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151.
Catherine Hurley 《Journal of computational and graphical statistics》2013,22(4):365-379
Abstract Statistical software systems include modules for manipulating data sets, model fitting, and graphics. Because plots display data, and models are fit to data, both the model-fitting and graphics modules depend on the data. Today's statistical environments allow the analyst to choose or even build a suitable data structure for storing the data and to implement new kinds of plots. The multiplicity problem caused by many plot varieties and many data representations is avoided by constructing a plot-data interface. The interface is a convention by which plots communicate with data sets, allowing plots to be independent of the actual data representation. This article describes the components of such a plot-data interface. The same strategy may be used to deal with the dependence of model-fitting procedures on data. 相似文献
152.
William Y. C. Chen Eva Y. P. Deng Rosena R. X. Du Richard P. Stanley Catherine H. Yan 《Transactions of the American Mathematical Society》2007,359(4):1555-1575
We present results on the enumeration of crossings and nestings for matchings and set partitions. Using a bijection between partitions and vacillating tableaux, we show that if we fix the sets of minimal block elements and maximal block elements, the crossing number and the nesting number of partitions have a symmetric joint distribution. It follows that the crossing numbers and the nesting numbers are distributed symmetrically over all partitions of , as well as over all matchings on . As a corollary, the number of -noncrossing partitions is equal to the number of -nonnesting partitions. The same is also true for matchings. An application is given to the enumeration of matchings with no -crossing (or with no -nesting).
153.
We characterise all maximal convex l-subgroups of A(), the automorphismgroup of a doubly transitive chain of countable coterminality.We then determine, up to isomorphism, all doubly transitiveactions of the l-group A(). Finally, assuming the ContinuumHypothesis, we show that there exists an unbounded chain ofproper prime subgroups of A(). 相似文献
154.
155.
Coupier Gwennou Djellouli Adel Quilliet Catherine 《The European physical journal. E, Soft matter》2019,42(9):1-7
The European Physical Journal E - This report presents the results of high-pressure and broadband dielectric spectroscopy studies in polyvinylidene difluoride (PVDF) and barium strontium titanate... 相似文献
156.
157.
[reaction: see text] Computer-aided design protocols to identify new chiral ligands for reactions proceeding through well-defined transition states are outlined. Ligand families are discovered via computational screening of large structural databases such as the Cambridge Structural Database. Using this method, a novel cis-decalin ligand has been identified as a chiral auxiliary for the allylboration of aldehydes. Synthesis, resolution, and evaluation revealed that this new auxiliary provided the aldehyde facial approach upon which the design was predicated. 相似文献
158.
Dearden MJ Firkin CR Hermet JP O'Brien P 《Journal of the American Chemical Society》2002,124(40):11870-11871
A "(+)-sparteine-like" chiral diamine, readily synthesized in three steps from (-)-cytisine, has been evaluated in four different asymmetric transformations; in each case, selectivity in an enantiocomplementary fashion to (-)-sparteine was observed. 相似文献
159.
Petit A Vincent SJ Zwahlen C 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2002,156(2):313-317
A two-dimensional HSQC-based NMR method, (15)N-COSMO-HSQC, is presented for the rapid determination of homonuclear (3)J(HNHalpha) couplings in (15)N-labeled proteins in solution. Scalar couplings are extracted by comparing the intensity of two separate datasets recorded with and without decoupling of the (3)J(HNHalpha) during a preparation period. The scalar couplings are introduced through a cosine modulation of the peak intensities. The experiment relies on a BIRD sandwich to selectively invert all amide protons H(N) and is very simple to implement. (3)J(HNHalpha) couplings were determined using both the (15)N-COSMO-HSQC and quantitative-J on (15)N-labeled chemokine RANTES. The two experiments show well-correlated values. 相似文献
160.