全文获取类型
收费全文 | 273470篇 |
免费 | 2029篇 |
国内免费 | 738篇 |
专业分类
化学 | 127266篇 |
晶体学 | 3991篇 |
力学 | 14542篇 |
综合类 | 7篇 |
数学 | 42170篇 |
物理学 | 88261篇 |
出版年
2021年 | 991篇 |
2020年 | 1112篇 |
2019年 | 1127篇 |
2018年 | 10440篇 |
2017年 | 11407篇 |
2016年 | 6533篇 |
2015年 | 2844篇 |
2014年 | 2609篇 |
2013年 | 7819篇 |
2012年 | 10749篇 |
2011年 | 20842篇 |
2010年 | 12436篇 |
2009年 | 12586篇 |
2008年 | 18258篇 |
2007年 | 21895篇 |
2006年 | 7208篇 |
2005年 | 13883篇 |
2004年 | 9558篇 |
2003年 | 8563篇 |
2002年 | 6394篇 |
2001年 | 6188篇 |
2000年 | 4866篇 |
1999年 | 3515篇 |
1998年 | 2671篇 |
1997年 | 2632篇 |
1996年 | 2743篇 |
1995年 | 2370篇 |
1994年 | 2244篇 |
1993年 | 2100篇 |
1992年 | 2405篇 |
1991年 | 2379篇 |
1990年 | 2090篇 |
1989年 | 2076篇 |
1988年 | 2108篇 |
1987年 | 2040篇 |
1986年 | 1945篇 |
1985年 | 2859篇 |
1984年 | 2850篇 |
1983年 | 2296篇 |
1982年 | 2473篇 |
1981年 | 2355篇 |
1980年 | 2312篇 |
1979年 | 2277篇 |
1978年 | 2355篇 |
1977年 | 2228篇 |
1976年 | 2194篇 |
1975年 | 2168篇 |
1974年 | 2068篇 |
1973年 | 2190篇 |
1972年 | 1232篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
The magnetic and electric properties of the Sr2FeMoO6 compound produced under different preparation conditions were studied. Depending on the preparation condition, a strong variation in the nonmagnetic SrMoO4 impurity content was found, which in turn determined the metallic or semiconducting behavior of the resistivity of the Sr2FeMoO6 compound. There was also evidence that SrMoO4 played a crucial role in modifying the low magnetic field intergrain tunneling magnetoresistance in Sr2FeMoO6. In addition, we have established a simple method to prepare the single phase Sr2FeMoO6 polycrystals. 相似文献
992.
Auvergne R. Saint‐Loup R. Joly‐Duhamel C. Robin J. J. Boutevin B. 《Journal of polymer science. Part A, Polymer chemistry》2007,45(7):1324-1335
The synthesis and characterization of photopolymerizable unsaturated polyester resins based on PET waste are described. The resins came from a depolymerization process based on the glycolysis of PET by diethylene glycol (DEG). Different molecular weights of glycolysates were synthesized. Then, the latter was functionalized by a methyl hemiester of maleic acid to obtain unsatured α,ω‐bismaleate PET oligomers. In the presence of an electron donor monomer, such as triethylene glycol divinyl ether, these electron acceptor oligomers were copolymerized by way of charge‐transfer complexes under UV irradiation. The reaction was monitored in situ by real‐time IR spectroscopy to study the kinetics of photopolymerization. This one was studied in relation with the physical and chemical characteristics of oligoesters and the composition of mixtures containing divinyl ethers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1324–1335, 2007 相似文献
993.
Christopher K. Yee‐Chan Robert C. Scogna Richard A. Register 《Journal of Polymer Science.Polymer Physics》2007,45(10):1198-1204
In the idealized two‐phase model of a semicrystalline polymer, the amorphous intercrystalline layers are considered to have the same properties as the fully‐amorphous polymer. In reality, these thin intercrystalline layers can be substantially influenced by the presence of the crystals, as individual polymer molecules traverse both crystalline and amorphous phases. In polymers with rigid backbone units, such as poly(etheretherketone), PEEK, previous work has shown this coupling to be particularly severe; the glass transition temperature (Tg) can be elevated by tens of degrees celsius, with the magnitude of the elevation correlating directly with the thinness of the amorphous layer. However, this connection has not been explored for flexible‐chain polymers, such as those formed from vinyl‐type monomers. Here, we examine Tg in both isotactic polystyrene (iPS) and syndiotactic polystyrene (sPS), crystallized under conditions that produce a range of amorphous layer thicknesses. Tg is indeed shown to be elevated relative to fully‐amorphous iPS and sPS, by an amount that correlates with the thinness of the amorphous layer; the magnitude of the effect is severalfold less than that in PEEK, consistent with the minimum lengths of polymer chain required to make a fold in the different cases. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1198–1204, 2007 相似文献
994.
