Synthesis of mikto‐topology star polymer containing one cyclic arm

Well‐defined mikto‐topology star polystyrene composed of one cyclic arm and four linear arms was synthesized by a combination of atom transfer radical polymerization (ATRP) and Cu‐catalyzed azide‐alkyne cycloaddition (CuAAC) click reaction. First, the bromine‐alkyne α,ω‐linear polystyrenes containing four hydroxyl groups protected with acetone‐based ketal groups were synthesized by ATRP of styrene using a designed initiator. Then, the bromine end‐group was converted to the azide and the linear polystyrene was cyclized intra‐molecularly by the CuAAC reaction. The four hydroxyl groups were released by deprotection and then esterified with 2‐bromoisobutyryl bromide to produce a cyclic polymer bearing four ATRP initiating units. By subsequent ATRP of styrene to grow linear polymers with the cyclic polystyrene as a macroinitiator, the mikto‐topology star polymers were prepared. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012     

On the leading term and the degree of the polynomial trace mapping associated with a substitution

Using the trace mapping and the reduced trace mapping associated with a substitution, one obtaines the spectral properties of one-dimensional Schrödinger operators of the formH=–+V onl ², where is the discrete Laplacian andV is a diagonal operator with elements derived from a substitution rule. In particular, the reduced trace mapping is closely related to the leading term of the original trace mapping. In this paper, the explicit expression of the leading term is given and its properties are discussed.     

SYSTEMATIC STUDY OF POLARIZATION OF TWO-PHOTON ABSORPTION IN SYMMETRY ASSIGNMENTS

In this paper, we have systematically analyzed the degenerate and nondegenerate two-photon polarization ratios of various point groups. We present the maximum of symmetry assignments of two-photon transition with the combination of degenerate and nondegenerate two-photon absorption. These results provide the theoretical basis for the experimental assignments.     

原子模型势理论中径向微分算符矩阵元的计算

本文推广［７，８］的工作，导出了多电子原子模型势理论中含径向微分算符的矩阵元通式，可直接用于以“速度”及“加速度”形式跃迁振子强度计算。     

Pr3+在SBN晶体中的发光特性

通过测量Ｐｒ：ＳＢＮ晶体的吸收光谱和荧光光谱来确定Ｐｒ³⁺在ＳＢＮ晶体中的能级位置。由于Ｐｒ³⁺离子占据晶体中的不同格位而引起荧光带呈现双峰结构。测量荧光寿命随温度的变化关系，表明Ｐｒ³⁺在ＳＢＮ晶体中 ³Ｐ₀态的无辐射弛豫主要是 ³Ｐ₀→¹Ｄ₂多声子弛豫过程。 关键词：     

KTiOPO4晶体纵横模劈裂的喇曼谱

在室温下测量了ＫＴｉＯＰＯ₄单晶的偏振喇曼散射谱，应用９０°散射及背散射得到了各模的峰位值，其中Ｂ₁（ＬＯ）模、Ｂ₂（ＬＯ）模的喇曼谱测量尚未见报道过。根据ＬＯ－ＴＯ劈裂的实验结果，计算出该晶体极化模的有效电荷、振子强度及沿对称轴方向的静态介电常数。 关键词：     

Traveling－Wave Electrooptical Modulator on Polymeric Film with Reversal Poling Structure

Ｔｒａｖｅｌｉｎｇ－ＷａｖｅＥｌｅｃｔｒｏｏｐｔｉｃａｌＭｏｄｕｌａｔｏｒｏｎＰｏｌｙｍｅｒｉｃＦｉｌｍｗｉｔｈＲｅｖｅｒｓａｌＰｏｌｉｎｇＳｔｒｕｃｔｕｒｅ￥ＺＨＯＵＹｉ；ＣＨＥＮＹｉｘｉｎ（ＤｅｐａｒｔｍｅｎｔｏｆＡｐｐｌｉｅｄＰｈｙｓｉｃｓ，Ｓ...     

Hybrid Optical-Electronic Implementation of Morphological Edge Detection

ＨｙｂｒｉｄＯｐｔｉｃａｌ－ＥｌｅｃｔｒｏｎｉｃＩｍｐｌｅｍｅｎｔａｔｉｏｎｏｆＭｏｒｐｈｏｌｏｇｉｃａｌＥｄｇｅＤｅｔｅｃｔｉｏｎ￥ＹＵＡＮＳｈｉｆｕ；ＺＨＡＮＧＸｕｅｒｕ；ＺＨＡＯＳｈｉｊｉｅ；ＬＩＹａｎ；ＣＨＥＮＬｉｘｕｅ（Ｄｅｐａｒｔｍｅｎｔ...     

关于虚拟激励法的一个注记

从具有随机频率与随机相位的随机谐和函数出发,证明了当随机频率与相位均为均匀分布而随机幅值与功率谱密度平方根成正比时,该随机过程的功率谱即精确地等于目标功率谱.进而表明:只需遍历频率区间,即可由单一谐和函数激励下的响应幅值给出响应的功率谱密度,从而揭示了虚拟激励法的物理意义.研究还表明:为了给出结构响应的功率谱密度,实际...