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排序方式: 共有162条查询结果,搜索用时 46 毫秒
71.
Ana‐Maria Gurban Lucian Rotariu Virgil Emanuel Marinescu Camelia Bala 《Electroanalysis》2012,24(12):2371-2379
A ternary composite material based on Prussian blue, single‐walled carbon nanotubes and 1‐butyl‐3‐methylimidazolium hexafluorophosphate was prepared and tested for electrochemical detection of H2O2. The sensor allows amperometric detection of H2O2 at ?0.05 V, with a sensitivity of 137 mA M?1?cm?2. The nanocomposite provides a favorable microenvironment for immobilization of horseradish peroxidase (HRP). Determination of xenoestrogenic compounds was performed by enzymatic oxidation at the surface of modified screen printed biosensor in the presence of H2O2. The developed electrochemical biosensors exhibited high sensitivity, low detection limits, good operational and storage stability, for detection of 4‐t‐butylphenol, 4‐t‐octylphenol, 4‐n‐nonylphenol and 4‐n‐nonylphenol ethoxylate. 相似文献
72.
Adina Arvinte Lucian Rotariu Camelia Bala Ana Maria Gurban 《Bioelectrochemistry (Amsterdam, Netherlands)》2009,76(1-2):107
Very sensitive, low cost and reliable NADH and H2O2 sensors were realised and used for development of enzyme based biosensors. The active surface of the electrodes was modified with a nanocomposite obtained by modification of SWNT with a proper mediator: Meldola Blue (for NADH) and Prussian Blue (for H2O2). Low applied potential of − 50 mV vs. Ag/AgCl reference electrode proved the synergistic effect of nanocomposite materials towards NADH and H2O2 detection. Biosensors for malic acid and alkylphenols have been developed, using mediator-functionalised-SWNT-based electrodes and two different classes of enzymes: NAD+-dependent dehydrogenases and peroxidases. Immobilization of the enzymes was realised using a series of different procedures — adsorption, Nafion membrane, sol–gel and glutaraldehyde, in order to find the best configuration for a good operational stability. A higher sensitivity comparing with other reported biosensors of about 12.41 mA/M·cm2 was obtained for l-malic acid biosensor with enzyme immobilised in Nafion membrane. Phenol, 4-t-octylphenol and 4-n-nonylphenol were used as standard compounds for HRP based biosensor. Fast biosensor response and comparable detection limit with HPLC methods were achieved. 相似文献
73.
The electrochemical determinations of 4-chlorophenol (4-CP) and 4-nitrophenol (4-NP) by chronoamperometry (CA) and multiple pulsed amperometry (MPA) using expanded graphite-epoxy composite (EG-Epoxy) and rotating spectral graphite disc (SG) electrodes are reported. The electrochemical behaviours of both electrodes in the presence of organics informed about oxidation peak potential and the electrode fouling with organics concentration increasing. Setting up the oxidation peak potential as detection potential, only SG gave good electroanalytical performance using CA. However, by MPA applying both electrodes exhibited the capability to assess electrochemically and quantitatively the pollutants from aqueous solutions. UV spectrometric method detecting 4-CP and 4-NP at λ = 280 nm and λ = 398 nm wavelength, respectively was used for validation and parallel determinations. 相似文献
74.
Simultaneous electrochemical determination of nitrate and nitrite in aqueous solution using Ag-doped zeolite-expanded graphite-epoxy electrode 总被引:2,自引:0,他引:2
In this work a new electrochemical sensor based on an Ag-doped zeolite-expanded graphite-epoxy composite electrode (AgZEGE) was evaluated as a novel alternative for the simultaneous quantitative determination of nitrate and nitrite in aqueous solutions. Cyclic voltammetry was used to characterize the electrochemical behavior of the electrode in the presence of individual or mixtures of nitrate and nitrite anions in 0.1 M Na2SO4 supporting electrolyte. Linear dependences of current versus nitrate and nitrite concentrations were obtained for the concentration ranges of 1-10 mM for nitrate and 0.1-1 mM for nitrite using cyclic voltammetry (CV), chronoamperometry (CA), and multiple-pulsed amperometry (MPA) procedures. The comparative assessment of the electrochemical behavior of the individual anions and mixtures of anions on this modified electrode allowed determining the working conditions for the simultaneous detection of the nitrite and nitrate anions. Applying MPA allowed enhancement of the sensitivity for direct and indirect nitrate detection and also for nitrite detection. The proposed sensor was applied in tap water samples spiked with known nitrate and nitrite concentrations and the results were in agreement with those obtained by a comparative spectrophotometric method. This work demonstrates that using multiple-pulse amperometry with the Ag-doped zeolite-expanded graphite-epoxy composite electrode provides a real opportunity for the simultaneous detection of nitrite and nitrate in aqueous solutions. 相似文献
75.
Cellular automata are discrete dynamical systems having the ability to generate highly complex behaviour starting from a simple initial configuration and set of update rules. The discovery of rules exhibiting a high degree of global self-organization is of major importance in the study and understanding of complex systems. This task is not easily achieved since coordinated global information processing must rise from the interactions of simple components with local information and communication. In this paper, a fast supporting heuristic of linear complexity is proposed to encourage the development of rules characterized by increased dynamics with regard to cell state changes. This heuristic is integrated in an evolutionary approach to the density classification task. Computational experiments emphasize the ability of the proposed approach to facilitate an efficient exploration of the search space leading to the discovery of complex rules situated beyond the simple block-expanding rules. 相似文献
76.
