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221.
222.
The effect of iodine sorption on the free volume of polycarbonate is investigated by Positron Annihilation Lifetime method.
The observed results are interpreted in terms of the Charge Transfer Complex formation and precipitation of iodine at the
initial and final stages of sorption, respectively. At higher levels of sorption, changes in the second lifetime and its intensity
seem to suggest a conformational transformation, probably due to the net change in the amorphous-crystalline boundary regions
of the polymer matrix. The free volume cavities have been predominantly occupied by I-
3 species and the diffusion process obeys Fick’s law. An exponential type correlation has been observed between fractional
free volume and the diffusion coefficient.
Received: 13 June 1996/Accepted: 20 September 1996 相似文献
223.
Reynaldo C. Castells Eleuterio L. Arancibia Angel M. Nardillo 《Journal of solution chemistry》1993,22(1):85-94
The retention behavior of eight halomethanes and four saturated hydrocarbons was measured in gas chromatographic stationary phases consisting in tri-n-octylamine (TOA), squalane (SQ) and six TOA+SQ mixtures, at 55.0, 58.5, 62.5 and 65.0°C. Equlibrium constants for complex formation were extracted from experimental data by using a lattice model developed by Martire. The results may be interpreted in terms of the formation of weak hydrogen-bonded complexes, with sociation constants of about 0.13 L-mol–1 for haloforms and 0.07 L-mol–1 for dihalomethanes at 60°C. 相似文献
224.
J. E. Fischer E. Werwa P. A. Heiney 《Applied Physics A: Materials Science & Processing》1993,56(3):193-196
We have used both reflection-geometry and grazing-incidence-geometry X-ray scattering to study thin films of C60 evaporated onto mica substrates via a hot-wall technique. The growth mode yields close-packed C60 planes, which are parallel to the substrate surface and which exhibit out-of-plane correlation lengths of 850 Å. In the film plane the C60 is at best pseudo-epitaxial, with a 0.9° distribution of crystallite orientations, a 450 Å in-plane correlation length, and a 3.7% lattice mismatch, better than obtained by other thin film techniques but far from the accepted definition of single crystal thin film epitaxy. 相似文献
225.
I. V. Ukrainets S. G. Taran O. V. Gorokhova P. A. Bezuglyi A. V. Turov 《Chemistry of Heterocyclic Compounds》1994,30(2):204-207
In a solution of DMF, 2-carbethoxymethyl-4H-3,1-benzoxazin-4-one reacts with primarily aromatic amines basically with the formation of the corresponding 2-carbethoxymetlzyl-3-arylquinazolin-4(3H)-ones. Possible mechanisms of these chemical transformations are reported and discussed.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 225–228, February, 1994. Original article submitted June 28, 1993. 相似文献
226.
Molecular n-v complexes of quinoline N-oxides with BF3 have been studied by electronic and IR spectroscopy. In most case the donor centre is the oxygen atom of the N-oxide group.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1087–1092, August, 1994. 相似文献
227.
V. D. Orlov Z. Kaluski N. P. Borob'eva E. Figas A. A. Tishchenko F. G. Yaremko 《Chemistry of Heterocyclic Compounds》1994,30(8):964-971
We have measured the PMR spectra of 5, 7-diaryl-1, 4-diazabicyclo[4. ].O]hept-4-enes. We have studied the structure of the 5-(4-nitrophenyl)-7-phenyl derivative by x-ray diffraction. We show that the six-membered heterocycle has the half-chair form. The 6-H and 7-H protons of the aziridine ring are trans, while the 7-aryl is exo relative to the six-membered ring. Introduction of substituents into the aromatic ring has practically no effect on the geometry of the bicycle.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1117–1124, August, 1994.For Communication 11, see [1]. 相似文献
228.
A. Sh. Isamukhamedov N. P. Goncharova A. I. Glushetskova 《Chemistry of Natural Compounds》1994,30(2):170-174
The influence of sunflowerseed and cottonseed oils and also of fractions of normal and oxidized triacylglycerols isolated from them on cytochrome P-450 from rat liver microsomes has been investigated. 相似文献
229.
A. Aitmambetov S. N. Shinkaruk S. P. Bondarenko V. P. Khilya 《Chemistry of Natural Compounds》1994,30(4):453-456
6-Halogeno-1,3-benzodioxane analogs of chalcones have been synthesized by various methods. Flavanone and flavone analogs of silandrin and hydnocarpin have been obtained from them. The structures of the new flavonoids have been shown by their PMR spectra. 相似文献
230.
A. N. Komissarenko T. P. Nadezhina N. F. Komissarenko 《Chemistry of Natural Compounds》1994,30(4):521-522
State Scientific Center for Drugs, Khar'kov. Ukrainian Pharmaceutical Academy, Khar'kov. Botanical Gardem, Russian Academy
of Sciences, St. Petersburg. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 564–565, July–August, 1994. 相似文献