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911.
We study two estimators of the long-range parameter of a covariance stationary linear process. We show that one of the estimators
achieve the optimal semiparametric rate of convergence, whereas the other has a rate of convergence as close as desired to
the optimal rate. Moreover, we show that the estimators are asymptotically normal with a variance, which does not depend on
any unknown parameter, smaller than others suggested in the literature. Finally, a small Monte Carlo study is included to
illustrate the finite sample relative performance of our estimators compared to other suggested semiparametric estimators.
More specifically, the Monte-Carlo experiment shows the superiority of the proposed estimators in terms of the Mean Squared
Error.
The first author research was funded by the Economic and Social Research Council (ESRC) reference number: R000238212. The
second author research was funded by the Ministry of Education, Culture, Sports and Technology of Japan, reference number:
09CE2002 and B(2)10202202. 相似文献
912.
Effect of anions on the phase stability of γ-FeOOH nanoparticles and the magnetic properties of gamma-ferric oxide derived from lepidocrocite 总被引:1,自引:0,他引:1
C. Sudakar 《Journal of Physics and Chemistry of Solids》2003,64(12):2337-2349
The effect of anions such as Cl−, SO42−, and HPO42− on the phase stability of FeOOH (α or γ) during precipitation is investigated. Oxidation of Fe(OH)2·xH2O from FeCl2 solution with high Cl− concentration ([Cl−]/[Fe]=RCl≥8) or (NH4)2Fe(SO4)2 (FAS) with [HPO42−]/[Fe]=RP≥0.02 yields phase-pure γ-FeOOH. In the medium ranges of RCl and RP, mixed phases of α-FeOOH and γ-FeOOH are obtained. Replacement of OH− by Cl− with the bridging cations or strongly bonded HPO42− ions in the matrix of the intermediate phase (Fex2+Fey3+(OH)2x+2y−nz·xH2O(A)zn−, where A is anions such as Cl−, SO42−, HPO42−, etc.), promoted the lower density γ-FeOOH. However, the particles are less developed and have poor crystallinity as evidenced from transmission electron microscope and thermogravimetry-differential thermal analysis of the precipitates. Whereas, monophasic, uniformly sized, nano-lath shaped particles with high aspect ratio >10 are obtained when morphology-controlling cation additives such as Pt4+, Pd2+ or Rh3+ are present in FeCl2 (RCl≥8) solution. Preferential adsorption of additives on (0k0) and (h00) planes limits the growth in the perpendicular directions leading to high aspect ratios. The effect of these additives are suppressed by the phosphate ion, a strong complexing ligand, giving rise to fibrous aggregate with the length of individual particles as small as 10-30 nm. While most of the Cl− ion is removed from the final precipitates on washing, phosphate remained as HPO42− as evidenced from IR absorption spectra. Maghemite obtained by dehydroxylating γ-FeOOH contains randomly distributed micropores bringing in the relaxation effects of spins on the surface atoms as deciphered from Mössbauer spectroscopy. This leads to the low σs (44-48 emu/g) and Hc (120-130 Oe) for γ-Fe2O3−δ particles. Whereas nearly pore-free single crystalline particles obtained by reduction followed by reoxidation has high value of σs (73 emu/g) and Hc (320 Oe), which decreases to 30 emu/g and 75 Oe, respectively, for nanoparticles obtained from phosphate stabilized lepidocrocite. The mobility of iron ions and counter mobility of vacancies during the topotactic transformation of γ-FeOOH to magnetite to γ-Fe2O3−δ renders the particles pore-free. 相似文献
913.
T. Ramanathan S. Stankovich D. A. Dikin H. Liu H. Shen S. T. Nguyen L. C. Brinson 《Journal of Polymer Science.Polymer Physics》2007,45(15):2097-2112
Mechanical, thermal, and electrical properties of graphite/PMMA composites have been evaluated as functions of particle size and dispersion of the graphitic nanofiller components via the use of three different graphitic nanofillers: “as received graphite” (ARG), “expanded graphite,” (EG) and “graphite nanoplatelets” (GNPs) EG, a graphitic materials with much lower density than ARG, was prepared from ARG flakes via an acid intercalation and thermal expansion. Subsequent sonication of EG in a liquid yielded GNPs as thin stacks of graphitic platelets with thicknesses of ~10 nm. Solution‐based processing was used to prepare PMMA composites with these three fillers. Dynamic mechanical analysis, thermal analysis, and electrical impedance measurements were carried out on the resulting composites, demonstrating that reduced particle size, high surface area, and increased surface roughness can significantly alter the graphite/polymer interface and enhance the mechanical, thermal, and electrical properties of the polymer matrix. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2097–2112, 2007 相似文献
914.
