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991.
Storage and transport of hydrogen constitutes a key enabling technology for the advent of a hydrogen-based energy transition. Main research trends on hydrogen storage materials, including metal hydrides, porous adsorbents and hydrogen clathrates, are reviewed with a focus on recent developments and an appraisal of the challenges ahead. . 相似文献
992.
Balderas-Hernández P Ramírez-Silva MT Romero-Romo M Palomar-Pardavé M Roa-Morales G Barrera-Diaz C Rojas-Hernández A 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,69(4):1235-1245
This work presents the results obtained from a spectrophotometry study performed on some indicators of the sulfonphtaleins like phenol red (PR), thymol blue (TB), bromothymol blue (BTB), xylenol orange (XO) and methylthymol blue (MTB). During the first stage the acidity constants of some of the indicators were determined using the data from spectrophotometry, potentiometry and with the use of the software SQUAD. These were as follows: for the equilibrium 2H+BTB<-->H(2)BTB, log beta(2)=15.069+/-0.046 and for H+BTB<-->HBTB, log beta(1)=8.311+/-0.044. For the XO and the MTB five values were calculated for each, namely, for MTB: log beta(5)=42.035, log beta(4)=38.567+/-0.058, log beta(3)=32.257+/-0.057, log beta(2)=23.785+/-0.057, and log beta(1)=12.974+/-0.045 while for XO: log beta(5)=40.120+/-0.102, log beta(4)=35.158+/-0.062, log beta(3)=29.102+/-0.053, log beta(2)=21.237+/-0.044, and log beta(1)=11.682+/-0.044. During the second stage, a study was conducted on the effect of the substituents present in the indicators to determine the effect of different functional groups on the pK(a) value corresponding to the last indicator's dissociation. 相似文献
993.
Martínez-Huitle CA Brillas E 《Angewandte Chemie (International ed. in English)》2008,47(11):1998-2005
Chlorination is the most common method worldwide for the disinfection of drinking water. However, the identification of potentially toxic products from this method has encouraged the development of alternative disinfection technologies. Among them, electrochemical disinfection has emerged as one of the more feasible alternatives to chlorination. This article reviews electrochemical systems that can contribute to drinking water disinfection and underscores the efficiency of recently developed diamond films in chlorine-free electrochemical systems. 相似文献
994.
995.
Javier Sotres Anabel Lostao Dr. Linda Wildling Andreas Ebner Carlos Gómez‐Moreno Prof. Hermann J. Gruber Prof. Dr. Peter Hinterdorfer Prof. Dr. Arturo M. Baró Prof. 《Chemphyschem》2008,9(4):590-599
Atomic force microscopy is a technique capable to study biological recognition processes at the single‐molecule level. In this work we operate the AFM in a force‐scan based mode, the jumping mode, where simultaneous topographic and tip–sample adhesion maps are acquired. This approach obtains the unbinding force between a well‐defined receptor molecule and a ligand attached to the AFM tip. The method is applied to the avidin–biotin system. In contrast with previous data, we obtain laterally resolved adhesion maps of avidin–biotin unbinding forces highly correlated with single avidin molecules in the corresponding topographic map. The scanning rate 250 pixel s?1 (2 min for a 128×128 image) is limited by the hydrodynamic drag force. We are able to build a rupture‐force distribution histogram that corresponds to a single defined molecule. Furthermore, we find that due to the motility of the polymer used as spacer to anchor the ligand to the tip, its direction at rupture does not generally coincide with the normal to the tip–sample, this introduces an appreciable error in the measured force. 相似文献
996.
Ivano Tavernelli Dr. Marie‐Pierre Gaigeot Prof. Rodolphe Vuilleumier Dr. Carlos Stia Dr. Marie‐Anne Hervé du Penhoat Dr. Marie‐Françoise Politis Dr. 《Chemphyschem》2008,9(14):2099-2103
The early stages of the Coulomb explosion of a doubly ionized water molecule immersed in liquid water are investigated with time‐dependent density functional theory molecular dynamics (TD–DFT MD) simulations. Our aim is to verify that the double ionization of one target water molecule leads to the formation of atomic oxygen as a direct consequence of the Coulomb explosion of the molecule. To that end, we used TD–DFT MD simulations in which effective molecular orbitals are propagated in time. These molecular orbitals are constructed as a unitary transformation of maximally localized Wannier orbitals, and the ionization process was obtained by removing two electrons from the molecular orbitals with symmetry 1B1, 3A1, 1B2 and 2A1 in turn. We show that the doubly charged H2O2+ molecule explodes into its three atomic fragments in less than 4 fs, which leads to the formation of one isolated oxygen atom whatever the ionized molecular orbital. This process is followed by the ultrafast transfer of an electron to the ionized molecule in the first femtosecond. A faster dissociation pattern can be observed when the electrons are removed from the molecular orbitals of the innermost shell. A Bader analysis of the charges carried by the molecules during the dissociation trajectories is also reported. 相似文献
997.
