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91.
92.
The expansion theorem of quantum field theoy relating Heisenberg operators to asymptotic free-field operators is rewritten by means of the time-path technique, originally due to Schwinger, which to date has only found application in statistical mechanics. The theorem is combined with Bogoliubov's initial condition of vanishing correlations in the infinite past to rederive Keldysh's perturbation scheme for non-equilibrium statistical Green's functions. 相似文献
93.
CH. B. Tsvetanov D. T. Dotcheva 《Journal of polymer science. Part A, Polymer chemistry》1986,24(9):2253-2259
The electro-chemical characteristics of isobutyronitrile lithium (P1Li) and 2-lithio-4-cyano-2,4-dimethylpentanenitrile (P2Li) are studied. The dissociation constants K of P1Li and P2Li are of the order of 10?11M and show that in THF mainly contact ion pairs exist. The lower value of K for P2Li is an indication for intramolecular complexation between the counterion and the cyano group, next to the active center. Both compounds tend to form ion triples. The results obtained show that in THF the nitrile group of the second monomer unit participates both in intra- and intermolecular interactions with the counterion. 相似文献
94.
We describe a uniformly enclosing discretization technique formildly nonlinear boundary-value problems. This method allowsus to derive a grid generation principle, using the distancebetween the lower and upper solutions to control the grid-generationprocedure. The convergence of the proposed feedback gridgenerationmethod is proved. 相似文献
95.
Clauwaert KM Van Bocxlaer JF Major HJ Claereboudt JA Lambert WE Van den Eeckhout EM Van Peteghem CH De Leenheer AP 《Rapid communications in mass spectrometry : RCM》1999,13(14):1540-1545
This paper describes the investigation of the potential of a quadrupole orthogonal acceleration time-of-flight mass spectrometer (Q-TOF) equipped with an atmospheric pressure ionisation interface for quantitative measurements of small molecules separated by reversed phase liquid chromatography. To this end, the detection limits and linear dynamic range in particular were studied in an LC/MS/MS experiment using 3,4-methylenedioxymethamphetamine standards and 3,4-methylenedioxyethylamphetamine for internal standardisation. In a second phase, the experiment was repeated with real biological extracts (whole blood, serum, and vitreous humour). A calibration for 3,4-methylenedioxymethamphetamine and its metabolite 3,4-methylenedioxyamphetamine was prepared in each of these matrices again using 3,4-methylenedioxyethylamphetamine as internal standard. The resulting quantitative data were compared with those obtained by liquid chromatography with fluorescence detection for the same extracts. The Q-TOF results revealed excellent sensitivity and a linear dynamic range of nearly four decades (2-10 000 pg on-column, r(2) = 0.9998, 1/x weighting). Furthermore, all the calibration curves prepared in biological material were superimposable, LC/MS/MS and LC-fluorescence, and the quantitative results for actual samples compared very favourably. It was concluded that the Q-TOF achieves a linear dynamic range for quantitative LC/MS/MS work exceeding that of fluorescence detection and at much better absolute sensitivity. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
96.
Photonuclear activation and high resolution gamma-ray spectrometry have been used to determine non-destructively the concentrations of 25 trace elements in Maroccan phosphate rock. The activation was simultaneously performed for phosphate samples and multielement standards in the bremsstrahlung beam of a linear electron accelerator at 18 and 30 MeV maximum energies. Gamma-ray spectra were recorded with a 79 cm3 Ge(Li) detector and a programmable analyzer IN 96. A detailed study of interferences was carried out. Limits of detection between 0.5 and 125 μg·g?1 were obtained. 相似文献
97.
Shigeo Shioda 《Queueing Systems》2008,60(1-2):153-170
We study a single-server finite-capacity queue with batch fluid inputs. We assume that the input traffic is observed in an interval-wise basis; that is, along the time axis divided into fixed-length intervals, with the amount of work brought into the queue during each interval sequentially observed. Since the sequence of the amounts of work during respective intervals, which is referred to as the interval-wise input process in this paper, does not reveal complete information about an input process, we cannot be precisely aware of the performance of the queue. Thus, in this paper, we focus on knowing the performance limit of the queue based on the interval-wise input process. In particular, we establish an upper limit of the long-run loss ratio of the workload in the queue. Our results would reveal useful tools to evaluate the performance of queuing systems when information about input processes in a fine timescale is not available. 相似文献
98.
Fractional Linear Multistep Methods for Abel-Volterra Integral Equations of the First Kind 总被引:1,自引:0,他引:1
Fractional powers of linear multistep methods are suggestedfor the numerical solution of weakly singular Volterra integralequations of the first kind. The proposed methods are convergentof the order of the underlying multistep method. The stabilityproperties are directly related to those of the multistep method. 相似文献
99.
We estimate the growth order in n of the Taylor coefficientsof bounded univalent functions in the unit disk. Our estimatedepends on the norm of the Grunsky operator. In particular,we improve the known results for coefficients of quasiconformallyextendible univalent functions. 1991 Mathematics Subject Classification30C50, 30C75, 30C55. 相似文献
100.