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排序方式: 共有138条查询结果,搜索用时 171 毫秒
131.
A silanization procedure is used to form a layer of silicon hydride on the surface of alumina. IR and NMR data confirm the presence of the hydride on the surface. Modification of the hydride intermediate is accomplished by reaction with a terminal olefin in the presence of a transition metal catalyst to form an alkyl-bonded material. Both IR and NMR confirm the bonding of the alkyl ligand to the hydride surface. Chromatographic tests indicate reversed-phase behavior. Exposure to high concentrations of phosphate solution for an extended period resulted in no significant deterioration of the bonded phase. 相似文献
132.
An experimental investigation on the possibility of obtaining tunable, multiple wavelength output in mixture of dyes pumped by a nitrogen laser has been carried out. A great number of binary dye mixtures have been tested. Simultaneous two wavelength operation is generally possible provided the gain profiles of both dyes are neither strongly overlapped nor too widely separated. Three color emission is feasible in many mixtures, but the possible combinations are limited. A simple scheme for multiple, simultaneous wavelength tuning is presented. 相似文献
133.
The presence of heavy metals in environmental waters having an important place in the industrial waste is a major threat to viability. Heavy metals are transported to humans through the ecological cycle, damaging many tissues and organs. In recent years, agricultural and food waste can be used to remove heavy metals. At the present study, magnetically modified coffee grains which are alternative to conventional particle systems were prepared and heavy metal removal performances were investigated. The coffee grains used were magnetically modified by contact with water-based magnetic fluid. Magnetically modified coffee grains were characterized by scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) surface area analysis and electron spin resonance (ESR). Adsorption studies are made with four different heavy metal ions, namely Cu(II), Pb(II), Cd(II) and Zn(II). Adsorption isotherms were determined and heavy metal removal performance of magnetic coffee grains were investigated from synthetic waste water. 相似文献
134.
Back Cover: Enhanced Thermal Oxidation Stability of Reduced Graphene Oxide by Nitrogen Doping (Chem. Eur. J. 38/2014)
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135.
Minerva Ramírez‐Berriozabal Laura Galicia Silvia Gutiérrez‐Granados José Sandoval Cortes Pilar Herrasti 《Electroanalysis》2008,20(15):1678-1683
Uric acid (UA) was determined in the presence of ascorbic acid (AA) by using a carbon paste electrode modified superficially by a β‐cyclodextrin film (CPE/β‐CD). The surface carbon paste electrode was prepared applying a 30 cycles potential program and using a 1 M HClO4+0.01 M β‐CD electrolytic solution. The UA and AA solutions were used to evaluate the electrode selectivity and sensitivity by cyclic voltammetric and amperometric methods. In these experiments the detection limit for UA was (4.6±0.01)×10?6 M and the RSD calculated from the amperometric curves was 10%. From the data obtained it was possible to quantify UA in the urine and saliva samples. Selective detection of UA was improved by formation of an inclusion complex between β‐CD and UA. The results show that the CPE/β‐CD is a good candidate due to its selectivity and sensitivity in the UA determination in complex samples like the biological fluids. 相似文献
136.
Sandoval CA Yamaguchi Y Ohkuma T Kato K Noyori R 《Magnetic resonance in chemistry : MRC》2006,44(1):66-75
The solution structures of a number of trans-RuH(eta(1)-BH(4))[(S)-tolbinap](1,2-diamine) precatalysts [TolBINAP = 2,2'-bis(di-4-tolylphosphino)-1,1'-binaphthyl; 1,2-diamine==(S,S)- or (R,R)-1,2-diphenylethylenediamine (DPEN), ethylenediamine (EN), and (S)-1,1-di(4-anisyl)-2-isopropylethylenediamine (DAIPEN)] have been determined using 2D NMR ((1)H--(1)H DQF-COSY, (1)H--(13)C HMQC, (1)H--(31)P HSQC, and (1)H--(15)N HSQC), and a double-pulsed field-gradient spin-echo (DPFGSE) NOE technique. All the octahedral Ru complexes adopt a trans configuration with respect to the BH(4) and hydride ligands. Amine protons of trans-RuH(eta(1)-BH(4))[(S)-tolbinap](1,2-diamine) complexes undergo H/D exchange in (CD(3))(2)CDOD. This inherent high acidity, coupled with the lability and chemical properties of the BH(4) ligand, allows for precatalyst activation without the need for an added base, in contrast to trans-RuCl(2)[(S)-tolbinap](1,2-diamine) precatalysts, which require a strong base for generation of a catalytic species. The H/BH(4) complex in a 2-propanol solution is converted to catalytically active [trans-RuH{(S)-tolbinap}{(S,S)-dpen}(ROH)](+) [(RO)(ROH)(n)](-) (R = (CH(3))(2)CH), a loosely associated ion pair of the discrete (solvated) cationic fragment and anionic species. 相似文献
137.
Liu Y Sandoval CA Yamaguchi Y Zhang X Wang Z Kato K Ding K 《Journal of the American Chemical Society》2006,128(44):14212-14213
A new generation of monodentate phosphoramidite ligands bearing a primary amine moiety was found to display comparable or better efficiency than bisphosphines in the Rh-catalyzed asymmetric hydrogenation of challenging substrates, such as (Z)-methyl alpha-acetoxyacrylate or (E)-beta-aryl itaconate derivatives, affording the corresponding hydrogenation products with excellent enantioselectivities (up to >99% ee). The presence of intermolecular hydrogen bonding (HB) between two monodentate ligands in the catalyst was found to be critical for excellent catalyst performance. This finding provides a basis for design and development of further catalyst systems using this type of monodentate phosphoramidite ligands. 相似文献
138.