Spatial and temporal distribution of environmental markers from Coastal to Plateau areas in Antarctica by firn core chemical analysis

The chemical analysis of shallow firn cores sampled in coastal and plateau areas in Northern Victoria Land and along a transect from Talos Dome to Dome C (East Antarctica, Pacific Ocean sector) allowed a global view of spatial and temporal changes in chemical composition of snow depositions over the last 100 years. Variations in concentration of primary (sea spray) and secondary (biogenic emission, atmospheric inputs) source markers were observed and discussed as a function of distance from the sea and altitude.

In the stations characterized by relatively high snow accumulation rates, the sub-sampling resolution was sufficient to obtain a stratigraphic dating by using the periodical variations of seasonal markers. In these stations, a subdivision in “summer” and “winter” samples was carried out in order to study the seasonal changes of the contributions of the measured compounds to the snow composition as elevation and distance from the sea increase.

Some evidence of post-depositional effects which are able to change the original deposition of chloride and nitrate, was observed at stations with low accumulation rates. The reliability of the depth/concentration profile of these substances for reconstructing past deposition was also discussed.     

Modified Particle Detachment Model for Colloidal Transport in Porous Media

Particle detachment from the rock during suspension transport in porous media was widely observed in laboratory corefloods and for flows in natural reservoirs. A new mathematical model for detachment of particles is based on mechanical equilibrium of a particle positioned on the internal cake or matrix surface in the pore space. The torque balance of drag, electrostatic, lifting and gravity forces, acting on the particle from the matrix and the moving fluid, is considered. The torque balance determines maximum retention concentration during the particle capture. The particle torque equilibrium is determined by the dimensionless ratio between the drag and normal forces acting on the particle. The maximum retention function of the dimensionless ratio (dislodging number) closes system of governing equations for colloid transport with particle release. One-dimensional problem of coreflooding by suspension accounting for limited particle retention, controlled by the torque sum, allows for exact solution under the assumptions of constant filtration coefficient and porosity. The explicit formulae permit the calculation of the model parameters (maximum retention concentration, filtration and formation damage coefficients) from the history of the pressure drop across the core during suspension injection. The values for maximum retention concentration, as obtained from two coreflood tests, have been matched with those calculated by the torque balance on the micro scale.     

Cyclotron production and parameters calculation of <Superscript>48</Superscript>V Nitinol stent for renal arteries in brachytherapy

The Nitinol stent was bombarded in a cyclotron at a flux rate of 4 μA/cm² to produce ⁴⁸V via ⁴⁸Ti (p, n) ⁴⁸V reaction. In this study dose distribution of ⁴⁸V radioactive stent was investigated for renal arteries. Version X-2.6 of the MCNP Monte Carlo radiation transport system code was employed to calculate dose distribution around the stent. As ⁴⁸V is a mixed gamma and beta particle emitter, two separate runs of MCNP for both beta and gamma particles were performed and the total deposited dose was acquired by adding the two mentioned values. In order to verify the simulation, the calculated results have been compared with previous published data for the source. Calculated results show high dose gradient near the stent and the maximum amount of dose deposits at the vessel wall. According to (AAPM) TG-60/149 protocol, the dosimetric parameters, including geometry function, G(ρ,z), radial dose function, g _L (ρ), and anisotropy function, F(ρ,z), were also determined.     

19F NMR transverse and longitudinal relaxation filter experiments for screening: a theoretical and experimental analysis

Ligand‐based ¹⁹F NMR screening represents an efficient approach for performing binding assays. The high sensitivity of the methodology to receptor binding allows the detection of weak affinity ligands. The observable NMR parameters that are typically used are the ¹⁹F transverse relaxation rate and isotropic chemical shift. However, there are few cases where the ¹⁹F longitudinal relaxation rate should also be used. A theoretical and experimental analysis of the ¹⁹F NMR transverse and longitudinal relaxation rates at different magnetic fields is presented along with proposed methods for improving the sensitivity and dynamic range of these experiments applied to fragment‐based screening. Copyright © 2016 John Wiley & Sons, Ltd.