A study ofK + p elastic scattering and reactionK + p→K + pπ+π− at 70 GeV/c

Results are presented onK ⁺ p elastic scattering and on the reactionK ⁺ p→K ⁺ pπ⁺π^? at 70 GeV/c. For the elastic channel, we measured the total ((2.29±0.04)mb) and differentialdσ/dt cross sections. The reactionK ⁺ p→K ⁺ pπ⁺π^? has a total cross section of (470±23) μb and is shown to be dominated by diffractive dissociation processes. The contributions of the quasi-two-body channels $$K^ + p \to K*^0 (890)\Delta ^{ + + } (1,236)$$ and $$K^ + p \to K*^0 (1,430)\Delta ^{ + + } (1,236)$$ and of the Double-Pomeron Exchange (DPE) processes are estimated.     

The use of sulfamic acid as a primary standard in nonaqueous titrimetry

A method has been developed for the standardization of a typical nonaqueous base lithium methoxide, with an inorganic primary standard, sulfamic acid. 'T'his acid was found to dissolve readily in four independant basic solvents, dimethyl formamide, ethylenediamine, n-butylamine and dimethyl sulfoxide. Sulfamic acid could be titrated in each of these solvents, by both visual and potentiometric means with lithium methoxide dissolved in benzene-methanol. No gels nor precipitates resulted in the course of the titrations and the accuracy of the method was comparable to that obtained using benzoic acid as the primary standard. Conductometric titrations were also performed using sulfamic acid dissolved in two systems, dimethyl formamide and glacial acetic acid. In the latter solvent it was possible to titrate sulfamic acid with perchloric acid in glacial acetic acid.     

Physicochemical characterization and cytotoxic activity evaluation of hydroxymethylferrocene:β-cyclodextrin inclusion complex

An inclusion complex of hydroxymethylferrocene (FeMeOH) with β-cyclodextrin (β-CD) was prepared in the solid state by different techniques such as physical mixture, coprecipitation, kneading and freeze-drying. The formation of the inclusion complex was confirmed by X-ray Powder Diffractometry and Fourier Transform-Infrared spectroscopy. In aqueous solution, the 1:1 stoichiometry was established by a Job plot. The inclusion complex formation was also investigated by NMR and the stability constant (Kb) of the complex was determined to be 478 M?1, which is in agreement with that obtained with UV-Vis tritation (Kb = 541.3 M?1). The phase solubility study showed a diagram classified as Bs type and that the solubility of FeMeOH was slightly increased in the presence of β-CD. Furthermore, utilizing phase solubility diagram data, the Kb was estimated to be equal to 528.0 M?1. The cytotoxic activity of FeMeOH and its complexation product with β-CD was determined using the MTT-assay on MDA-MB-231 cell line, showing that the inclusion complex has a higher capability of inhibiting cell growth compared to that of pure FeMeOH.