Theoretical Study on the Conformational Conversion of 1,3-Dioxane Inside a Capsular Host

The mechanism for the conformational conversion of 1,3-dioxane guest encapsulated inside a capsular host was theoretically investigated using semiempirical PM3 method and DFT methods. The free-state process of the conformational conversion of 1,3-dioxane was also investigated to make a comparison between the two different states using the same theory. The influences of the inner phase of the capsule on the conformational conversion of guest molecule were discussed via analyzing the comparative results. It was found that the capsular host could accommodate 1,3-dioxane within its cavity by the weak attractive interactions between host and guest, and it responds to the conformational conversion of guest by the deformation of hydrogen-bonding seam at the middle of the capsule. When entrapped in the capsule, the guest molecule undergoes the conformational conversion from chair form to twist-boat form slower than that under the free condition. The deformation of the capsule is favorable to maximize the attractive interactions between host and guest.     

Cloning, Expression and Purification of Wheat Acetyl-CoA Carboxylases CT Domain in E.coil

The entire gene of carboxyltransferase(CT) domain of acetyl-CoA carboxylase(ACCase) from Chinese Spring wheat(CSW) plastid was cloned firstly,and the 2.3 kb gene was inserted into PET28a+ vector and expressed in E.coil in a soluble state.The (His)6 fusion protein was identified by SDS-PAGE and Western blot.The recombinant protein was purified by affinity chromatography,and the calculated molecular mass(Mr) was 88000.The results of the sequence analysis indicate that the cloned gene(GeneBank accession No.EU124675) was a supplement and revision of the reported ACCase CT partial cDNA from Chinese Spring wheat plastid.The recombinant protein will be significant for us to investigate the recognizing mechanism between ACCase and herbicides,and further to screen new herbicides.     

pH 响应P(AM-co-AA)/PAAC 半互穿网络微凝胶的合成及表征

在反相微乳液体系中,合成了 pH 响应的聚丙烯酰胺(AM)-丙烯酸(AA)/聚烯丙基氯化铵(PAAC)半互穿网络(semi-IPN-P(AM-co-AA)/PAAC)微凝胶.采用 TEM、光散射及 Zeta电位对微凝胶的微观形貌及 pH 的响应行为进行测定,考察离子强度对微凝胶粒径的影响.结果表明:微凝胶的粒径约 80 nm,溶胀行为对pH及离子强度敏感,改变PAAC的含量可以得到不同PH 下响应的微凝胶.     

基于长光程技术的痕量海水营养盐自动分析仪的设计与测试

海水中可溶性的营养盐浓度是海洋监测的常规项目之一;大洋水体中的营养盐含量很低,使用传统的分光光度计难于定量测量。文章基于液芯波导长光程技术,设计了高灵敏度的痕量海水营养盐光谱分析仪。分析仪以1.02 nm的光谱分辨率实现350～900 nm光谱范围的水样吸光度连续光谱测量,并由嵌入式PC104微机自动实现了水样采集、吸光度测量和数据分析的功能。针对亚硝酸盐的测试实验结果表明,仪器检出限达到nmol·L-1的量级,比传统分光光度计的检测限提高了三个量级,且显色反应时间可缩短到3 min,能适用于大洋水体中营养盐的现场痕量分析。     

Electromagnetic Properties of YIG Polycrystalline Ceramics Fabricated by Tape-casting Method

Pure phase Y_3Fe_5O_(12) (YIG) ceramic was successfully produced by tape-casting forming process and one-step solid-state sintering method.The activation energy for densification was calculated to be 183.81 kJ/mol.Pure YIG ceramic with a relative density as high as 99.8%was fabricated.The existence of O vacancy and Fe~(2+)ions was determined by XPS and EPR spectra.The RT saturation magnetization was measured to be 28.2 emu/g,and the hysteresis loss was calculated to be smaller than 10 mJ/kg in the temperature range of 230～360 K and be as high as238.8 mJ/kg at 30 K.The dielectric loss tangent tan was nearly zero at 6～7 GHz and 11～12 GHz.For complex permeability in the frequency range of 5～18 GHz,the magnetic loss tangent tan fluctuated at around zero.Therefore,the low values of tan and tan indicate that it is a low loss ceramic material.     