We give a review and a comparison of recent methods of analyzing circular and noncircular optical waveguides. Comparison among competing methodologies is made as follows: Galerkin's method is used with Laguerre-Gauss basis functions in circular geometry to examine the modal solution in a step index fiber, and comparison with the exact solution is made. A W-fiber, which has no exact solution, is then examined. Rectangular geometry is considered, and discussion centers on the use of Galerkin's method using trigonometric basis functions and Hermite-Gauss basis functions. Re difficulty arising from the use of basis functions that do not decay exponentially for large argument (trigonometric functions) is illustrated. Finally, a square step index waveguide is used to illustrate a comparison between a variational method that uses the Gaussian approximation as the starting point, and Galerkin's method using Hermite-Gauss basis functions. We conclude that the variational method does well in predicting the propagation constant β but does not do well in predicting the modal field. 相似文献
995.
C. Saragovi F. Labenski S. M. Duhalde S. Acebal R. Venegas 《Hyperfine Interactions》1994,91(1):765-769
Clay fractions of a Mollisol sample as is, treated with ammonium oxalate (AO), with dithionite-citrate-bicarbonate (DCB) and with dithionite-ethilene-diamine-tetraacetic acid (D-EDTA) methods, were studied. Illite-montmorillonites together with hematites, goethites and maghemites, all of the AI-substituted and with a wide range of sizes, were identified. It is found that the AO attack extracts little iron, whereas the other two attacks extract the magnetic signal. Furthermore, the DCB attack facilitates the reduction of the Fe3+ ions, while the D-EDTA method does not. Instead, this attack extracts more clay mineral Fe ions. A comparison with large grain soil samples is made. 相似文献
996.
The Borel-Weil (BW) construction for unitary irreps of a compact Lie group is extended to a construction of all unitary irreps of the quantum groupU
q(n). Thisq-BW construction uses a recursion procedure forU
q(n) in which the fiber of the bundle carries an irrep ofU
q(n–1)×U
q(1) with sections that are holomorphic functions in the homogeneous spaceU
q(n)/U
q(n–1)×U
q(1). Explicit results are obtained for theU
q(n) irreps and for the related isomorphism of quantum group algebras.Supported in part by the National Science Foundation, No. PHY-9008007 相似文献
997.
Granular films prepared from well-defined In clusters embedded in Kr (? 10-40 at % Kr) show sharp resistance anomalies very close to the superconducting transition temperature. The observed resistance peak(s), which go(es) above the normal state resistance RN and which can be as high as ? 1.5 RN, can be explained by a “mesoscopic” effect: Superconducting percolation aggregates of size ξρ, larger than the superconducting coherence length ξS, but smaller than the quasiparticle relaxation length λQ*, have a superconducting gap, but are not yet able to carry a supercurrent. 相似文献
998.
What is the maximum number of unit distances between the vertices of a convex n-gon in the plane? We review known partial results for this and other open questions on multiple occurrences of the same interpoint distance in finite planar subsets. Some new results are proved for small n. Challenging conjectures, both old and new, are highlighted. 相似文献
999.
R. C. Batra 《Journal of Elasticity》1987,17(1):3-8
It is shown that the force on a lattice defect in an elastic body is, like the force on a disclination in a nematic liquid crystal, a real force which, for equilibrium, must be balanced by an external force applied to the closed surface enclosing the defect. 相似文献
1000.
C. Jeyaprabha 《Applied Surface Science》2005,252(4):966-975
The inhibitor performance of chemically synthesized water soluble poly(aminoquinone) (PAQ) on iron corrosion in 0.5 M sulphuric acid was studied in relation to inhibitor concentration using potentiodynamic polarization and electrochemical impedance spectroscopy measurements. On comparing the inhibition performance of PAQ with that of the monomer o-phenylenediamine (OPD), the OPD gave an efficiency of 80% for 1000 ppm while it was 90% for 100 ppm of PAQ. PAQ was found to be a mixed inhibitor. Besides, PAQ was able to improve the passivation tendency of iron in 0.5 M H2SO4 markedly. 相似文献