全文获取类型
收费全文 | 119篇 |
免费 | 2篇 |
专业分类
化学 | 43篇 |
力学 | 8篇 |
数学 | 4篇 |
物理学 | 66篇 |
出版年
2021年 | 3篇 |
2020年 | 2篇 |
2016年 | 1篇 |
2015年 | 3篇 |
2013年 | 2篇 |
2012年 | 2篇 |
2011年 | 6篇 |
2010年 | 6篇 |
2009年 | 5篇 |
2008年 | 6篇 |
2007年 | 15篇 |
2006年 | 11篇 |
2005年 | 9篇 |
2004年 | 6篇 |
2003年 | 6篇 |
2002年 | 2篇 |
2001年 | 6篇 |
1999年 | 7篇 |
1998年 | 1篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1983年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有121条查询结果,搜索用时 31 毫秒
21.
M. W. Hunter R. Dykstra M. H. Lim T. G. Haskell P. T. Callaghan 《Applied magnetic resonance》2009,36(1):1-8
We report on the use in Antarctica of a portable nuclear magnetic resonance spectrometer which utilizes the Earth’s magnetic
field. We obtain estimates of brine content, in samples of sea ice extracted at different depths from the annual ice of McMurdo
Sound, in the vicinity of Cape Evans, Ross Island. These measurements are correlated with estimates of brine content obtained
from temperature and salinity measurements at each depth, using a knowledge of the phase diagram. 相似文献
22.
We present a new class of one-step, multi-value Exponential Integrator (EI) methods referred to as Exponential Almost Runge-Kutta (EARK) methods which involve the derivatives of a nonlinear function of the solution. In order to approximate such derivatives to a sufficient accuracy, the EARK methods will be implemented within the broader framework of Exponential Almost General Linear Methods (EAGLMs) to accommodate past values of this nonlinear function and becoming multistep in nature as a consequence. Established EI methods, such as Exponential Time Differencing (ETD) methods, Exponential Runge-Kutta (ERK) methods and Exponential General Linear Methods (EGLMs) become special cases of EAGLMs. We present order conditions which facilitate the construction of two- and three-stage EARK methods and, when cast in an EAGLM format, we perform a stability analysis to enable a comparison with existing EI methods. We conclude with some numerical experiments which confirm the convergence order and also demonstrate the computational efficiency of these new methods. 相似文献
23.
We observe the movement of water over time between pores of differing sizes in Castlegate sandstone. To achieve this, we perform an NMR transverse relaxation exchange experiment for several mixing times. The resulting data are converted to 2D T2 distributions using a 2D inverse Laplace transform (ILT). We show for the first time that quantitative analysis of ILT distributions enables one to extract characteristic times for different pores sizes. This information is potentially useful for permeability determination as well as better understanding of exchange between specific pore subpopulations. 相似文献
24.
We present an attempt to characterize planar surfactant aggregates from the measurement of the diffusion of solvent molecules
located between the lamellae. Besides anisotropy, those experiments reveal properties of the bilayers such as their orientation,
dimension and also the characteristics of their hydrodynamic modes. Experimental results are presented for two different surfactant
systems. Significant differences are apparent.
Authors' address: Paul T. Callaghan, MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and
Physical Sciences, Victoria University of Wellington, Wellington, New Zealand 相似文献
25.
We discuss the potential insights gained from 1H nuclear magnetic resonance (NMR) spectroscopy experiments on polymeric systems under both shear and extension, and we show
in particular that 1H spin-spin relaxation is sensitive to both molecular conformation and to molecular interactions. Rheo-NMR 1H spectroscopy studies on semi-dilute solutions of polyacrylamide demonstrate that the chain protons exhibit a marked T
2 reduction under shear and that the recovery on shear cessation is indicative of slow reorganisational dynamics. Studies of
the wheat flour protein, gluten, indicate marked spectroscopic changes in the vicinity of the amidic resonances associated
with glutamine residues, an effect we attribute to the disruption of hydrogen bonding.
Received: 23 June 1999/Accepted: 23 August 1999 相似文献
26.
E D Minot P T Callaghan N Kaplan 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1999,140(1):200-205
It is well known that dipolar field effects lead to multiple spin echoes in a simple two-RF pulse experiment (the MSE experiment). We show here that coherence transfer echoes (which identify the existence of multiple quantum coherences in liquid NMR) and multiple spin echoes have a common origin. Using density matrix theory we have calculated the phase and timing of multiple spin echoes from all quadrature phase combinations of RF pulses. We show for the MSE experiment that there is a one-to-one correspondence between the time domain echo order and the multiple quantum coherence order. The experimental confirmation of these phase predictions shows that multiple spin echoes provide independent evidence for the breakdown of the high temperature approximation as proposed by Warren et al. (Science 262, 2005 (1993)). 相似文献
27.
The interaction energies between PS, Pα-MS, and PMMA with several bisphenol-A-based polycarbonates were quantitatively determined from oligomer/oligomer, oligomer/homopolymer, and homopolymer/copolymer blends. Interaction energies were calculated from the Flory-Huggins theory and the Sanchez-Lacombe equation of state theory using experimental cloud points or miscibility boundaries. Alkyl addition to the phenyl rings of polycarbonate is favorable for miscibility with polystyrene whereas halogenation of the bisphenol connector unit is favorable for miscibility with poly(methyl methacrylate). Interaction energies are quantitatively ranked and described qualitatively in terms of changes in the electronic charge distribution of the polymer repeat units as calculated by SYBYL software. © 1994 John Wiley & Sons, Inc. 相似文献
28.
Diffusion-relaxation correlation in simple pore structures 总被引:2,自引:0,他引:2
Callaghan PT Godefroy S Ryland BN 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2003,162(2):320-327
The effects of independent encoding for relaxation and for diffusion using separate time and gradient dimensions are calculated for spins diffusing in plane parallel and spherical pores with relaxing walls. Two-dimensional inverse Laplace transformation is used to obtain computed (D,T(2)) maps for both geometries, in the regime in which the dimensionless diffusion coefficient is less than unity and the dimensionless relaxation parameter of order unity or greater. It is shown that there exist two distinct branches on the (D,T(2)) maps, one with diffusion and relaxation strongly correlated and one in which the diffusion coefficients vary widely independently of relaxation. 相似文献
29.
30.
Callaghan PL Fernández-Pacheco R Jasim N Lachaize S Marder TB Perutz RN Rivalta E Sabo-Etienne S 《Chemical communications (Cambridge, England)》2004,(2):242-243
Metal phosphine hydrides of type RuP(4)H(2) and RhP(3)H(3) react photochemically with HB(pin)(pin = pinacolate) to form metal boryl hydride complexes via 16-electron intermediates generated by H(2) loss; the second order rate constants for reaction of the intermediates with HB(pin) are even larger than those for reaction with Et(3)SiH. 相似文献