915.
A. V. Porfir’eva G. A. Evtyugin E. Yu. Podshivalina L. I. Anchikova G. K. Budnikov 《Journal of Analytical Chemistry》2007,62(12):1180-1186
A new technique is proposed for detecting interactions between DNA and DNA autoimmune antibodies using a potentiometric sensor based on a glassy-carbon electrode modified with polyaniline and native DNA from chicken erythrocytes. It is shown that the DNA-antibody interaction changes the rate of polyaniline doping in transferring the DNA sensor from an alkaline (pH 7.5) solution, which is optimum for the immunochemical reaction, to an acidic (pH 3.0) solution. The dynamics of the variation of the DNA sensor potential depends on the titer of antibodies and their origin. The dependence of the DNA sensor signal on the dilution of the blood sera from systemic lupus erythematosus and autoimmune thyroiditis patients shows that DNA antibodies can be diagnosed by the characteristic maximum in the dilution curve found in the range of serum dilutions from 1: 20 to 1: 50. 相似文献
916.
B. Velázquez-Martí C. Gracia-López 《International Journal of Infrared and Millimeter Waves》2004,25(7):1109-1122
The thermal treatment by millimeter waves for the soil disinfection can be one possible alternative to chemical treatments. This physical method is based on incrementing the soil temperature and its pathogens irradiating with high frequency electromagnetic waves. So the previous knowledge of the temperature distribution in the irradiated soil is essential for achieving an effective bad microorganism and weed seeds elimination. This report analyse the heating kinetic and spatial distribution of the maximum temperatures reached by the soil. It is presented a mathematic model about how are distributed the reached temperatures in the depth of the irradiated soil. This model concludes that when an orchard soil is irradiated superficially by microwaves, the microwaves have a big attenuation due to the soil dielectric properties and the water located in the pores of the most superficial layer. This fact causes a shield effect blocking the waves penetration in few centimetres. The heating by radiation is reduced to the superficial layer. The heating propagation in the depth is occurred by conduction following the Fourier equations. 相似文献
917.
Natural convections in conjugated single and double enclosures 总被引:7,自引:0,他引:7
The natural convection in single and double conjugated enclosures are numerically investigated. The single and double enclosures are formed by low conductance walls with finite thickness. The outside vertical surfaces of the conducting walls are of the third kind of boundary condition while the top and bottom outside surfaces are adiabatic. The problem studied is characterized by a dominant horizontal temperature gradient and the thermal boundary conditions at the cavity surfaces can not be specified in priori. Numerical results reveal the characteristics in such kind of enclosures and show the importance of the thermal boundary conditions on the natural convection in enclosures. It is also found that the natural convections in the conjugated double enclosures are basically the same, with a major difference in their fluid temperature levels. 相似文献
918.
D. V. Treschev 《Proceedings of the Steklov Institute of Mathematics》2007,259(1):196-235
We propose a method for constructing noncommutative analogs of objects from classical calculus, differential geometry, topology,
dynamical systems, etc. The standard (commutative) objects can be obtained from noncommutative ones by natural projections
(a set of canonical homomorphisms). The approach is ideologically close to the noncommutative geometry of A. Connes but differs
from it in technical details. 相似文献
919.
Martin I. Karakhanyan 《Journal of Contemporary Mathematical Analysis (Armenian Academy of Sciences)》2007,42(3):146-150
The paper proves some general facts on commutators that refer to Fuglede-Putnam classical theorem in the spectral theory of not necessarily selfadjoint operators. 相似文献
920.
V. I. Maslov 《Russian Physics Journal》2007,50(5):425-428
An abrupt rise of the field electron emission (FEE) current from a high-temperature superconductor (HTSC) being in the normal
state has been detected. The current amplification with a factor reaching ∼106 occurs as an HTSC emitter is heated in the temperature range 110–170 K. The features of the temperature dependence of FEE
are discussed. Measured parameters of the effect observed are presented. Possible mechanisms of the process under consideration
are discussed.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 13–16, May, 2007. 相似文献