Bi-2223喷雾热分解粉末热处理工艺优化

Bi-2223带材目前在电流引线、超导电机、超导电缆、超导限流器等领域实现了许多示范性应用,载流性能是表征其性能的重要指标,而高质量的前驱体粉末是最终带材性能的关键保障.本文选用具有工艺简单、粉末效率高、批次稳定性好等优点的喷雾热分解法制备的Bi-2223前驱体粉末,利用TG-DSC、XRD、SEM等测试手段对低氧条件下不同保温时间烧结的粉末进行分析,并结合最终带材的载流性能测试结果,获得了最优粉末烧结参数,为后续喷雾热分解粉末的进一步生成Bi-2223相以及高性能粉末的制备提供了依据.     

全合成法光纤预制棒制造研究

介绍了一种全新的全合成法G.655和G.656光纤制造工艺,详细分析了该工艺中芯层折射率差Δ0、芯层厚度a、第二包层的折射率差Δ2、第二包层的厚度c2等结构参量与光纤光学性能的关系.结果表明,制造该两种光纤时,Δ0应在0.012 0～0.015 5之间,Δ2应在0.014 0～0.023 0之间,a应在2.8～3.2 μm之间,c2应在满足截止波长的要求下尽可能小.     

木卫停泊轨道间低耗能小推力转移轨道设计方法研究

对木卫停泊轨道间的低耗能小推力转移轨道设计方法进行了研究,提出基于“类halo轨道截面”法的低耗能转移轨道参数化方法和基于配点法的多体Lambert问题求解算法,并利用全局优化算法得出了燃耗最少的初步优化结果;利用多体同伦法和固定近心点高度的多圈转移控制律得到了各段小推力转移轨道的有效设计结果.所提方法同样适用于其他天体间的转移轨道设计,为多体环境下低耗能小推力转移轨道提出了新的设计思路和方法.     

静电纺丝法制备柔性SERS基底及性能研究

利用静电纺丝技术制备了聚乙烯醇(PVA)/银纳米粒子高活性SERS柔性基底。将硝酸银、聚乙烯醇按照一定比例混合配置纺丝溶液,纺丝成膜后采用紫外光照射还原法得到纳米纤维基底。采用扫描电子显微镜(SEM),透射电子显微镜(TEM),傅立叶红外光谱(FT-IR),拉曼光谱(Raman),紫外可见光谱(UV-Vis)等技术,对合成的纳米纤维基底进行表征。研究表明,银纳米颗粒呈球形分布在复合纤维中,粒径小于10 nm。以罗丹明为探针分子,硝酸银含量16wt%,紫外光照射3 h制备的基底具备最优的SERS性能。同时将此基底应用于烟酸药品检测,拉曼检测极限可达10^-5 mol·L^-1。     

油酸钠改性无水硫酸钙晶须及其机理研究

采用油酸钠改性无水硫酸钙晶须(AW),既可以增强无水硫酸钙晶须的疏水性,又可以在晶须表面引入-C=C-增加其功能性。利用晶须在甲基丙烯酸甲酯(MMA)的分散性能探究油酸钠加量、时间、改性温度等因素对改性效果的影响;采用XRD、XPS和DRIFTS探索晶须的吸附及改性机理、Washburn法测定晶须的疏水性能。结果表明随油酸钠用量的增加,分散性能先变好后变差,油酸钠与晶须质量比为1∶100时,沉降高度和沉降速度由油酸钠与晶须质量比为1∶200时的3.1 cm和0.31 cm/min大幅增加到10.6 cm和1.06 cm/min;分散性能开始出现突变时的油酸钠用量随温度升高而增加;DRIFTS表明油酸钠中的油酸根离子主要以物理吸附和化学吸附的方式与钙离子结合存在于晶须表面,其特征吸收峰分别是1 577 cm^-1和1 540 cm^-1的双峰和1 547 cm^-1的单峰;改性后的晶须疏水性较改性前大幅增加,与水的接触角从改性前的0.04°增加到改性后的77.35°。