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71.
Galvosas P Callaghan PT 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2006,181(1):119-125
We here demonstrate the use of NMR velocity imaging techniques to measure flow in a free falling jet of water at speeds up to and on the order of 1m/s. In particular, we show how to adapt the RARE imaging method, based on a CPMG multiple rf pulse train, so that the real and imaginary parts of the signal may be suitably acquired, enabling pulsed gradient spin echo encoding for flow. We term this method "soft-pulse-quadrature-cycled PGSE-RARE" or SPQC-PGSE-RARE. We further demonstrate the use of a one-dimensional (slice selective) imaging method which takes advantage of the cylindrical symmetry of the flow, and considerably shortens the image acquisition time. 相似文献
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A Bunker PT Männistö J.-F. St. Pierre T Róg P Pomorski L Stimson 《SAR and QSAR in environmental research》2013,24(1-2):179-189
Results from extensive 70 ns all-atom molecular dynamics simulations of catechol-O-methyltransferase (COMT) enzyme are reported. The simulations were performed with explicit TIP3P water and Mg2?+ ions. Four different crystal structures of COMT, with and without different ligands, were used. These simulations are among the most extensive of their kind and as such served as a stability test for such simulations. On the methodological side we found that the initial energy minimization procedure may be a crucial step: particular hydrogen bonds may break, and this can initiate an irreversible loss of protein structure that becomes observable in longer time scales of the order of tens of nanoseconds. This has important implications for both molecular dynamics and quantum mechanics–molecular mechanics simulations. 相似文献
74.
On the use of 2D correlation and exchange NMR spectroscopy in organic porous materials 总被引:1,自引:0,他引:1
Two-dimensional (2D) nuclear magnetic resonance (NMR) methods for the investigation of correlation and exchange have been introduced in recent years and have been applied to a range of different systems. Here, we report on the use of 2D NMR diffusion-diffusion correlation spectroscopy for the investigation of diffusion anisotropy in cellular plant tissues and of diffusion-diffusion exchange spectroscopy for the study of the diffusive exchange of dextran in a dispersion of polyelectrolyte multilayer hollow capsules. Furthermore, diffusion-relaxation correlation spectroscopy was applied to both systems. 相似文献
75.
The flow and diffusion driven separation of initially adjacent liquid molecules is known as dispersion. The primary physical quantity describing this process, the nonlocal dispersion tensor, provides insight regarding both the spatial and temporal correlations of molecular velocity fluctuations in complex flows. We here propose and demonstrate a nuclear magnetic resonance method for the measurement of this tensor, validating its implementation for the case of cylindrical Couette flow, and demonstrating its application to the study of fluid dispersion in a random bead pack. 相似文献
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2D correlations between NMR relaxation and/or diffusion have been used to investigate water and oil dynamics in food and micro-emulsion systems. In the case of Mozzarella and Gouda cheese samples, a significant change in D/T2 correlation is appearing with cheese aging. In the case of a water/toluene micro-emulsion, some evidence for coalescence effects is suggested by D/D exchange spectra. 相似文献
80.
A rapid version of PEPI (pi-echo planar imaging) velocimetry has been implemented, enabling a velocity image, at microscopic resolution, to be acquired in less than 1 s. The velocity map was reconstructed using the phase information from the ratio of two PEPI images, one obtained with a velocity-encoding filter applied prior to the imaging sequence and the other image without. The acquisition time for each image was about 80 ms and the two complete image acquisitions were acquired in one shot in 500 ms. This rapid velocimetry sequence gave a good representation of laminar pipe flow. It has also been used to examine extensional flow in a biaxial extension in which the transient extension takes about 3 s. 相似文献