全文获取类型
收费全文 | 5113篇 |
免费 | 1127篇 |
国内免费 | 1957篇 |
专业分类
化学 | 3610篇 |
晶体学 | 246篇 |
力学 | 478篇 |
综合类 | 191篇 |
数学 | 963篇 |
物理学 | 2709篇 |
出版年
2024年 | 13篇 |
2023年 | 53篇 |
2022年 | 189篇 |
2021年 | 178篇 |
2020年 | 193篇 |
2019年 | 186篇 |
2018年 | 162篇 |
2017年 | 252篇 |
2016年 | 176篇 |
2015年 | 239篇 |
2014年 | 295篇 |
2013年 | 375篇 |
2012年 | 359篇 |
2011年 | 413篇 |
2010年 | 408篇 |
2009年 | 474篇 |
2008年 | 546篇 |
2007年 | 515篇 |
2006年 | 511篇 |
2005年 | 428篇 |
2004年 | 332篇 |
2003年 | 257篇 |
2002年 | 228篇 |
2001年 | 265篇 |
2000年 | 287篇 |
1999年 | 146篇 |
1998年 | 81篇 |
1997年 | 59篇 |
1996年 | 55篇 |
1995年 | 57篇 |
1994年 | 42篇 |
1993年 | 50篇 |
1992年 | 41篇 |
1991年 | 33篇 |
1990年 | 23篇 |
1989年 | 42篇 |
1988年 | 36篇 |
1987年 | 25篇 |
1986年 | 23篇 |
1985年 | 14篇 |
1984年 | 14篇 |
1983年 | 15篇 |
1982年 | 15篇 |
1981年 | 10篇 |
1980年 | 11篇 |
1979年 | 7篇 |
1978年 | 7篇 |
1977年 | 7篇 |
1965年 | 19篇 |
1958年 | 5篇 |
排序方式: 共有8197条查询结果,搜索用时 31 毫秒
71.
5-甲基吡咯-2-羧酸酯在磺酰氢,溴或四乙酸铅作用下,生成相应的在5-甲基上含取代基的产物,后者不经分离不便可自缩合得标题化合物,核磁共振氢谱研究和分子构象木匠,当3,3位的取代基为甲酸(酯)基或乙酸(酯)基时,可形成3,3位酯基与另一吡咯环上的氮氢之间的分子内氢键,而3,3位是其它取代基,如乙酰基,丙酸(酯)基,丁酸(酯)基时不能形成类似的分子内氢键。 相似文献
72.
THE ELECTRON-BEAM IRRADIATION ON THE HIGH TEMPERATURE SUPERCONDUCTING THIN FILMS: A NUMERICAL SIMULATION OF THE LOW TEMPERATURE SCANNING ELECTRON MICROSCOPY 下载免费PDF全文
Low-temperature scanning electron microscopy (LTSEM) is a promising measuring technique for probing the spatial distribution of the superconducting properties of the high-temperature superconducting (HTS) thin films. A theoretical analysis of the electron-beam irradiation on the HTS thin films in the LTSEM has been carried out. An inhomogeneously distributed grain array model has been applied in the analysis, and some numerical sim-ulations have been carried out on the electron-beam induced voltage (EIV) signals in the LTSEM experiments. The comparisons of our numerical results with the LTSEM experi-mental data indicate that it is quite reasonable to use a two-dimensional Josephson junction array for stimulating the inhomogeneous HTS thin film sample. Our numerical results also show that the EIV signals are influenced by the electron-beam power used in the LTSEM, and a reduction of the electron-beam power is suggested in order to eliminate the errors in estimating the local values of critical temperature Tc and critical current Ic by the sample temperature and the bias current at which the first EIV signal occurs. 相似文献
73.
74.
Using the ligand pyridazine-3,6-dicarboxylate (H2pzdc), a coordination polymer [Cd2(pzdc)2(H2O)4] was synthesized and characterized by elemental analysis, thermal analysis, IR and single-crystal X-ray diffraction. The complex crystallizes in the tetragonal system with space group I41/a. The crystallographic data are: a=1.470 6(4) nm, c=1.489 8(6) nm, V=3.222 0(19) nm3, Z=16, μ=2.725 mm-1, Dc=2.594 g·cm-3, R1=0.017 8, wR2=0.044 6. In the complex, the cadmium(Ⅱ) ions with the eight-coordinated dodecahedral geometry are linked by the pzdc ligands to generate one-dimensional chains, which are associated into the three-dimensional architecture via O-H…O hydrogen bonding. CCDC: 658853. 相似文献
75.
76.
The long chain branching of polybutadienes (PB) was measured with gel permeation chroma-tography coupled to an automatically recording capillary viscometer. In this method the experimentalrelation [η] (V) was translated into the calibration curve [η] (V_R) for the monodisperse species. The curve is combined with the universal calibration so that the molecular weight distributionand an additional parameter, e.g. the average branching factor of this samples may be obtained. Longchain branching molecular weight changes with polyemerization conditions. 相似文献
77.
The structures and stabilities of these still experimentally unknown CH_nCl_(3-n)O_(2-)Li~ and CF_nCl_(3-n)O_(2-)Li~ ionshave been theoretically investigated by ab initio molecular orbital theory and density functional theory(DFT)inconjunction with the 6-311G(d,p),6-311 G(d,p),6-311 G(2d,p)and 6-311 G(2df,2p)basis sets.The optimizedgeometries,chemical bonding and NBO analysis indicate that these complexes of CH_nCl_(3-n)O_(2-)Li~ and CF_nCl_(3-n)O_(2-)Li~ exist as ion-dipole molecules.The calculated affinity energies of these species exceed 41.9 kJ/mol,which arelarge enough to suggest the possibility that these title complexes could be detected as stable species in gas phase byLi~ ion attachment mass spectrometry. 相似文献
78.
79.
80.
Solvent-free organic reactions have been attracting great interest of chemists due to the elimination of the usage of harmful organic solvents,low costs,and simplicity in the procedure1.Solvent-free mechanochemical reactions of fullerenes were explored and are significant for the reactions of fullerenes because the low solubility of fullerenes in common organic solvents requires large quantity of organic solvents and some novel fullerene reactions could only occur in the solid-state reaction2.… 相似文献