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941.
The soft mode dielectric response of three ferroelectric chiral smectic C* substances is studied in the vicinity of the smectic C*-smectic A* phase transition. For some substances the soft mode dielectric strength exhibits a pronounced anomaly in the C* phase just below the phase transition. We show how this anomaly can be systematically correlated with a corresponding anomaly in the experimentally determined ratio of spontaneous polarization over tilt. By comparing the experimental results with the theoretical predictions of an extended Landau model, we demonstrate how the crossover behaviour of the system can be interpreted as being the consequence of the presence of a biquadratic coupling between tilt and polarization in the Landau free-energy of the system. 相似文献
942.
Oxyethylene macrocyclic compounds (crown-ethers) act as ligands of intracrystalline cations of certain layered silicates as montmorillonites. Stable intercalation materials are formed which are used to prepare organic-inorganic membranes by encapsulating these intercalation compounds with a poly-butadiene thin coating. Electrochemical Impedance Spectroscopy (EIS) is used to study the resulting composite membranes in contact with aqueous electrolytes. From the impedance plots, the ionic resistance of the membranes is obtained. The thickness of the polybutadiene coating is an important factor determining the ability of ions to pass across the membrane. Marked differences in the ionic resistance are observed as a function of the nature of the interlayer macrocyclic compound. For non-intercalated montmorillonite membranes, the ionic resistance is strongly reduced, whereas for some crown-ether intercalated materials such as 18-crown-6 and dibenzo 24-crown-8, iono-selective membranes are obtained. Concerning the nature of the electrolyte, cations exhibiting greater hydration energies show higher difficulties to pass through the membrane and, consequently, the ionic resistance increases. 相似文献
943.
Equations are derived, which allow one to determine the electrode's surface coverage with adsorbate, charge, differential capacitance, and interfacial tension within the framework of a phenomenological model, for which the Grahame–Parsons and Alekseev–Popov–Kolotyrkin models are the limiting cases. 相似文献
944.
Simulation results are presented for the focusing of shock waves in conical and wedge-shaped cavities. Results are reported for plane waves and explosion waves. The distribution of parameters in the focusing zone is found to depend on the specific conditions. 相似文献
945.
Here we study the behaviour of the spin 0 sector of the DKP field in spaces with torsion. First we show that in a Riemann-Cartan manifold the DKP field presents an interaction with torsion when minimal coupling is performed, contrary to the behaviour of the KG field, a result that breaks the usual equivalence between the DKP and the KG fields.Next we analyse the case of the Teleparallel Equivalent of General Relativity (Weitzenböck manifold), showing that in this case there is a perfect agreement between KG and DKP fields. The origins of both results are also discussed.On leave from 相似文献
946.
In contrast to stochastic differential equation models used for the calculation of the term structure of interest rates, we
develop an approach based on linear dynamical systems under non-stochastic uncertainty with perturbations. The uncertainty
is described in terms of known feasible sets of varying parameters. Observations are used in order to estimate these parameters
by minimizing the maximum of the absolute value of measurement errors, which leads to a linear or nonlinear semi-infinite
programming problem. A regularized logarithmic barrier method for solving (ill-posed) convex semi-infinite programming problems
is suggested. In this method a multi-step proximal regularization is coupled with an adaptive discretization strategy in the
framework of an interior point approach. A special deleting rule permits one to use only a part of the constraints of the
discretized problems. Convergence of the method and its stability with respect to data perturbations in the cone of convexC
1-functions are studied. On the basis of the solutions of the semi-infinite programming problems a technical trading system
for future contracts of the German DAX is suggested and developed.
Supported by the Stiftung Rheinland/Pfalz für Innovation, No. 8312-386261/307. 相似文献
947.
K. B. Aleinikova E. N. Zinchenko A. V. Arakcheeva V. V. Grinevich 《Crystallography Reports》2002,47(4):555-558
An amorphous sediment was prepared by the decomposition of potassium oxofluoroniobate K2 ? x Nb4O3(O, F)3F in water. For this sediment, the atomic radial distribution function was analyzed with the use of a fragment model, which allows one to interpret expanded coordination spheres as being formed by first several strongest diffusion maxima. These spheres carry the most reliable information on the structure. It is shown that the amorphous sediment consists of the randomly packed Nb(O,F)6-octahedra with interatomic distances close to those observed in the ordered region in the N-Nb2O5 structure. During decomposition in water, the initial K2 ? x Nb4O3(O, F)3F phase loses KF-layers, whereas Nb6 clusters with metal bonds are destroyed. 相似文献
948.
S. I. Pesotskii R. B. Lyubovskii W. Biberacher M. V. Kartsovnik V. I. Nizhankovskii N. D. Kushch H. Kobayashi A. Kobayashi 《Journal of Experimental and Theoretical Physics》2002,94(2):431-433
Behavior of the de Haas-van Alphen (dHvA) oscillations depending on the angle between the magnetic field direction and the perpendicular to conducting layers in the quasi-two-dimensional organic metal α-(BETS)2 KHg(SCN)4 was studied in detail. The angular dependence of the dHvA oscillation amplitude exhibits a series of minima (at ±43.2°, ±64.6°, and ±72.0°) related to the “zero spin” effect, through which it is possible to estimate the splitting factor. An analysis of this value suggests that many-body interactions in the compound studied are either absent or at least radically weakened. 相似文献
949.
V. S. Averbakh B. N. Bogolyubov Yu. A. Dubovoi Yu. M. Zaslavskii A. V. Lebedev A. P. Maryshev V. E. Nazarov K. E. Pigalov V. I. Talanov 《Acoustical Physics》2002,48(2):121-127
To excite seismic waves with a high coherence, powerful hydroacoustic radiators placed in a natural reservoir were used. Theoretical estimates and the test data demonstrate a high efficiency of the proposed method of seismic wave excitation. The calculations are in good agreement with the results of measurements. The results of phasing the radiation with the use of two monopole sources separated by a quarter-wave distance are presented. It is shown that the use of the proposed scheme of excitation makes it possible to control the radiation pattern while obtaining a high coherence of seismic waves. 相似文献
950.
G. Michałek B.R. Bułka 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,28(1):121-128
The currents and their fluctuations in two capacitively coupled single electron transistors are determined in the limit of
sequential tunnelling. Our considerations are restricted to the case when the islands (dots) of the transistors are atomic-sized,
which means each of them has only one single electronic level available for the tunnelling processes. The Coulomb interactions
of accumulated charges on the both single electron transistors lead to the effect of the negative differential resistance.
An enhancement of the current shot-noise was also found. Spectral decomposition analysis indicated the two main contributions
to the shot-noise: low- and high-frequency fluctuations. It was found that the low frequency fluctuations (polarization noise)
are responsible for a strong enhancement of the current noise.
Received 9 October 2001 / Received in final form 8 March 2002 Published online 9 July 2002 相似文献