全文获取类型
收费全文 | 771篇 |
免费 | 15篇 |
国内免费 | 4篇 |
专业分类
化学 | 582篇 |
晶体学 | 2篇 |
力学 | 3篇 |
数学 | 19篇 |
物理学 | 184篇 |
出版年
2021年 | 6篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 3篇 |
2017年 | 6篇 |
2016年 | 8篇 |
2015年 | 4篇 |
2014年 | 16篇 |
2013年 | 32篇 |
2012年 | 30篇 |
2011年 | 45篇 |
2010年 | 18篇 |
2009年 | 22篇 |
2008年 | 53篇 |
2007年 | 41篇 |
2006年 | 60篇 |
2005年 | 48篇 |
2004年 | 42篇 |
2003年 | 19篇 |
2002年 | 23篇 |
2001年 | 28篇 |
2000年 | 15篇 |
1999年 | 18篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1996年 | 10篇 |
1995年 | 10篇 |
1994年 | 6篇 |
1993年 | 9篇 |
1992年 | 5篇 |
1991年 | 13篇 |
1990年 | 9篇 |
1989年 | 8篇 |
1988年 | 6篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 14篇 |
1984年 | 22篇 |
1983年 | 7篇 |
1982年 | 8篇 |
1981年 | 4篇 |
1980年 | 7篇 |
1979年 | 12篇 |
1978年 | 10篇 |
1977年 | 6篇 |
1976年 | 15篇 |
1975年 | 7篇 |
1974年 | 11篇 |
1973年 | 8篇 |
1968年 | 3篇 |
排序方式: 共有790条查询结果,搜索用时 0 毫秒
71.
T. Faestermann F. Feilitzsch R. S. Raghavan C. Signorini T. Yamazaki C. V. K. Baba D. B. Fossan D. Proetel 《Zeitschrift für Physik A Hadrons and Nuclei》1975,275(2):157-161
Then th,α)-reaction spectroscopical data are reported on95Mo,123Te and145Nd (target nuclei). The95Mo(n, α)92Zr and123Te(n, α)120Sn reactions showed up two lines each corresponding to the ground state and the 1st excited state with a total cross section of 32 ub and 52 μb respectively. In the case of145Nd(n, α)142Ce, a transition only to the 1st excited state of142Ce is present. It is shown that in the case of95Mo,145Nd and probably123Te, most of the cross-section comes respectively from the 2+ possibly 4?, and 0 bound levels whose widths are determined to beΓ α=0.5 × 10?6 eV,Γ α=1.6×10?8 eV andΓ α=1.6 × 10?6 eV. The present results on these three nuclei, when combined with the existing data, are consistent with the calculated statistical model values. 相似文献
72.
Norimasa Yoza Hisanobu Hirano Yoshinobu Baba Shigeru Ohashi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4):605-608
Abstract Inorganic pyrophosphatase (EC 3. 6. 1. 1) drived the reaction of uridine 5′-triphosphate with glucose 1-monophosphate in the direction of uridine 5′-diphosphoglucose formation. 相似文献
73.
Prof. Jun Ishihara Fuma Usui Tomohiro Kurose Tomohiro Baba Yasunori Kawaguchi Yuki Watanabe Prof. Susumi Hatakeyama 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(6):1543-1552
The upper fragment of spirolides A and B, which are marine phycotoxins that exhibit strong antagonistic activities on nicotinic acetylcholine receptors, was constructed. The functionalized cyclohexene in spirolides was stereoselectively synthesized from the bicyclic lactone, which could be readily accessed by the Lewis acid template-catalyzed asymmetric Diels–Alder reaction of the pentadienol and methyl acrylate. 相似文献
74.
75.
Wang NH Taniguchi M Tsuji D Doi M Ohishi H Yoza K Baba K 《Chemical & pharmaceutical bulletin》2003,51(1):68-70
Four new guaianolides, sinodielides A-D (1-4), were isolated from Sinodielsia yunnanensis WOLFF together with a known polyacetylene, falcarindiol, and two known coumarins, bergapten and scopoletin. Their structures were established by spectral and X-ray analyses. 相似文献
76.
