A Simple and Rapid Label-free Fluorimetric “Turn Off-on” Sensor for Cadmium Detection Using Glutathione-capped CdS Quantum Dots

A convenient label-free fluorescence(FL) nanoprobe for rapid detection of cadmium(Cd) was established using glutathione-capped CdS quantum dots(QDs) and 1,10-phenanthroline(phen). The prepared CdS QDs exhibited a strong FL emission at 536 nm, which could be quenched by phen due to the photoinduced hole transfer(PHT) mechanism. The existence of Cd effectively recovered the FL intensity of CdS QDs, which was due to the easy detachment of phen from the surface of QDs to form[Cd(phen)₂(H₂O)₂]²⁺ in solution. Cd concentrations were linearly correlated with the FL intensity in the range of 0.0625-1.25 μmol/L under the optimized conditions and the detection limit was 0.01 μmol/L. Finally, the Cd concentration was accurately quantified in real water sample using the proposed sensor.     

吡咯亚胺配体与过渡金属的反应性及其催化烯烃聚合

在经典的Brookhart吡啶双亚胺后过渡金属烯烃聚合催化剂基础上,用吡咯五元环代替吡啶六元环骨架可得到具有不同电子效应的新型吡咯亚胺配体.通过吡咯环特殊的电子效应和位阻效应可设计出种类繁多的有别于吡啶亚胺配体的配合物.综述了吡咯亚胺配体与前过渡金属(Ti,Zr等)、后过渡金属(Fe,Co,Ni,Pd等)、稀土金属(Y...     

Resonant inelastic scattering in dilute magnetic semiconductors by soft X-ray fluorescence spectroscopy

1-x Mn_xS (where 0.05<x<1) were measured as the energy of the exciting radiation was tuned across the S and Mn-L_2,3 absorption edges of these compounds. Strong resonance peaks in Mn-L emission spectra and the systematic appearance of new spectral features in S-L emission spectra were observed. Partial substitution of Zn by a magnetic Mn ion results in strong hybridization of the Mn 3d orbitals with the sp band of the host semiconductor. A detailed study of resonant inelastic scattering in the vicinity of the S and Mn-L_2,3 absorption edges of these DMS is presented. Received: 6 March 1997     

基频估计算法研究平均骨小梁间距

超声背散射信号能提供松质骨微结构信息从而能有效的诊断骨质疏松,而平均骨小梁间距(MTBS)是表征松质骨微结构的重要参数之一。本文提出了一种基频估计的MTBS估计算法,对仿真信号和离体牛胫骨松质骨中的超声背散射信号分别进行分析处理,并和现有的两种算法(简易反向滤波跟踪(SIFT)算法和AR倒谱法)进行比较。实验结果表明基频估计算法对噪声和随机散射回波有更好的鲁棒性,在信噪比较低和随机散射回波幅度较大时估计值更加精确,且有很好的方差性能。充分说明了本文算法是一种有效的MTBS估计算法。     

Detection of long bones based on Barker code excited ultrasonic guided waves

Single pulse excited ultrasonic guided wave surfers high attenuation during the propagation in long bones.This results in small amplitude and low signal-to-noise ratio(SNR)of measured signals.Thus,the Barker code excitation is introduced into long bone detection to improve the quality of received signals,due to its efficiency in increasing amplitude and SNR.Both simulation and in vitro experiment were performed,and the results were decoded by the weighted match filter(WMF) and the finite impulse response- least squares inverse filter(FIRLSIF),respectively.The comparison between the results of Barker code excitation and sine pulse excitation was presented.For 13-bit Barker code excitation,WMF produced 13 times larger amplitude than sine pulse excitation,while FIR-LSIF achieved higher peak-sidelobe-level(PSL) of —63.59 dB and better performance in noise suppression.The results show that the Barker code excited guided waves have the potential to be applied to the long bone detection.     

Hydrothermal Synthesis and Crystal Structure of a Novel Polyoxometalate K(C_4N_2H_(12))_4(C_4N_2H_(11))_(2-)[Mo_8~ⅤMo_4~ⅥCdP_8O_(54)(OH)_8]F·6H_2O

The title compound 1 has been synthesized by the reaction of H_2MoO_4, CdCl_2, H_3PO_4, KF, piperazine hexahydrate and water in aqueous solution under mild hydrothermal conditions. Single-crystal X-ray analysis reveals that the title compound crystallizes in the triclinic system, space group P(-1) with a = 14.049(3), b = 15.972(3), c = 20.043(4) (A), α = 85.82(3), β = 81.28(3),γ = 67.15(3)°, V= 4095.9(14) (A)~3, M_r = 3204.62, Z=2,D_c = 2.598 g/cm~3,μ = 2.360 mm~(-1), F(000) = 3124, the final R = 0.0314, wR = 0.0826 and S = 0.989 for 18592 observed reflections with I > 2σ(I). The crystal packing is stabilized by N-H…O and O-H…O intra- and intermolecular hydrogen bonds to form an infinite 3D network.