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101.
102.
Kazuo Eda Yuichi Uno Noriyuki Sotani M. Stanley Whittingham 《Journal of solid state chemistry》2006,179(5):1453-1458
We have explored several structure-inheriting solid-state reactions (SISSRs) under hydrothermal conditions for syntheses in the Co-Mo-O system. And we found an interesting hydrothermal SISSR from CoMoO4·3/4H2O to high-pressure (hp-) phase of CoMoO4, which enabled us to considerably reduce the severe conditions for the synthesis of hp-CoMoO4. As similar hydrothermal SISSRs are expected to be useful tools for material syntheses, we also briefly discuss them as a means of developing novel material syntheses and designs. 相似文献
103.
Eda Gungor Cigdem Bilir Gurkan Hizal Umit Tunca 《Journal of polymer science. Part A, Polymer chemistry》2010,48(21):4835-4841
Azide end‐functionalized polyhedral oligomeric silsesquioxane (POSS‐N3) was incorporated into the periphery of well‐defined alkyne‐polystyrene50‐poly(divinyl benzene) (alkyne‐PS50‐polyDVB) and alkyne‐poly(tert‐butyl acrylate)43‐poly(divinyl benzene) (alkyne‐PtBA43‐polyDVB) multiarm star polymers via highly efficient azide‐alkyne click reaction, resulting in POSS‐PS50‐polyDVB and POSS‐PtBA43‐polyDVB multiarm star block copolymers respectively, in the solution of tetrahydrofuran/N,N‐dimethyl formamide, CuBr/N,N,N′,N″,N″‐pentamethyldiethylenetriamine (PMDETA) at room temperature for 24 h. Linear precursors and star polymers obtained in this study were characterized 1H NMR, gel permeation chromatography (GPC), and triple detection GPC (TD‐GPC). Absolute molecular weight, hydrodynamic radius, and intrinsic viscosity ([η]) values for all star polymers were determined by TD‐GPC. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
104.
Vüsala Ibrahimova Meliha Eda Kocak Ahmet M. Önal Dönüs Tuncel 《Journal of polymer science. Part A, Polymer chemistry》2013,51(4):815-823
A series of novel, fluorene‐based conjugated copolymers, poly[(9,9‐bis{propenyl}‐9H‐fluorene)‐co‐(9,9‐dihexyl‐9H‐fluorene)] ( P1 ), poly[(9,9‐bis{carboxymethylsulfonyl‐propyl}fluorenyl‐2,7‐diyl)‐co‐(9,9‐dihexyl‐9H‐fluorene)] ( P2 ) and poly[(9,9‐dihexylfluorene)‐co‐alt‐(9,9‐bis‐(6‐azidohexyl)fluorene)] ( P3 ), are synthesized by Suzuki coupling reactions and their electrochemical properties, in the form of films, are investigated using cyclic voltammetry. The results reveal that the polymer films exhibit electrochromic properties with a pseudo‐reversible redox behavior; transparent in the neutral state and dark violet in the oxidized state. Among the three polymers, P2 possesses the shortest response time and the highest coloration efficiency value. These polymers emit blue light with a band gap value of around 2.9 eV and have high fluorescent quantum yields. Their metal ion sensory abilities are also investigated by titrating them with a number of different transition metal ions; all of these polymers exhibit a higher selectivity toward Fe3+ ions than the other ions tested with Stern–Volmer constants of 4.41 × 106M?1, 3.28 × 107M?1, 1.25 × 106M?1, and 6.56 × 106M?1 for P1 , P2 , water soluble version of P2 ( P2S ) and P3 , respectively. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
105.
Tsunehito Eda Katsuhiro Arai Yoshio Matsubara Masakuni Yoshihara Toshihisa Maeshima 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(3):359-365
Abstract Radical copolymerizability of 6-methyl-2-vinyl-3-pyridazinone (I) has been reinvestigated in acetic acid and also in the presence of polyacrylic acid (PAA). Copolymerization of styrene with I was carried out in a few solvents. A positive e2 value was obtained in acetic acid while negative ez values were obtained in benzene and DMF. I was allowed to copolymerize with a few monomers such as styrene, methyl methacrylate, and acrolein in the presence of PAA to give block-type copolymers. All these observations indicate that polymerizability of I is controlled by the hydrogen bonding interaction between the carbonyl group of I and the hydroxyl group of the additive. 相似文献
106.
107.
108.
We construct a functor AC(?, ?) from the category of path connected spaces X with a base point x to the category of simply connected spaces. The following are the main results of the paper: (i) If X is a Peano continuum then AC(X, x) is a cell-like Peano continuum; (ii) If X is n-dimensional then AC(X, x) is (n + 1)?dimensional; and (iii) For a path connected space X, π 1(X, x) is trivial if and only if π 2(AC(X, x)) is trivial. As a corollary, AC(S 1, x) is a 2-dimensional nonaspherical cell-like Peano continuum. 相似文献
109.
Shuzo Akiyama Shinichi Nakatsuji Shohei Eda Motohiro Kataoka Masazumi Nakagawa 《Tetrahedron letters》1979,20(30):2813-2816
Isorenieratene has been efficiently synthesized using 4-(t-butylthio)-3-buten-2-one as chain lengthening agent. 相似文献
110.
A Ashimori T Ono Y Inoue S Morimoto M Eda T Uchida Y Ohtaki Y Fujino H Kido Y Ogura 《Chemical & pharmaceutical bulletin》1991,39(1):91-99
Novel 1,4-dihydropyridine derivatives bearing 3-[4-(substituted amino)phenylalkyl]ester side chains were prepared and tested for their antihypertensive activity in spontaneously hypertensive rats. Most compounds showed a more potent antihypertensive effect and a longer duration of action than nicardipine. The derivatives with a benzhydrylpiperazinyl and a benzhydrylpiperidinyl group were distinctive. 2-[4-(4-Benzhydryl-1-piperazinyl)phenyl]ethyl methyl 1,4-dihydro-2,6-dimethyl-4-(3-nitrophenyl)-3,5-pyridinedicarboxylate (4e), its 4-(4-cyano-2-pyridyl) analogue (4f), its 3-[4-(4-benzhydryl-1-piperazinyl)phenyl]propyl ester analogue (4h), its 2-[4-(4-benzhydryl-1-piperidinyl)phenyl]ethyl ester analogue (4j), and its 2-[4-(1-benzhydryl-4-piperidinyl)phenyl]ethyl ester analogue (4k) were selected as candidates for further pharmacological investigations. 相似文献