Efficient terpene hydroxylation catalysts based upon P450 enzymes derived from actinomycetes

The hydroxylation of alpha-ionone 1 and beta-ionone 2 to their corresponding mono-hydroxylated derivatives has been examined using a recombinant E. coli whole cell system, in which cytochromes P450 SU1 and SU2, and P450 SOY were over-expressed with their cognate ferrodoxins. Both substrates are hydroxylated with a high degree of regioselectivity and for alpha-ionone 1 the reaction is highly diastereoselective yielding the anti-isomer.     

Enantioselective epoxidation of linolenic acid catalysed by cytochrome P450(BM3) from Bacillus megaterium

Cytochrome P450(BM3), from Bacillus megaterium, catalyses the epoxidation of linolenic acid yielding 15,16-epoxyoctadeca-9,12-dienoic acid with complete regio- and moderate enantio-selectivity (60% ee). The absolute configuration of the product is tentatively assigned as 15(R),16(S)-. The Michaelis-Menten parameters kcat and Km for the reaction were determined to be 3126 +/- 226 min(-1) and 24 +/- 6 microM respectively.     

Boron‐Metallated Borirenes and Bis(Borirenes)

Heating the metalloborylene complex [{(η⁵‐C₅Me₅)Fe(CO)₂}(μ‐B){Cr(CO)₅}] with alkynes and diynes leads to the formation of B‐metallated borirenes and a bis(B‐metallated borirene) through formal transfer of the metalloborylene moiety [(η⁵‐C₅Me₅)(OC)₂Fe(B:)]. By using this protocol, a range of B‐metallated borirenes with electron‐donating and electron‐withdrawing substituents are prepared, and these are studied spectroscopically, structurally, and computationally. The yellow‐orange color of the complexes is additionally explained through time‐dependent density functional theory calculations.     

Synthesis and characterization of semiconductor tin oxide thin films on glass substrate by sol–gel technique

In this study, synthesis and characterization of semiconductor tin oxide (SnO₂) thin films on glass substrate were systematically investigated by using sol–gel technique for gas sensing applications. Turbidity, pH values, wettability and rheological properties of solution were measured by turbidimeter, pH meter, contact angle goniometer and rheometer machines before coating process. The thermal, structural, microstructural and optical properties of the coatings and powders made from the sols were extensively characterized by using DTA-TG, FT-IR, XRD, SEM-EDS, refractometer and spectrophotometer. Four different solutions, including 6, 8, 10 and 14 mL methanol content, were prepared by sol–gel technique to determine solvent influence on microstructure and semiconducting properties of the thin films. Refractive indiceses, band gaps, absorbance and transmittance values of SnO₂ thin films, containing different methanol quantity, were determined and their variations depending on solvent content were obtained. It is concluded that solvent content influences microstructural and semiconducting properties of Sn based oxide thin films notably.     

Heat transfer due to impinging co-axial jets and the jets’ fluid flow characteristics

This investigation had multiple goals. One goal was to obtain definitive information about the heat transfer characteristics of co-axial impinging jets, and this was achieved by measurements of the stagnation-point, surface-distribution and average heat transfer coefficients. These results are parameterized by the Reynolds number Re which ranged from 5000 to 25,000, the dimensionless separation distance between the jet exit and the impingement plate H/D (4–12), and the ratio of the inner diameters of the inner and outer pipes d/D (0–0.55). The d/D = 0 case corresponds to a single circular jet. The other major goal of this work was to quantify the velocity field of co-axial free jets (impingement plate removed). The velocity-field study included both measurements of the mean velocity and the turbulence intensity.It was found that the variation of the stagnation-point heat transfer coefficient with d/D attained a maximum at d/D = 0.55. Furthermore, the variation of the local heat transfer coefficient across the impingement surface was more peaked for d/D = 0 and became flatter with decreasing d/D. This suggests that for cooling a broad expanse of surface, co-axial jets of high d/D are preferable. On the other hand, for localized cooling, the single jet (d/D = 0) performed the best. In general, for a given Reynolds number, a co-axial jet yields higher heat transfer coefficients than a single jet. Off-axis velocity peaks were encountered for the jets with d/D = 0.105. The measurements of turbulence intensity yielded values as high as 18%.     

Optimal aggregation of fuzzy preference relations with an application to broadband internet service selection

This paper investigates the aggregation of multiple fuzzy preference relations into a collective fuzzy preference relation in fuzzy group decision analysis and proposes an optimization based aggregation approach to assess the relative importance weights of the multiple fuzzy preference relations. The proposed approach that is analytical in nature assesses the weights by minimizing the sum of squared distances between any two weighted fuzzy preference relations. Relevant theorems are offered in support of the proposed approach. Multiplicative preference relations are also incorporated into the approach using an appropriate transformation technique. An eigenvector method is introduced to derive the priorities from the collective fuzzy preference relation. The proposed aggregation approach is tested using two numerical examples. A third example involving broadband internet service selection is offered to illustrate that the proposed aggregation approach provides a simple, effective and practical way of aggregating multiple fuzzy preference relations in real-life situations.     

Fabrication and characterization of anhydrous polymer electrolyte membranes based on sulfonated poly(vinyl alcohol) and benzimidazole

In the present study, a new type of chemically cross-linked polymer blend membranes consisting of poly(vinyl alcohol) (PVA), sulfosuccinic acid (SSA) and benzimidazole (BnIm), as a dopant, at different stoichometric ratios were prepared and used as proton conducting polymer electrolytes. The proton conductivities of the membranes were investigated as a function of blending composition and the temperature. TGA indicated that the blend polymers were thermally stable up to approximately 175°C; differential scanning calorimetry (DSC) results illustrated the homogeneity of the materials. The local chain flexibility of the host polymer increased with BnIm concentration. The methanol permeability values of the membranes were much lower than that of a Nafion-membrane. The proton conductivity of these materials increased with BnIm and SSA concentration and the temperature.     

A Differential Calculus on the (h,j)-Deformed Z3-Graded Superplane

In this work, Z₃-graded quantum (h, j)-superplane is introduced with a help of proper singular g matrix and a Z₃-graded calculus is constructed over this new h-superplane. A new Z₃-graded (h, j)-deformed quantum (super)group is constructed via the obtained calculus.