Ortho effects in mass spectrometric fragmentation processes

The mass spectra of the phenylhydrazones and 2,4-dinitrophenylhydrazones of ortho substituted benzaldehydes and acetophenones (X = I, Br, Cl, OCH₃, OH) show characteristic [M ? X]⁺ ions which allow the ortho derivatives to be distinguished from their meta and para isomers.     

Neutron diffraction analysis of a compositionally modulated alloy of nickel-copper

A compositionally modulated Ni_0.4Cu_0.6 alloy, made in a thin film of 1.8 μm thickness, was examined by polarized neutron diffraction. The results show that the material is ferromagnetic, with a large enhancement of the magnetic moment (0.3μ_B/Ni) with respect to a disordered alloy. The behaviour of the magnetic moments gives strong evidence of chemical clustering.     

High-speed, high-resolution optical coherence tomography retinal imaging with a frequency-swept laser at 850 nm

High-speed, high-resolution optical coherence tomography (OCT) imaging of the human retina is demonstrated using a frequency-swept laser at 850 nm. A compact external cavity semiconductor laser design, optimized for swept-source ophthalmic OCT, is described. The laser enables an effective 16 kHz sweep rate with >10 mm coherence length and a tuning range of approximately 35 nm full width at half-maximum, yielding an axial resolution of <7 micro m in tissue.