High-resolution geoacoustic inversion in shallow water: a joint time- and frequency-domain technique

High-resolution geoacoustic data are required for accurate predictions of acoustic propagation and scattering in shallow water. Since direct measurement of geoacoustic data is difficult, time-consuming, and expensive, inversion of acoustic data is a promising alternative. However, the main problem encountered in geoacoustic inversion is the problem of uniqueness, i.e., many diverse geoacoustic models can be made to fit the same data set. A key, and perhaps unique, aspect of this approach is the combination of data analysis in both the space-time and the space-frequency domains. This combination attempts to ameliorate the uniqueness problem by exploiting as much independent data as possible. In order to meet the stringent requirements of high spatial resolution and uniqueness, an entire method has been developed including a new measurement technique, processing/analysis technique, and inversion strategy. These techniques are described and then illustrated with a shallow-water data set. Sound-speed gradients in the upper few meters of the sub-bottom appear to be much higher (one order of magnitude) than generally assumed. And, although often ignored, a large density gradient was observed in the top layer that played an acoustically significant role.     

Die Methoden zur direkten Messung des osmotischen Drucks

Ohne Zusammenfassung     

Bergman kernel asymptotics for generalized Fock spaces

Letm(t)dt be a positive measure onR ⁺. We investigate the relations among the growth ofm, the growth of its moment sequence {y_n}, the growth of its Bergman kernel functionk x=Σγ{_n/^-1}x ⁿ, and the growth of the kernel function associated to the measureK(t) ⁻¹m(t) dt. For a large class of measures, we find that these quantities satisfy asymptotic relations similar to the simple exact relations which hold in the model casem(t)=e ⁻¹. Supported in part by a grant from the National Science Foundation.     

Ion beam etching of high resolution structures in Ta2O5 for grating-assisted directional coupler applications

An investigation on thin Ta₂O₅ films patterning using argon ion beam etching (IBE) is presented. The etch rates are characterised by varying the angle of incidence of the beam onto the substrate. Ta₂O₅ gratings with a period of 2.2 μm (1.1 μm linewidth) and 0.25 μm thickness are fabricated using an angle of incidence of 0°. The resulting Ta₂O₅ grating cross sectional profiles are analysed using AFM and SEM imaging. A fabrication method is thus demonstrated which could be used to implement wavelength selective gratings in applications such as grating-assisted directional couplers (GADCs).     

Beauveria bassiana ATCC 7159 Containsan L-Specific a-Amino Acid Benzamidase

 Biotransformation of a series of racemic N-benzoyl α-amino acids by the fungus Beauveria bassiana ATCC 7159 results in isolation of the corresponding D-amino acid benzamides in high enantiomeric purity and yield.     

Growth of carbon nanotubes from waste blast furnace gases at atmospheric pressure

Carbon emissions from industrial sources are of major global concern, especially contributions from the steel manufacturing process which accounts for the majority of emissions. Typical blast furnace gases consist of CO₂ (20‐25%), CO (20‐25%), H₂ (3‐5%) and N₂ (40‐50%) and trace amounts of other gases. It is demonstrated that gas mixtures with these compositions can be used at atmospheric pressure to grow carbon nanotubes (CNTs) by chemical vapor deposition (CVD) on to steel substrates, which act as catalysts for CNT growth. Computational modelling was used to investigate the CNT growth conditions inside the CVD chamber. The results show that industrial waste pollutant gases can be used to manufacture materials with significant commercial value, in this case CNTs.     

Solution and structural characterization of iron(II) complexes with ortho-halogenated phenolates: insights into potential substrate binding modes in hydroquinone dioxygenases

The new ligand cis,cis-1,3,5-tris-(E)-(tolylideneimino)cyclohexane (TACH-o-tolyl) forms a 1:1 complex with iron(II). Addition of substituted phenolates forms 1:1:1 ligand:iron:phenolate complexes, which have been characterized both in the solid state and in solution. There is complete binding of the phenolate to the complex only when there are ortho-halogens on the phenolate. The tertiary complexes with ortho-halo-substituted phenolates exhibit short Fe-halogen distances, and the complex containing a non-coordinating but similarly sized ortho-methyl phenolate has a significantly different conformation and coordination geometry. Therefore, it is likely that the metal-halogen interaction stabilizes the complexes. The iron(II)-halogen interaction in these complexes may explain the substrate specificity of PcpA and LinE, enzymes that preferentially bind phenols and hydroquinones containing halogen substituents in ortho positions.