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We have used57Fe Mössbauer spectroscopy carried out on a magnetically aligned powder sample of DyFe10Cr2 to investigate its magnetic structure at low temperatures. Previous susceptibility measurements by Stefanski [1] demonstrated the occurrence of a spin-reorientation in DyFe10Cr2 at 190 K. Subsequent work by Yang et al. [2] confirmed this reorientation, at 175 K, and also demonstrated a second spin-reorientation at 75 K. By invoking the example of the RFe11Ti series of compounds, Yang et al. claimed that the reorientation at 175 K is axis-cone type and the 75 K reorientation is cone-plane type. Our measurements confirm the nature of these reorientations. 相似文献
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The Chainpur meteorite is one of 23 ordinary chondrites classified as LL3-type (low-Fe & low-metal). It was observed as a shower of stones falling on May 9, 1907 in Uttar Pradesh, India. We report here the characterization of the Fe-bearing phases in this chondrite using 57Fe Mössbauer spectroscopy carried out at 298 K, 120 K, 50 K and 13 K. The paramagnetic doublets of olivine and pyroxene dominate the room temperature spectrum, accounting for around 70 % of the spectral area. Moreover, a doublet present with a spectral area of 5 % and assigned to a superparamagnetic Fe 3+ phase is a consequence of terrestrial weathering. On the basis of the measured 57Fe electric quadrupole splitting of the olivine component at room temperature we estimate the mean Fe:Mg ratio in this meteoritic olivine to be around 35:65 % although there is clearly a wide range of composition. The effects of magnetic ordering of the major components olivine and pyroxene are observed at 13 K. 相似文献
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We analyse different error propagation mechanisms for conservativeand nonconservative time-integrators of nonlinear Schrödingerequations. We use a geometric approach based on interpretingwaves as relative equilibria. 相似文献
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In a recent study of the magnetic order in Gd3Ag4Sn4 by neutron powder diffraction and 119Sn Mössbauer Spectroscopy we showed that both the Gd(2d) and Gd(4e) sublattices order antiferromagnetically at 28.8(2) K. We also demonstrated that the ‘magnetic event’ around 8 K is in fact a ‘plane to axis’ spin-reorientation of the Gd magnetic structure. Here, we extend our study with 155Gd Mössbauer Spectroscopy. The initial magnetic ordering at 30(2) K is clear for both sites and substantial changes in the hyperfine fields are observed at 8 K when the magnetic structure reorients. 相似文献
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J. M. Cadogan Hong-Shuo Li Jian-Min Xu S. X. Dou H. K. Liu 《Hyperfine Interactions》1994,94(1):1921-1927
In our search for new ternary rare-earth (R) iron silicon intermetallic compounds, a novel ternary phase with the chemical formula R3Fe18.5Si3.5 has been identified with the RFeSi ratio in the range of 12–1574–7810–12. We have studied compounds with R=Gd, Tb, Dy, Ho, Er, Tm and Lu. All of the samples, except for R=Lu, form the new ternary phase3–22. X-ray diffraction data suggest that for R=Gd and Tb, the crystal structure is the rhombohedral Th2Zn17-type structure and for R=Dy, Ho, Er and Tm, the hexagonal Th2Ni17-type structure. We suggest that a 1/4 replacement of the R sites by Fe(Si) dumbbells in the CaCu5-type structure leads to the new3–22 phase, which is an ordered version of the TbCu7-type structure.57Fe Mössbauer spectroscopy has been used to determine the hyperfine parameters of the57Fe nuclei in the3–22 compounds. At 295 K, the average hyperfine field of the new3–22 phase ranges from 19.8 T (R=Ho) to 22.2 T (R=Gd). Thermogravimetric analysis (TGA) of these compounds gives Curie temperatures in the range 467 K (Tm)–549 K (Gd). Furthermore, our Mössbauer analysis enables us to investigate the preferential site occupancy shown by Si in these structures. 相似文献