Miyashita T Baba M Shigeta S Mori K Shinozuka K 《Chemical & pharmaceutical bulletin》2003,51(6):630-634
A series of novel 10-thiaisoalloxazine derivatives bearing an alkoxymethyl or benzyloxymethyl moiety at the N-1 position has been synthesized through the bromination of 1-substituted-5-hydroxyuracils and subsequent condensation with aminobenzenethiol in a one-pot reaction. Contrary to the previous report, the formation of intermediary 5,6-diethoxy-5-hydroxy-5,6-dihydrouracil seems to be not the necessary factor for the formation of the thiaisoalloxazines, since the reaction proceeds in tetrahydrofuran (THF) or acetonitrile far more smoothly than in ethanol. The anti-human immunodeficiency virus (HIV)-1 activity of the resulted thiaisoalloxazine derivatives was evaluated in lymphocyte cells based on the inhibitory activity against the viral-induced cytopathic activity. Among the derivatives, compounds 6, 7, and 8 bearing an alkoxymethyl moiety at the N-1 position exhibited modest inhibitory activity towards the cytotopathic effect of HIV-1. 相似文献
77.
Bouchra Filali Baba Abdelali Kerbal Najib Bitit Brahim El‐Bali Jean Escudie Henry Ranaivonjatovo Michael Bolte 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(5):e205-e206
The title compound, C19H15NO6, contains a planar isoxazole ring. An intramolecular hydrogen bond is formed between the OH group attached to a phenyl ring and a carbonyl O atom. 相似文献
78.
Tatsushi Baba 《Tetrahedron letters》2004,45(31):5973-5975
New water-soluble porphycenes having sulfonic acid groups at the β-pyrrolic positions were synthesized and characterized by UV-vis, NMR, IR, and mass spectroscopy as well as elemental analyses. The series of mono- to tri-sulfonato derivatives were simply separated by the extraction method. 相似文献
79.
Saeki D Sugiura S Baba T Kanamori T Sato S Mukataka S Ichikawa S 《Journal of colloid and interface science》2008,320(2):611-614
We investigated dynamic interactions between oppositely charged small unilamellar vesicles using positively charged vesicles containing 1,2-dioleoyl-3-trimethylammonium-propane or 3beta-[N-(N('),N(')-dimethylaminoethane)-carbamoyl] cholesterol and negatively charged vesicles containing L-alpha-phosphatidyl-DL-glycerol. Aggregation, lipid bilayer mixing, contents mixing and contents leakage were systematically examined using optical density measurements, fluorescence resonance energy transfer assays, fluorescence quenching assays, light-scattering analyses, and freeze-fracture transmission electron microscopy. The oppositely charged vesicles aggregated immediately. Lipid mixing was observed, but there was no mixing of the contents. The vesicle aggregates disaggregated spontaneously after several minutes. The surface potential of the disaggregated vesicles was neutralized. From these results, we infer that the lipids in the external monolayers were exchanged between the oppositely charged vesicles while the internal monolayers remained intact. The two types of cationic lipids used exhibited different speeds of disaggregation. 相似文献
80.
Hashimoto Y Hasegawa H Baba T Waki I 《Journal of the American Society for Mass Spectrometry》2006,17(5):685-690
We describe a new mass selective ejection method from a linear ion trap, which we call axial resonant excitation (AREX). A set of vane lenses are inserted between each quadrupole rod to produce electrostatic potential that is approximately harmonic along the central axis of the quadrupole field. After ions with specific m/z are resonantly oscillated in the axial direction, the ions are mass selectively ejected in the axial direction. At a high scan rate of 11 Th/ms, AREX achieved a high ejection efficiency of more than 60%, which is more than three times higher than a conventional mass selective axial ejection method from a linear trap using fringing field. 相似文献