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141.
Fu-bao Zheng Chang-wen Zhang Pei-ji Wang Hang-xing Luan 《Solid State Communications》2012,152(14):1199-1202
The electronic and magnetic properties of N-doped ZnO nanosheets are investigated by density functional theory using local spin density approximation. The results show that in an isolated N-doped ZnO nanosheet, there is a clear spontaneous polarization of N 2p state with a magnetic moment 1.0 μB/N. We also find that the doped nitrogen atoms in ZnO nanosheets have a clustering tendency with ferromagnetic coupling between them, and thus a high room-temperature ferromagnetic nature is expected. The ferromagnetic coupling in N-doped ZnO nanosheets can be attributed to the hole-mediated double-exchange mechanism through strong p–d interaction between nitrogen and zinc atoms. 相似文献
142.
In this Letter, we propose general optimization methods to design broadband high-efficiency grating couplers for planar waveguides. We attribute the coupling bandwidth to the mismatch of effective indices between the diffracted beam and the actual grating structure around the operation wavelength for fiber to waveguide excitation. The coupling bandwidth formula is deduced. A simple parameter-separate optimization procedure is proposed for general layered grating couplers for high coupling efficiency. Using our principle, we optimized a grating coupler for a horizontal slot waveguide operating at wavelength 1.55 μm for TM polarization. The grating coupler has 1 dB bandwidth of 60 nm and coupling efficiency of 65% with incident light from single-mode optical fiber (SMF) at 8°. 相似文献
143.
We propose and demonstrate a novel and simple dual-parameter measurement scheme based on a cascaded optical fiber device of long-period grating (LPG) and photonic crystal fiber (PCF) modal interferometer. The temperature and refractive index (RI) can be measured simultaneously by monitoring the spectral characteristics of the device. The implemented sensor shows distinctive spectral sensitivities of -30.82 nm/RIU (refractive index unit) and 47.4 pm/°C by the LPG, and 171.96 nm/RIU and 10.4 pm/°C by the PCF modal interferometer. The simultaneous measurement of the temperature and external RI is experimentally demonstrated by the sensor. The temperature shift and RI shift calculated by the sensor matrix agree well with the actual temperature and RI change in the experiment. 相似文献
144.
Xiaomeng LiShifang Luan Huawei YangHengchong Shi Jie ZhaoJing Jin Jinghua Yin Paola Stagnaro 《Applied Surface Science》2012,258(7):2344-2349
Poly(styrene-b-(ethylene-co-butylene)-b-styrene) (SEBS) copolymer biomedical elastomer was covalently grafted with poly(ethylene glycol) methyl ether methacrylate (PEGMA) via a photo-initiated graft polymerization technique. The surface graft polymerization of SEBS with PEGMA was verified by ATR-FTIR and XPS. Effect of graft polymerization parameters, i.e., monomer concentration, UV irradiation time and initiator concentration on the grafting density was investigated. Comparing with the virgin SEBS film, the PEGMA-modified SEBS film presented an enhanced wettability and a larger surface energy. Besides, the surface grafting of PEGMA imparted excellent anti-platelet adhesion and anti-protein adsorption to the SEBS surface. 相似文献
145.
A novel polyaniline/Bi(2)SnTiO(7 )composite polymer was synthesized by chemical oxidation in-situ polymerization method and sol-gel method for the first time. The structural properties of novel polyaniline/Bi(2)SnTiO(7) have been characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and X-ray spectrometry. The lattice parameter of Bi(2)SnTiO(7) was found to be a = 10.52582(8) ?. The photocatalytic degradation of methylene blue was realized under visible light irradiation with the novel polyaniline/Bi(2)SnTiO(7) as catalyst. The results showed that novel polyaniline/Bi(2)SnTiO(7 )possessed higher catalytic activity compared with Bi(2)InTaO(7) or pure TiO(2) or N-doped TiO(2) for photocatalytic degradation of methylene blue under visible light irradiation. The photocatalytic degradation of methylene blue with the novel polyaniline/Bi(2)SnTiO(7) or N-doped TiO(2) as catalyst followed first-order reaction kinetics, and the first-order rate constant was 0.01504 or 0.00333 min(-1). After visible light irradiation for 220 minutes with novel polyaniline/Bi(2)SnTiO(7 )as catalyst, complete removal and mineralization of methylene blue was observed. The reduction of the total organic carbon, the formation of inorganic products, SO(4)2- and NO(3-), and the evolution of CO(2) revealed the continuous mineralization of methylene blue during the photocatalytic process. The possible photocatalytic degradation pathway of methylene blue was obtained under visible light irradiation. 相似文献
146.
