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751.
Probing the response of soft materials at small scales requires examining fundamental behaviors that are often distinct from large-scale interactions. In the development of micrometer- and nanometer-sized holes in soft materials, understanding failure modes becomes essential. We observe fracture behavior in a soft material through a novel method, which leads to the fabrication of small-scale holes in polydimethylsiloxane. We utilize an ultra-sharp tungsten needle to drill this soft elastomeric polymer; this results in controlled hole size and exhibits fracture characteristics observed in brittle materials at larger length scales. We also examine the macroscopic characteristics known to contribute to brittleness and hardness for this material’s response with respect to curing times. This understanding will contribute to many applications including the development of porous materials and DNA sequencing efforts. PACS 81.05.Lg; 81.40.Np; 82.35.Lr 相似文献
752.
The impedance spectra of Pb5Ge3O11 single crystals are measured in the frequency range from 5 Hz to 13 MHz at temperatures of 600 to 800 K in dry air and in
a dry or wet nitrogen gas. It is found that the temperature and the gas composition significantly affect the electrical properties
of the compound. The data obtained are used to discuss the origin of crystal lattice defects and their influence on charge
transfer. It is concluded that the conduction is mixed in character (p-type electronic and ionic due to oxygen ions). The proton conduction is shown experimentally to be feasible. The possible
mechanisms of proton transport in Pb5Ge3O11 are discussed. 相似文献
753.
J. Gañán J.F. González C.M. González-García A. Ramiro E. Sabio S. Román 《Applied Surface Science》2006,252(17):5988-5992
In this work the results obtained in the preparation and characterization of carbons made from almond tree pruning by non-catalytic and catalytic gasification (using K and Co) with air are analyzed and discussed. The main aim was to obtain high quality activated carbons at the lowest possible cost. The variables studied have been the temperature (190-260 °C) and the time (1-10 h) in non-catalytic gasification and the influence of the catalyst type (K and Co, 1 wt.% referred to cation, at 190 °C and 1 h) and the time (1-4 h) in catalytic gasification with Co at 190 °C. The air flow rate used in all the series was 167 cm3 min−1. In non-catalytic gasification the reaction normalized rate versus the conversion degree was maintained until a conversion value of 10% for the experiment made at 260 °C since, at lower temperatures, this rate drops quickly for low conversion values. The N2 adsorption isotherms for the carbons of this series resemble type I, although there is an increase of N2 adsorbed volume at relatively high pressures. A temperature rise produced an increase of the carbon porosity and BET specific surface (116-469 m2 g−1). The activation time has a positive effect on the N2 volume adsorbed by the carbons. The isotherms shapes were similar to those previously commented. A concentration equal to 1 wt.% was used to study the influence of the catalyst type. Under the studied experimental conditions, Co drives to a bigger porosity development than K, although with both catalysts a very similar pore size distribution is obtained. The activation time, in the gasifications catalyzed with Co, gives rise to a very important porosity development in the carbons. This produces a strong increase of the carbon specific surface area with very high values in the 4 h experiment, in which a BET specific surface of 959 m2 g−1 was obtained. 相似文献
754.
Highly ordered composite nanowires with multilayer Ni/Cu and NiFe/Cu have been fabricated by pulsed electrodeposition into
nanoporous alumina membrane. The diameter of wires can be easily varied by pore size of alumina, ranging from 30 to 100 nm.
The applied potential and the duration of each potential square pulse determine the thickness of the metal layers. The nanowires
have been characterized by transmission electron microscopy (TEM), magnetic force microscopy (MFM), and vibrating sample magnetometer
(VSM) measurements. The MFM images indicate that every ferromagnetic layer separated by Cu layer was present as single isolated
domain-like magnet. This technique has potential use in the measurement and application of magnetic nanodevices. 相似文献
755.
John C. Baez 《Foundations of Physics》1989,19(1):91-95
E. P. Wigner's argument that the probability of the existence of self-reproducing units, e.g., organisms, is zero according to standard quantum theory is stated and analyzed. Theorems are presented which indicate that Wigner's mathematical result in fact should not be interpreted as asserting the improbability of self-reproducing units. 相似文献
756.
757.
758.
Mitre C. Dourado Fábio Protti Jayme L. Szwarcfiter 《Discrete Applied Mathematics》2007,155(18):2435-2443
Let p?1 and q?0 be integers. A family of sets F is (p,q)-intersecting when every subfamily F′⊆F formed by p or less members has total intersection of cardinality at least q. A family of sets F is (p,q)-Helly when every (p,q)-intersecting subfamily F′⊆F has total intersection of cardinality at least q. A graph G is a (p,q)-clique-Helly graph when its family of (maximal) cliques is (p,q)-Helly. According to this terminology, the usual Helly property and the clique-Helly graphs correspond to the case p=2,q=1. In this work we present a characterization for (p,q)-clique-Helly graphs. For fixed p,q, this characterization leads to a polynomial-time recognition algorithm. When p or q is not fixed, it is shown that the recognition of (p,q)-clique-Helly graphs is NP-hard. 相似文献
759.
The FRS-ESR facility at GSI provides one of the most efficient methods for direct mass measurements. In the present experiment,
exotic nuclei were produced via fragmentation of 152Sm projectiles in a thick beryllium target at 500-600 MeV/u, separated in-flight with the fragment separator FRS, and injected
into the storage-cooler ring ESR. Time-resolved Schottky Mass Spectrometry was applied for mass measurements of stored and
electron-cooled bare and few-electron ions. 373 different nuclides were identified by means of the spectra of their revolution
frequencies. Masses for 18 nuclides (84Zr, 92Ru, 94Rh, 107,108,110Sb, 111,112,114I, 118Ba, 122,123La, 124Ce, 127Pr, 129Nd, 132Pm, 134Sm, 137Eu) have been determined for the first time. Masses for 111,112I and 113Xe have been obtained via known α-decay energies. The experiment and first results will be presented. 相似文献
760.
T. C. Devore 《Journal of Molecular Structure》1987,162(3-4):287-304
Fourier transform infrared spectroscopy has been used to investigate the IR spectra of the XNCO (X = Cl, Br, I, CN), the XSCN (X = Cl, Br, I) and the NCNCS vapor molecules from 4800 to 400 cm−1. Vibrational frequencies have been determined for each normal mode of vibration in each molecule in this region. 相似文献