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981.
A practical Sonogashira alkynylation protocol for the preparation of 8-alkynylated adenosines and guanosines has been developed. Protection of the sugar hydroxyl substituents is not required; protection hinders the purification of these products. A preliminary fluorescent study is reported, which shows that the presence of a substituent on the phenylene ring influences the fluorescent properties considerably, an outcome that could be utilized in biological applications. 相似文献
982.
A three-dimensional molecular dynamics (MD) model is utilized to investigate the effect of tool geometry on the deformation process of the workpiece and the nature of deformation process at the atomic-scale. Results show that different states exist between the atomic force microscope (AFM) pin tool and the workpiece surface, i.e. the non-wear state, the ploughing state, the state in which ploughing is dominant and the state in which cutting plays a key role. A relationship between the deformation process of the workpiece and the potential energy variation is presented. The potential energy variation of atoms in different deformed regions in the workpiece such as plastically deformed region, elastically deformed region and the mixed deformation region is different. The features of variations of potential energy are discussed. 相似文献
983.
N. S. Simonović 《Few-Body Systems》2006,38(2-4):139-145
In agreement with the Kohn theorem the relative motion (rel) of three electrons in a two-dimensional parabolic trap separates
from the centre-of-mass (CM) motion. By introducing new coordinates the Hamiltonian for relative motion in the approximation
of non-interacting electrons can be taken to the normal form. The eigenstates of the normalized Hamiltonian are products of
the Fock-Darwin states for normal modes. The energy levels for relative motion are obtained by diagonalizing the exact Hamiltonian
in the eigenbasis for the non-interacting case. In this basis the interaction matrix elements can be obtained in the analytical
form. Since the rank of the Hamiltonian matrix is significantly reduced, the calculations are faster and more accurate than
those for the full (CM + rel) motion. This advantage is especially important for the calculations of excited states and the
analysis of energy spectra. 相似文献
984.
A.Y. El-Etre 《Applied Surface Science》2006,252(24):8521-8525
The inhibitive effect of the extract of khillah (Ammi visnaga) seeds, on the corrosion of SX 316 steel in HCl solution was determined using weight loss measurements as well as potentiostatic technique. It was found that the presence of the extract reduces markedly the corrosion rate of steel in the acid solution. The inhibition efficiency increases as the extract concentration is increased. The inhibitive effect of khillah extract was discussed on the basis of adsorption of its components on the metal surface. Negative values were calculated for the energy of adsorption indicating the spontaneity of the adsorption process. The formation of insoluble complexes as a result of interaction between iron cations and khellin, which present in the extract, was also discussed. 相似文献
985.
A. G. Bratsos 《Numerical Algorithms》2006,43(4):295-308
A three-time level finite-difference scheme based on a fourth order in time and second order in space approximation has been
proposed for the numerical solution of the nonlinear two-dimensional sine-Gordon equation. The method, which is analysed for
local truncation error and stability, leads to the solution of a nonlinear system. To avoid solving it, a predictor–corrector
scheme using as predictor a second-order explicit scheme is proposed. The procedure of the corrector has been modified by
considering as known the already evaluated corrected values instead of the predictor ones. This modified scheme has been tested
on the line and circular ring soliton and the numerical experiments have proved that there is an improvement in the accuracy
over the standard predictor–corrector implementation.
This research was co-funded by E.U. (75%) and by the Greek Government (25%). 相似文献
986.
Steven D. Bull Simon W. Epstein Nadeam Mujtaba Edward D. Savory Juan A. Tamayo 《Tetrahedron》2006,62(33):7911-7925
Enolates of (S)-N,N′-bis-(p-methoxybenzyl)-3-iso-propylpiperazine-2,5-dione exhibit high levels of enantiodiscrimination in alkylations with (RS)-1-aryl-1-bromoethanes and (RS)-2-bromoesters, affording substituted diketopiperazines containing two new stereogenic centres in high de. Deprotection and hydrolysis of the resultant substituted diketopiperazines provides a route to the asymmetric synthesis of homochiral methyl 2-amino-3-aryl-butanoates and 3-methyl-aspartates in high de and ee. 相似文献
987.
G. Giorgadze 《Journal of Mathematical Sciences》2006,132(6):716-738
We discuss a number of topics concerned with certain boundary-value problems in the context of generalized analytic functions.
Solution of the classical Riemann-Hilbert problem and the linear conjugation problem for analytic functions is described in
appropriate function classes and the same scheme is applied to generalized analytic functions and vectors. In particular,
we describe solution of the Riemann-Hilbert problem for generalized analytic functions and obtain an explicit analytic presentation
of monodromy matrices in the case of generalized analytic vectors.
__________
Translated from Sovremennaya Matematika i Ee Prilozheniya (Contemporary Mathematics and Its Applications), Vol. 15, Theory
of Functions, 2004. 相似文献
988.
On Quantum Team Games 总被引:2,自引:0,他引:2
E. Ahmed M. F. Elettreby A. S. Hegazi 《International Journal of Theoretical Physics》2006,45(5):880-886
Recently Liu and Simaan (2004) convex static multi-team classical games have been introduced. Here they are generalized to both nonconvex, dynamic and quantum games. Puu's incomplete information dynamical systems are modified and applied to Cournot team game. The replicator dynamics of the quantum prisoner's dilemma game is also studied. 相似文献
989.
V. V. Zhikov 《Journal of Mathematical Sciences》2006,132(3):285-294
We study the problem on density of smooth functions in Sobolev spaces of variable orders, also called Sobolev-Orlicz spaces.
In particular, we generalize the earlier obtained logarithmic condition and give a number of examples. Bibliography: 9 titles.
__________
Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 310, 2004, pp. 67–81. 相似文献
990.
We present the design and study of waveguide structures based on porous silicon where the light confinement is not due to the usual total reflection effect but to the use of photonic crystals (PCs) as confining walls. These PC are omnidirectional mirrors (OMs), consisting of the periodic repetition of two porous silicon layers with different refractive indices and thicknesses. They reflect the radiation for all angles of incidence within a frequency range called the omnidirectional band gap (OBG). We have followed the PC formalism to investigate the properties of the OM as a multimode waveguide: the number of modes within the band gap, their field spatial distribution and their confinement as a function of the frequency and the core thickness. 相似文献