Money VA Cartmell A Guerreiro CI Ducros VM Fontes CM Gilbert HJ Davies GJ 《Organic & biomolecular chemistry》2008,6(5):851-853
The substrate binding regions of a beta-1,3:1,4 glucanase are revealed through structural analysis with a thio-oligosaccharide and kinetics of enzyme variants. 相似文献
998.
A full-field generic photonic biosensor approach, which relies on a bio-doped polymeric strip waveguide configuration, is described. We show the potential of tailor-made hybrid polymeric materials prepared by sol-gel technology for the fabrication of ultra-compact biosensor devices, where both the transducer and the recognition elements are merged into one single microstructure. Such devices were fabricated by micromolding in capillaries (MIMIC) soft lithographic technique. In contrast to evanescent field sensors, the sensor response does not only rely on the interaction of the evanescent wave with the recognition element, but on the interaction of the whole field, thus enabling a reduction of the sensor dimensions and/or a decrease of its limit of detection (LOD). The potential of this generic approach was demonstrated by developing a biosensor for the detection of H(2)O(2) using horseradish peroxidase (HRP) as the doping agent. Solutions containing 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic) acid (ABTS) and different concentrations of H(2)O(2) were dispensed over the waveguide and the green-coloured cation radical ABTS*(+) product was mainly obtained inside the photonic structure, resulting in a maximum absorption increase of 2.5 a.u. at a set working wavelength of 670 nm over the H(2)O(2) concentration range studied. The sensor exhibited a sensitivity of (3.1+/-0.2) x 10(3) a.u./mol L(-1) and a limit of detection (LOD) of 4.4 x 10(-5) mol L(-1) H(2)O(2). These results anticipate that full-field waveguide microstructures based on bio-doped sol-gel polymers will enable the fabrication of cost-effective photonic biosensors. Moreover, the ease of fabrication by a soft lithography technique and the use of such polymeric materials are fully compatible with their integration in compact automatic analysis systems. 相似文献
999.
Djanashvili K Platas-Iglesias C Peters JA 《Dalton transactions (Cambridge, England : 2003)》2008,(5):602-607
The (17)O NMR shifts of aqueous samples of lanthanide triflates were measured and analysed. In these systems the triflate anion does not enter the first coordination sphere. The contact contribution to the shifts showed a break at Eu(III), which reflects a change in the number of water molecules in the first coordination sphere of the Ln(III) ion from 9 for La-Sm to 8 for the heavier lanthanides. This change in hydration number is accompanied by a change in the parameters governing the pseudo-contact shifts. Fitting of the data with tricapped trigonal prism and square antiprismatic geometries obtained by DFT (density function theory) calculations showed that the crystal field parameters for these geometries differ by an order of magnitude. The hyperfine coupling constant for both geometries was determined to be A/(Planck's constant)= -4.2 x 10(6) rad s(-1). 相似文献
1000.
Larriba C Yoshida Y Fernández de la Mora J 《The journal of physical chemistry. B》2008,112(39):12401-12407
An effort to systematize published and new data on the surface tension gamma of ionic liquids (ILs) is based on the hypothesis that the dimensionless surface tension parameter gamma V v (2/3)/ kT is a function of the void fraction x v = V v/ V m. The void volume V v is defined as the difference between the liquid volume V m occupied by an ion pair (known from cationic and anionic masses and liquid density measurements) and the sum V (+) + V (-) of the cationic and anionic volumes (known from crystal structures), while kT is the thermal energy. Our hypothesis that gamma V m (2/3)/ kT = G( x v) is initially based on cavity theory. It is then refined based on periodic lattice modeling, which reveals that the number N of voids per unit cell (hence the dimensionless surface tension) must depend on x v. Testing our hypothesis against data for the five ILs for which surface tension and density data are available over a wide range of temperatures collapses all of these data almost on a single curve G( x v), provided that slight (4%) self-consistent modifications are introduced on published crystallographic data for V (+) and V (-). An attempt to correlate the surface tension vs temperature data available for inorganic molten salts is similarly successful, but at the expense of larger shifts on the published ionic radii (8.8% for K; 3.3% for I). The collapsed G( x v) curves for ILs and inorganic salts do not overlap anywhere on x v space, and appear to be different from each other. The existence of a relation between gamma and x v is rationalized with a simple capillary model minimizing the energy. Our success in correlating surface tension to void fraction may apply also to other liquid properties. 相似文献