全文获取类型
收费全文 | 499篇 |
免费 | 15篇 |
国内免费 | 6篇 |
专业分类
化学 | 308篇 |
晶体学 | 8篇 |
力学 | 22篇 |
综合类 | 2篇 |
数学 | 56篇 |
物理学 | 124篇 |
出版年
2021年 | 7篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2017年 | 9篇 |
2016年 | 13篇 |
2015年 | 7篇 |
2014年 | 9篇 |
2013年 | 36篇 |
2012年 | 19篇 |
2011年 | 22篇 |
2010年 | 19篇 |
2009年 | 11篇 |
2008年 | 20篇 |
2007年 | 17篇 |
2006年 | 21篇 |
2005年 | 24篇 |
2004年 | 12篇 |
2003年 | 20篇 |
2002年 | 23篇 |
2001年 | 7篇 |
2000年 | 20篇 |
1999年 | 7篇 |
1998年 | 4篇 |
1997年 | 6篇 |
1996年 | 10篇 |
1995年 | 8篇 |
1994年 | 14篇 |
1993年 | 8篇 |
1992年 | 8篇 |
1991年 | 13篇 |
1990年 | 13篇 |
1989年 | 14篇 |
1988年 | 6篇 |
1987年 | 8篇 |
1986年 | 2篇 |
1985年 | 8篇 |
1984年 | 6篇 |
1983年 | 6篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 5篇 |
1979年 | 2篇 |
1978年 | 8篇 |
1975年 | 2篇 |
1973年 | 3篇 |
1972年 | 2篇 |
1964年 | 3篇 |
1955年 | 2篇 |
1927年 | 2篇 |
1925年 | 2篇 |
排序方式: 共有520条查询结果,搜索用时 0 毫秒
31.
Amelia P. Rauter José A. Figueiredo Isabel Ismael Maria S. Pais António G. Gonzalez Jesus Diaz 《Journal of carbohydrate chemistry》2013,32(2):259-272
Abstract Synthesis of stereoisomeric α-methylene-γ-lactones in furanose-and furanuronoamide derivatives was easily accomplished by Reformatsky Reaction with ethyl bromcmethylacrylic ester and zinc. Pyridinium chlorochromate/3Å molecular sieve powder showed to be an excellent reagent for the oxidation of secondary hydroxyl groups of a furanose system and of α-hydroxy amides. 相似文献
32.
Lauro Figueroa-Valverde Diaz Cedillo Francisco Lopez-Ramos Maria Rosas-Nexticapa Marcela Mateu-Armand Virginia Lopez-Gutierrez Tomas Alvarez-Ramirez Magdalena 《Journal of heterocyclic chemistry》2021,58(5):1154-1163
For several years ago, several epoxide derivatives have been prepared using different methods; however, some protocols use reagents which could be expensive and require specials conditions. The aim of this investigation was to prepare two new epoxide-derivatives from 3-ethynylaniline using some reactions such as oximation, acetylation, 2 + 2 addition, functionalized chloroamides, and epoxidation via Darzens reaction. The chemical characteristics of epoxide derivatives were determinate through a spectroscopic and spectrometric analysis. In conclusion, it is noteworthy that the reactions used in this study do not involve expensive reagents or special conditions for the synthesis of epoxide derivatives. 相似文献
33.
Franco Cristiani Francesco A. Devillanova Angelo Diaz Francesco Isaia Gaetano Verani 《Heteroatom Chemistry》1990,1(5):363-367
Using a series of N-methylated thiohydantoins as substrates, the donor properties of the sulfur atom are measured by determining the stability constants (K) of their adducts with molecular iodine. The K's have been determined by recording the UV-visible spectra of several CH2Cl2 solutions with different amounts of the reagents. The experimental data fit the 1:1 adduct model for all the compounds. The K values, compared with those previously found for the unsubstituted hydantoins and with those obtained for 5-methyl-2-thiohydantoin, show that the hydrogen-bonding interaction between the NH hydrogen and the S-bonded iodine plays an important role in determining the stability of the adduct. The K values obtained for several pentaatomic rings, all containing the thioureido group HN C() NH , are discussed on the basis of the influence of the substituents at C-4 and C-5 on the donor properties of the sulfur atom. 相似文献
34.
Raúl Pérez-Ruiz Robert Fichtler Yrene Diaz Miara Matthieu Nicoul Dominik Schaniel Helfried Neumann Matthias Beller Dirk Blunk Axel G. Griesbeck Axel Jacobi von Wangelin 《Journal of fluorescence》2010,20(3):657-664
The photophysical properties of a series of structurally related 4-aminophthalimides and the corresponding 5-aminophthalic
hydrazides (luminols) are reported. Absorption, steady-state, and time-resolved fluorescence spectra of luminols exhibited
substitution, solvent, and pH dependence. Singlet lifetimes have been determined by time-resolved laser flash spectroscopy.
UV spectra in gas phase and DMSO solution were calculated by TD-DFT which revealed the existence of two low-energy excited
singlet states with strong pH-sensitivity. 相似文献
35.
J. L. Pore D. S. Cross C. Andreoiu R. Ashley G. C. Ball P. C. Bender A. S. Chester A. Diaz Varela G. A. Demand R. Dunlop A. B. Garnsworthy P. E. Garrett G. Hackman B. Hadinia B. Jigmeddorj A. T. Laffoley A. Liblong R. Kanungo B. Noakes C. M. Petrache M. M. Rajabali K. Starosta C. E. Svensson P. J. Voss Z. M. Wang J. L. Wood S. W. Yates 《The European Physical Journal A - Hadrons and Nuclei》2017,53(2):27
36.
Tercero J Diaz C Ribas J Mahía J Maestro M 《Chemical communications (Cambridge, England)》2002,(4):364-365
The new heterodinuclear complex [Cu(Me2oxpn)Ni(NO2)(tmen)](ClO4), that exhibits strong antiferromagnetic intramolecular coupling between CuII and NiII ions (ferrimagnetic behavior), shows ferromagnetic ordering at low temperature, due likely to a small canting phenomenon; it is one of the very few compounds made from isolated molecules that lead to cooperative magnetic behavior. 相似文献
37.
The stereoisomers of 7,11-dimethylheptadecane and 7-methylheptadecane have been synthesized. The key step used has been the intramolecular hydride transfer from a secondary gamma-benzyloxy group with defined absolute stereochemistry to a cation generated by Lewis acid treatment of the suitable tertiary Co(2)(CO)(6)-complexed propargylic alcohol. The application of this method provided stereochemically defined alpha-alkyl-gamma-hydroxy-acetylenes that after hydrogenation and further reductive elimination of the hydroxyl group yielded sec-alkyl hydrocarbons. 相似文献
38.
Corma A Diaz U Domine ME Fornés V 《Angewandte Chemie (International ed. in English)》2000,39(8):1499-1501
39.
Fernandez YD Gramatges AP Amendola V Foti F Mangano C Pallavicini P Patroni S 《Chemical communications (Cambridge, England)》2004,(14):1650-1651
A new approach based on self-assembly inside micelles has been individuated to prepare a system behaving as a water-operating selective fluorescent sensor for Cu2+ and Ni2+. 相似文献
40.
Hoefman M Aphecetche L Bacelar JC Delagrange H Descouvemont P Diaz J d'Enterria D van Goethem M Holzmann R Huisman H Kalantar-Nayestanaki N Kugler A Lohner H Marques FM Martinez G Messchendorp JG Ostendorf RW Schadmand S Siemssen RH Simon RS Schutz Y Timmermans R Turrisi R Volkerts M Wagner V Weller H 《Physical review letters》2000,85(7):1404-1407