Dakin-West trick in the design of novel 2-alkyl(aralkyl) derivatives of oxazolo[3,2-a]pyridines

A series of previously unavailable derivatives of 2-alkyl- and 2-benzylderivatives of oxazolo[3,2-a]pyridines III were obtained via tandem ring opening and ring closure from stable mesoionic 3-acyloxazolo[3,2-a]pyridinium-2-olates I. The key intermediates of this tandem transformation are N-(b-oxoethyl)pyridones-2 II obtained by Dakin-West acylation of (pyridone-2-yl-1)acetic acid. An example of further utilization of this strategy is illustrated by preparation of unknown 2-benzylimidazo[1,2-a]pyridine from the salt I and ammonia.     

Growth and morphological study of copper oxide single crystals

Experiments on the growth of CuO single crystals by crystallization from flux in the CuO-Bi₂O₃-PbO-PbF₂, CuO-Bi₂O₃-Li₂O, CuO-Bi₂O₃-B₂O₃, CuO-BaO-Y₂O₃, and CuO-MO_x systems (M = P, V, or Mo) have been performed. The best results were obtained in crystallization in the CuO-Bi₂O₃-PbF₂ system: prismatic single crystals of platelet-and needlelike or isometric habit with dimensions up to 1 × 10 × 10, 1 × 1 × 20, or 6 × 6 × 8 mm, respectively, have been grown. The CuO crystals show polysynthetic twinning in the form of numerous alternating light and dark bands bound by systems of parallel straight lines on the {110} and {111} faces. A possible model of twinning associated with the Cu₂O → CuO transformation is considered.     

Low-frequency dynamic response of the bismuth strontium ferrite (Bi,Sr)FeO3−x

Broad-range measurements of the dynamic response of polycrystalline samples of the (Bi,Sr)FeO_3?x perovskite-like solid solution are performed over a frequency range from 10 Hz to 1 GHz at temperatures of 100–300 K for the first time. The colossal dielectric constant effect and the influence of electric contacts on the results of measurements are considered. It is shown that the frequency dependences of the permittivity and dynamic conductivity of (Bi,Sr)FeO_3?x samples can be described within the universal dielectric response model.     

Competition between helimagnetism and commensurate quantum spin correlations in LiCu2O2

Neutron diffraction and bulk measurements are used to determine the nature of the low-temperature ordered state in LiCu2O2, a S=1/2 spin-chain compound with competing interactions. The spin structure is found to be helimagnetic, with a propagation vector (0.5,zeta,0), zeta=0.174. The nearest-neighbor exchange constant and frustration ratio are estimated to be J(1)=5.8 meV and J(2)/J(1)=0.29, respectively. For idealized quantum spin chains, these parameter values would signify a gapped spin-liquid ground state with commensurate spin correlations. The observed temperature dependence of the magnetic propagation vector in LiCu2O2 is attributed to a competition between incommensurate helimagnetism in the classical spin model and commensurability in the quantum case. It is also proposed that long-range ordering in LiCu2O2 is facilitated by intrinsic nonstoichiometry.     

Low-frequency relaxation processes in Pb<Subscript>5</Subscript>Ge<Subscript>3</Subscript>O<Subscript>11</Subscript> ferroelectric crystals

Measurements and analysis of the temperature and frequency dependences of permittivity and losses and of the electrical resistivity of Pb₅Ge₃O₁₁ ferroelectric crystals at temperatures of 100 to 600 K and frequencies of 0.1 to 100 kHz are reported. The dielectric characteristics of the crystals exhibit, in addition to clearly pronounced anomalies near the Curie point T_C=450 K, less distinct anomalous features of the relaxation character in the range 230–260 K. The data obtained on the effect of various factors (degree of crystal polarization, crystal annealing at different temperatures and in different environments, etc.) on the low-temperature anomalies serve as a basis for discussing the possible mechanisms responsible for these anomalies. It is concluded that the low-temperature dielectric anomalies originate from thermal carrier localization in defect levels in the band gap, which entail the formation of local polarized states.     

One-neutron knockout from individual single-particle states of 11Be

The structure of the halo nucleus 11Be has been studied using the reaction 9Be(11Be,10Be+gamma)X at 60 MeV/nucleon. The ground state structure of 11Be is determined by comparing the experimental cross sections to a calculation combining spectroscopic factors from the shell model with l-dependent single-particle cross sections obtained in an eikonal model. This experiment shows the dominant 1s single-particle character of the 11Be ground state and indicates a small contribution of 0d admixture in the wave function. After correction for the approximately 22% intensity to excited levels, a clean and precise distribution of parallel momentum for knockout from the 1s halo wave function is obtained for the first time.     

Modelling two-dimensional flow past arbitrary cylindrical bodies using boundary element formulations

This paper presents an efficient method of solving Queen's linearized equations for steady plane flow of an incompressible, viscous Newtonian fluid past a cylindrical body of arbitrary cross-section. The numerical solution technique is the well known direct boundary element method. Use of a fundamental solution of Oseen's equations, the ‘Oseenlet’, allows the problem to be reduced to boundary integrals and numerical solution then only requires boundary discretization. The formulation and solution method are validated by computing the net forces acting on a single circular cylinder, two equal but separated circular cylinders and a single elliptic cylinder, and comparing these with other published results. A boundary element representation of the full Navier-Stokes equations is also used to evaluate the drag acting on a single circular cylinder by matching with the numerical Oseen solution in the far field.