Convenient Microwave-Assisted Chlorosulfonic Acid-Catalyzed Synthesis of Some Quinazolinones from 2-Phenylindole

Russian Journal of Organic Chemistry - A new convenient method has been developed for the synthesis of quinazolinones from 2-phenyl-1H-indole and substituted amines under catalysis by...     

Comparison of the Reactivities of Tyrosine–Proline-Based Dipeptides toward Acylation with Nitrophenyl Benzoates

Russian Journal of Organic Chemistry - The reactivities of the L-Tyr–L-Pro dipeptide and its analog with a hydroxymethyl group instead of carboxy group in the proline moiety were compared by...     

Synthesis and properties of novel 4-(diarylmethyl)pyridines based on pyridoxal 5′-phosphate

Russian Chemical Bulletin - The reaction pyridoxal 5′-phosphate with resorcinols in EtOH in the presence of concentrated HCl gives hydrochlorides of the corresponding...     

Synthesis and study of thioglycoside conjugates of 4-chloro-1,2-dithiol-3-one as potential cancer-preventive substances in vitro and in vivo

Russian Chemical Bulletin - Nucleophilic substitution of the chlorine atom in 4,5-dichloro-1,2-dithiol-3-one using 1-thio-β-d-glucopyranose and its 2,3,4,6-tetra-O-acetyl derivative in...     

On the Thermodynamics of Hydrogen Adsorption at Pt Electrodes

Russian Journal of Electrochemistry - In the mid 1960th–early 1970th, A. Frumkin and O. Petrii investigated the adsorption of hydrogen at a platinized platinum electrode surface performing...     

Biradical with a polyfluorinated terphenylene backbone

Russian Chemical Bulletin - A method was developed for the synthesis of perfluoro-1,1′:4′,1″-terphenyl by the reaction of chloroperfluorobenzene with zinc dust followed by the...     

Synthesis and study of interconversions of new indoline spiropyrans based on 4-hydroxy-3,5-diformylbenzoic acid

The synthesis of new indoline spiropyran by the cyclocondensation in methanol revealed that the free aldehyde group of the target spiropyran is easily converted into the dimethyl acetal moiety without the addition of an acid catalyst, giving 8′-dimethoxymethyl-1,3,3-trimethylspiro[indoline-2,2′-2H-chromene]-5,6′-dicarboxylic acid as a single reaction product. The structure of this compound was confirmed by NMR spectroscopy and mass spectrometry. The molecular structure was also established by single-crystal X-ray diffraction. The Hirshfeld surfaces were generated and analyzed and intermolecular interactions in the crystal were investigated using the CrystalExplorer software package. The reverse hydrolysis reaction of dimethyl acetal to the aldehyde group proceeds under mild conditions in dimethyl sulfoxide, as shown by NMR spectroscopy.

     

Synthesis and Antitumor Activity of 5-Phenyl-1,3-thiazole-4-sulfonamide Derivatives

Russian Journal of General Chemistry - A method for the synthesis of 5-phenyl-1,3-thiazole-4-sulfonyl chloride was developed based on the cyclization of ethyl...     

Phosphine-Catalyzed Reactions of Imides and Hydrophosphoryl Compounds Addition to Divinyl Sulfone

Russian Journal of General Chemistry - An efficient method for the phosphine-catalyzed bisaddition of P(O)H compounds and cyclic imides to divinyl sulfone has been developed. The reaction proceeds...     

Reaction of alkyl 3-bromo-3-nitroacrylates with substituted hydrazines. Synthesis of N′-substituted alkyl 3-nitropyruvate hydrazones

Russian Chemical Bulletin - The reaction of alkyl 3-bromo-3-nitroacrylates with substituted phenylhydrazines and hydrazides of aromatic acids proceeds through the formation of aza-Michael adducts....