Linuan Yin Jingqun Gao Jun Wang Xiaoyu Luan Pingli Kang Ying Li Kai Li Xiangdong Zhang 《Research on Chemical Intermediates》2012,38(2):523-536
The Er3+:Y3Al5O12 as an upconversion luminescence agent, which can transform visible light into ultraviolet light, was synthesized by nitrate?Ccitrate acid and calcined method. Then, a novel photocatalyst, Er3+:Y3Al5O12/TiO2?CZrO2, was prepared using ultrasonic dispersion and liquid boiling method. The samples were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). In succession, the degradation process of organic dye was monitored by UV?CVis spectrum and ion chromatography for verifying the photocatalytic activity of Er3+:Y3Al5O12/TiO2?CZrO2. The influences on its photocatalytic activity such as Ti/Zr molar ratio, heat-treated temperature, and time were studied. In addition, the influences of initial concentration, Er3+:Y3Al5O12/TiO2?CZrO2 amount, solar light irradiation time, and organic dye category on the photocatalytic degradation efficiency were also investigated. It was found the photocatalytic activity of Er3+:Y3Al5O12/TiO2?CZrO2 was superior to Er3+:Y3Al5O12/TiO2 and Er3+:Y3Al5O12/ZrO2. Therefore, the Er3+:Y3Al5O12/TiO2?CZrO2 is a useful photocatalytic material for the wastewater treatment duo to efficient utilization of solar light. 相似文献
147.
Analysis of Two-Grid Methods for Nonlinear Parabolic Equations by Expanded Mixed Finite Element Methods
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Yanping Chen Peng Luan & Zuliang Lu 《advances in applied mathematics and mechanics.》2009,1(6):830-844
In this paper, we present an efficient method of two-grid scheme for
the approximation of two-dimensional nonlinear parabolic equations
using an expanded mixed finite element method. We use two Newton
iterations on the fine grid in our methods. Firstly, we solve an
original nonlinear problem on the coarse nonlinear grid, then we use
Newton iterations on the fine grid twice. The two-grid idea is from
Xu$'$s work [SIAM J. Numer. Anal., 33 (1996), pp. 1759-1777] on
standard finite method. We also obtain the error estimates for the
algorithms of the two-grid method. It is shown that the algorithm
achieves asymptotically optimal approximation rate with the two-grid
methods as long as the mesh sizes satisfy
$h=\mathcal{O}(H^{(4k+1)/(k+1)})$. 相似文献
148.
近红外光谱小波分析在土壤参数预测中的应用 总被引:5,自引:0,他引:5
从田间采集了150个田间土壤样本,在分析了所有样本的土壤参数统计特征之后,对原始近红外光谱数据进行了聚类分析,分别得到了50个土壤全氮和50个土壤有机质的等价样本及其对应光谱。对样本光谱曲线进行8层Biorthogonal小波包分解,分解得到的最低低频[80]结点对应着土壤水分以及土壤质地的光谱变化趋势,最高高频[8 255]结点对应着土壤粒度、光谱仪精度等引起的高频震荡。对以上两个结点进行重构并从样本光谱曲线中剔除以上影响成分,得到了对应的土壤参数特征光谱。基于特征光谱建立了土壤参数偏最小二乘回归模型:全氮偏最小二乘预测模型的预测系数rc达到了0.960,验证系数rv达到了0.920;有机质偏最小二乘预测模型的预测系数rc达到0.922,验证系数rv达到0.883。模型精度明显提高,满足实际生产的需要。 相似文献
149.
150.
<正>Projective synchronization of a weighted complex network is studied in which nodes are spatiotemporal chaos systems and all nodes are coupled not with the nonlinear terms of the system but through a weighted connection.The range of the linear coefficient matrix of separated configuration,when the synchronization is implemented,is determined according to Lyapunov stability theory.It is found that projective synchronization can be realized for unidirectional star-connection even if the coupling strength between the nodes is a given arbitrary weight value.The Gray-Scott models having spatiotemporal chaos behaviours are taken as nodes in the weighted complex network,and simulation results of spatiotemporal synchronization show the effectiveness of the method. 相似文献