Vasile Georgescu Gianina Dobrescu Florica Papa Niculae I. Ionescu 《Reaction Kinetics and Catalysis Letters》2008,94(2):345-350
Benzene total oxidation on a Cu-Cr supported catalyst was investigated using the work function method. Above 300°C, the majority
of the oxygen species on the surface was O2− in the absence or in the presence of hydrocarbon. 相似文献
77.
Gabriela Czibula Alexandra-Ioana Albu Maria Iuliana Bocicor Camelia Chira 《Entropy (Basel, Switzerland)》2021,23(6)
Proteins are essential molecules, that must correctly perform their roles for the good health of living organisms. The majority of proteins operate in complexes and the way they interact has pivotal influence on the proper functioning of such organisms. In this study we address the problem of protein–protein interaction and we propose and investigate a method based on the use of an ensemble of autoencoders. Our approach, entitled , adopts a strategy based on two autoencoders, one for each type of interactions (positive and negative) and we advance three types of neural network architectures for the autoencoders. Experiments were performed on several data sets comprising proteins from four different species. The results indicate good performances of our proposed model, with accuracy and AUC values of over 0.97 in all cases. The best performing model relies on a Siamese architecture in both the encoder and the decoder, which advantageously captures common features in protein pairs. Comparisons with other machine learning techniques applied for the same problem prove that outperforms most of its contenders, for the considered data sets. 相似文献
78.
Vlad Tiberiu Alexa Camelia Szuhanek Antoanela Cozma Atena Galuscan Florin Borcan Diana Obistioiu Cristina Adriana Dehelean Daniela Jumanca 《Molecules (Basel, Switzerland)》2020,25(23)
Since ancient times complementary therapies have been based on the use of medicinal plants, natural preparations and essential oils in the treatment of various diseases. Their use in medical practice is recommended in view of their low toxicity, pharmacological properties and economic impact. This paper aims to test the antimicrobial effect of natural preparation based on clove, orange and bergamot essential oils on a wide range of microorganisms that cause infections in humans including: Streptococcus pyogenes, Staphylococcus aureus, Shigella flexneri, Candida parapsilosis, Candida albicans, Pseudomonas aeruginosa, Escherichia coli, Salmonella typhimurium and Haemophilus influenza. Three natural preparations such as one-component emulsions: clove (ECEO), bergamote (EBEO), and orange (EOEO), three binary: E(BEO/CEO), E(BEO/OEO), E(CEO/OEO) and a tertiary emulsion E(OEO/BEO/CEO) were obtained, characterized and tested for antimicrobial effects. Also, the synergistic/antagonistic effects, generated by the presence of the main chemical compounds, were studied in order to recommend a preparation with optimal antimicrobial activity. The obtained results underline the fact that the monocomponent emulsion ECEO shows antimicrobial activity, while EOEO and EBEO do not inhibit the development of the analyzed strains. In binary or tertiary emulsions E(BEO/CEO), E(CEO/OEO) and E(OEO/ BEO/CEO) the antimicrobial effect of clove oil is potentiated due to the synergism exerted by the chemical compounds of essential oils. 相似文献
79.
Multi-objective OLSR for proactive routing in MANET with delay,energy, and link lifetime predictions
Zhihao Guo Shahdi Malakooti Shaya Sheikh Camelia Al-Najjar Behnam Malakooti 《Applied Mathematical Modelling》2011,35(3):1413-1426
In this paper, we develop a multi-objective approach for proactive routing in a Mobile Ad Hoc Network (MANET). We consider three routing objectives: minimizing average end-to-end delay, maximizing network energy lifetime, and maximizing packet delivery ratio. Accordingly, we develop three routing metrics: mean queuing delay on each node, energy cost on each node, and link stability on each link. For the proposed multi-objective approach, we develop efficient prediction methods: (a) predicting queuing delay and energy consumption using double exponential smoothing, and (b) predicting residual link lifetime using a heuristic of the distributions of the link lifetimes in MANET. Extensive simulation (by using ns2) is performed for the comparison of this multi-objective OLSR with existing OLSRs. The results show that the multi-objective OLSR is effective in finding optimal routing by tradeoffs among proposed objectives. 相似文献
80.
Daniela IonitaMihaela Grecu Camelia UngureanuIoana Demetrescu 《Applied Surface Science》2011,257(21):9164-9168
The paper investigates the increase of anticorrosive and antimicrobial properties of a composite elaborated by coating TiAlZr with Ag nanoparticles. Silver nanoparticles (AgNPs) were synthesized by reducing silver salts using NaBH4, and were characterized using dynamic light scattering instrument to determine the size distribution. The morphological and elemental analysis of Ag nanoparticles on the TiAlZr surface were performed with scanning electron microscopy (SEM) and energy disperse spectroscopy (EDS). Antibacterial activity was evaluated on the basis of the inhibition of the growth of Escherichia coli bacteria, and of the electrochemical parameters from dynamic polarization tests performed in Ringers bioliquid.An empirical model of antibacterial effect of silver nanoparticles at biointerface in the presence of TiAlZr implant was discussed. 相似文献