光敏络合催化光解水析氢的电化学模拟

Durham等^[1]曾利用Pt(黑)|lN HCl‖Ru(bipy)₃²⁺、MV²⁺、EDTA(pH=9)|Pt(网)电池模拟光解水析氢反应。但该装置的左、右二半电池中溶液的pH值相差9以上,相当于外加0.5V以上的偏压,因此,不能真实地模拟自发的光解水析氢过程。     

Fabrication of Nb2O5/C nanocomposites as a high performance anode for lithium ion battery

Nb₂O₅/C nanosheets are successfully prepared through a mixing process and followed by heating treatment.Such Nb₂O₅/C based electrode exhibits high rate performance and remarkable cycling ability, showing a high and stable specific capacity of ~380 mAh g^-1 at the current density of 50 mA g^-1(much higher than the theoretical capacity of Nb₂O₅).Further more,at a current density of 500 mA g^-1,the nanocomposites electrode still exhibits a specific capacity of above 150 mAh g^-1 after 100 cycles.These results suggest the Nb₂O₅/C nanocomposite is a high performance anode material for lithium-ion batteries.     

Therapeutic effect of hepatocyte growth factor-secreting mesenchymal stem cells in a rat model of liver fibrosis

Bone marrow-derived mesenchymal stromal cells (MSCs) have been reported to be beneficial for the treatment of liver fibrosis. Here, we investigated the use of genetically engineered MSCs that overexpress hepatocyte growth factor (HGF) as a means to improve their therapeutic effect in liver fibrosis. Liver fibrosis was induced by intraperitoneal injection of dimethylnitrosamine. HGF-secreting MSCs (MSCs/HGF) were prepared by transducing MSCs with an adenovirus carrying HGF-encoding cDNA. MSCs or MSCs/HGF were injected directly into the spleen of fibrotic rats. Tissue fibrosis was assessed by histological analysis 12 days after stem cell injection. Although treatment with MSCs reduced fibrosis, treatment with MSCs/HGF produced a more significant reduction and was associated with elevated HGF levels in the portal vein. Collagen levels in the liver extract were decreased after MSC/HGF therapy, suggesting recovery from fibrosis. Furthermore, liver function was improved in animals receiving MSCs/HGF, indicating that MSC/HGF therapy resulted not only in reduction of liver fibrosis but also in improvement of hepatocyte function. Assessment of cell and biochemical parameters revealed that mRNA levels of the fibrogenic cytokines PDGF-bb and TGF-β1 were significantly decreased after MSC/HGF therapy. Subsequent to the decrease in collagen, expression of matrix metalloprotease-9 (MMP-9), MMP-13, MMP-14 and urokinase-type plasminogen activator was augmented following MSC/HGF, whereas tissue inhibitor of metalloprotease-1 (TIMP-1) expression was reduced. In conclusion, therapy with MSCs/HGF resulted in an improved therapeutic effect compared with MSCs alone, probably because of the anti-fibrotic activity of HGF. Thus, MSC/HGF represents a promising approach toward a cell therapy for liver fibrosis.     

Indium trichloride mediated intramolecular Prins-type cyclization

[reaction: see text] Intramolecular Prins-type reactions of compounds having both functionalities of homoallyl alcohol and acetal moiety are described. The intramolecular Prins cyclizations were performed using indium trichloride in chloroform or 25% aqueous THF. Both 9-oxabicyclo[3.3.1]nonane and 3,9-dioxabicyclo[3.3.1]nonane compounds were successfully obtained in moderate yields.     

Low tropospheric wind measurement with Mie Doppler Lidar

A double edge Mie Doppler lidar at 1064 nm was developed in Hefei, China in 2005 for low tropospheric wind measurement. Intercomparison experiments with a wind profiler and a wiresonde were held. Intercomparisons of concurrent lidar and other instrument observations show good agreement with expected measurement accuracy. The examples of validated lidar wind profiles obtained during these experiments as well as an example of continuous wind observations are presented. The instrument has demonstrated the capability of atmospheric wind field measurement from 0.2 to 5 km altitude, achieving below 2 m/s accuracy with 1 min averaging and 21.2 m vertical resolution.     

Comparison of nonlinear effects in amplitude and phase holograms recorded in photographic materials

Beam amplitudes of successive orders diffracted on holographic gratings are calculated and thus nonlinear effects in amplitude, bleached phase and reversal bleached phase holograms are compared. Then values of intermodulation noise are compared for the above three types of Fourier hologram of two circular holes.     

Rotational Raman lidar for obtaining aerosol scattering coefficients

Two-channel lidar signals that are composed of total rotational scattering and elastic signals provide good information about aerosol scattering coefficients. We can calculate the aerosol backscattering coefficient and extinction coefficient directly, without making any assumption or calibration. Generally, a high-spectral-resolution lidar is used for aerosol monitoring, but we have designed a new low-spectral-resolution lidar system that contains both kinds of scattering information simultaneously, and we have retrieved the aerosol scattering coefficient. The results show that there is no need to assume any relation between aerosol backscattering and extinction or to consider any wavelength calibration to determine the aerosol scattering coefficient.     

Knot signature functions are independent

A Seifert matrix is a square integral matrix satisfying

To such a matrix and unit complex number there corresponds a signature,

Let denote the set of unit complex numbers with positive imaginary part. We show that is linearly independent, viewed as a set of functions on the set of all Seifert matrices.

If is metabolic, then unless is a root of the Alexander polynomial, . Let denote the set of all unit roots of all Alexander polynomials with positive imaginary part. We show that is linearly independent when viewed as a set of functions on the set of all metabolic Seifert matrices.

To each knot one can associate a Seifert matrix , and induces a knot invariant. Topological applications of our results include a proof that the set of functions is linearly independent on the set of all knots and that the set of two-sided averaged signature functions, , forms a linearly independent set of homomorphisms on the knot concordance group. Also, if is the root of some Alexander polynomial, then there is a slice knot whose signature function is nontrivial only at and . We demonstrate that the results extend to the higher-dimensional setting.

     

Group-velocity-matched cascaded quadratic nonlinearities of femtosecond pulses in periodically poled MgO:LiNbO3

Large nonlinear phase shifts were generated with femtosecond pulses at 1560 nm through cascaded quadratic interactions in periodically poled MgO-doped LiNbO3. The off-diagonal component of the nonlinear coefficient was utilized for simultaneous quasi phase matching and group-velocity matching. The effective nonlinear refractive index was varied from -2.9 x 10(-14) to +3.3 x 10(-14) cm2/W by tuning the phase-mismatch conditions.