes

In our experimental work on carbon nanotubes synthesis, the influence of pre-treatment and reaction temperature conditions over Fe catalyst loaded on low-cost activated carbon (AC) in the catalytic chemical vapor deposition of methane was studied. Catalyst with the metal concentration of 5 mass % calcined at 350°C and reduced at 450°C was effective in CH₄ decomposition giving 98 % conversions. TEM images showed that thin multi-walled carbon nanotubes (MWNTs) with the average internal diameter of ∼ 8 nm and the wall thickness of ∼ 2.5 nm were obtained over unreduced Fe/AC catalyst at the reaction temperature of 850°C. On the other hand, broader filamentous nanostructures with the diameter of ∼ 22 nm and the wall thickness of ∼ 3.72 nm were observed over reduced catalyst.     

Effect of calcium supplements on osteoporosis by using nuclear analytical techniques

Neutron activation analysis (NAA) and dual energy X-ray absorptiometry (DEXA) have been used to study the effects of different calcium supplements on osteoporosis, including calcium carbonate, calcium threonate, calcium gluconate, calcium lactate, calcium acetate and a traditional Chinese medicine. Animal test results showed that calcium carbonate, calcium gluconate, calcium acetate and the Chinese medicine notably increased osteoporotic rat's femoral bone mineral density (BMD). Also, calcium carbonate, calcium acetate and the Chinese medicine significantly increased osteoporotic rat's vertebral BMD. But calcium L-threonate and calcium lactate had no such effects. Calcium gluconate, calcium acetate and the Chinese medicine improved the bone mechanical intensity of osteoporotic rats. The results of NAA showed that the loss of elements in spongy bones was more seriously than that in compact bone and was difficult to be improved. This revised version was published online in August 2006 with corrections to the Cover Date.     

Hybrid NAA method for assessment of the levels of organic halogen compounds in the atmosphere in China

Abstract Passive air samplers (polyurethane foam disks) were deployed at 25 urban sites and 66 rural sites over the period of July to October 2005, partly between October 2005 and January 2006 for about 120 days across China, and analyzed for extractable organo-chlorine /-bromine /-iodine (EOCl/EOBr/EOI) and polychlorinated biphenyls (PCBs) using hybrid neutron activation analysis (NAA) combined with gas chromatographymass spectrometry (GC-MS). The average concentration of EOCl, EOBr, EOI and ΣPCBs among all the sites were 173.7, 3.5, 1.0 and 0.74 ng/d, respectively. Higher values of EOCl/Br/I and PCBs were detected in the areas of high usage and high emission, which were linked to relatively high-income areas in China, while lower in the west ill-developed region of China, which indicated that these pollutants mainly came from industrial pollution. Higher EOCl contents in traffic areas stated that the exhaust emission from vehicle was another main source of organochlorines in the air. The relative proportions of the known organochlorines (84 PCB congeners) to total EOCl were 0.02–3.0%, which implied that most of EOCl measured in air were unknown.     

Urinary Metabolites of Isoliquiritigenin in Wistar Rats using UHPLC–TOF–MS-based Xenometabolomics

Isoliquiritigenin, a chalcone found in licorice root and many other plants, has shown potential antioxidant, estrogenic and antitumor activities. The present study was to investigate urinary metabolism of isoliquiritigenin in Wistar rats by ultra-high pressure liquid chromatography coupled to electrospray ionization TOF–MS (UHPLC–TOF–MS)-based xenometabolomics. Urine samples were collected before and after oral administration of isoliquiritigenin, and analyzed by UHPLC–TOF–MS. After deconvolution, the resulting data matrices were subjected to multivariate data analysis. Projection to latent structures discriminant analysis was performed to screen the metabolites. Fifteen urinary metabolites of isoliquiritigenin were screened out and 13 of them were further identified by Agilent MassHunter Software. The results of this work show that UHPLC–TOF–MS-based xenometabolomics was able to comprehensively identify the metabolites of phytochemicals and may represent a valuable tool for monitoring the food consumption.

     

Catalytic pyrolysis of waste wood chip over mesoporous materials using Py-GC/MS

Research on Chemical Intermediates - Pyrolysis Gas Chromatography/Mass Spectroscopy (Py-GC/MS) was used to investigate the catalytic pyrolysis of waste wood chip. Two different mesoporous...     

Solution of the fundamental space-filling mode of photonic crystal fibers: numerical method versus analytical approaches

The accuracy of the solution of the fundamental space-filling mode of photonic crystal fibers by scalar and vectorial analytical approaches and its effect on the effective index models are investigated. Using a plane wave method as a benchmark, we show that the optimal choice of the radius of the equivalent circular unit cell used in the approximations is different for the two approaches and this value has a great effect on the accuracy of the solution of the fundamental space-filling mode. We also show that the vectorial approach with a properly defined value of the radius is highly accurate over a wide parameter range, whereas the scalar approach causes the main error in the scalar effective index model. We also confirm that a fully vectorial effective index model is accurate and efficient in the case of photonic crystal fibers with large air filling fractions. PACS 42.25.Bs; 42.70.Qs; 42.81.Qb     

Deconvolution: a wavelet frame approach

This paper devotes to analyzing deconvolution algorithms based on wavelet frame approaches, which has already appeared in Chan et al. (SIAM J. Sci. Comput. 24(4), 1408–1432, 2003; Appl. Comput. Hormon. Anal. 17, 91–115, 2004a; Int. J. Imaging Syst. Technol. 14, 91–104, 2004b) as wavelet frame based high resolution image reconstruction methods. We first give a complete formulation of deconvolution in terms of multiresolution analysis and its approximation, which completes the formulation given in Chan et al. (SIAM J. Sci. Comput. 24(4), 1408–1432, 2003; Appl. Comput. Hormon. Anal. 17, 91–115, 2004a; Int. J. Imaging Syst. Technol. 14, 91–104, 2004b). This formulation converts deconvolution to a problem of filling the missing coefficients of wavelet frames which satisfy certain minimization properties. These missing coefficients are recovered iteratively together with a built-in denoising scheme that removes noise in the data set such that noise in the data will not blow up while iterating. This approach has already been proven to be efficient in solving various problems in high resolution image reconstructions as shown by the simulation results given in Chan et al. (SIAM J. Sci. Comput. 24(4), 1408–1432, 2003; Appl. Comput. Hormon. Anal. 17, 91–115, 2004a; Int. J. Imaging Syst. Technol. 14, 91–104, 2004b). However, an analysis of convergence as well as the stability of algorithms and the minimization properties of solutions were absent in those papers. This paper is to establish the theoretical foundation of this wavelet frame approach. In particular, a proof of convergence, an analysis of the stability of algorithms and a study of the minimization property of solutions are given.