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31.
The process of extracting ephedra herbage in a constant electric field has been studied. It has been shown that the application of an electric field considerably accelerates the isolation of the alkaloid molecules from the cellulose of the plant raw material. The main kinetic characteristics of the electroextraction of the total alkaloids as functions of various factors have been obtained.Institute of Organic Synthesis and Coal Chemistry, Kazakh SSR Academy of Sciences, Karaganda. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 862–864, November–December, 1987. 相似文献
32.
Summary Cholesterol isononatriacontanate has been isolated from sheep's wool wax by chromatography on silica gel and alumina.Institute of Organic Chemistry, Academy of Sciences of the Kirgiz SSR, Frunze. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 820–821, November–December, 1977. 相似文献
33.
A. I. Tolmachev Yu. L. Slominskii Zh. N. Belaya É. Z. Rodova 《Chemistry of Heterocyclic Compounds》1976,12(2):153-156
Glutaconic dialdehyde dianil salts, the ,-carbon atoms of which are included in dihydropyran, dihydrothiapyran, or N-methyltetrahydropyridine rings, were synthesized. Tricarbocyanine dyes with epoxydimethylene, epithiodimethylene, or N-methylepiminodimethylene groupings were synthesized by condensation of the dianil salts with a 2-methylbenzothiazole quaternary salt. The color of the dyes is discussed.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 175–178, February, 1976. 相似文献
34.
E. I. Matrosov K. Zh. Kulumbetova L. I. Arkhipova T. Ya. Medved' M. I. Kabachnik 《Russian Chemical Bulletin》1972,21(1):193-195
Conclusions Some tetraphenylmethylenediphosphine dioxides, substituted in the methylene bridge, were subjected to potentiometric titration in nitromethane with perchloric acid. The obtained values of the pK
a
basicity constants (CH3NO2) obey a linear relationship with the * constants of the substituents.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 199–201, January, 1972. 相似文献
35.
B. K. Kasenov Zh. K. Tukhmetova Sh. B. Kasenova S. M. Adekenov A. M. Gazaliev S. D. Fazylov A. Nukhuly A. V. Boldashevskii 《Russian Journal of Applied Chemistry》2005,78(12):2029-2031
Heat of solution of salsoline salsolinodithiocarbamate (SS) at 1 : 18 000, 1 : 36 000, and 1 : 72 000 dilution (mol per mol H2O) was determined on a DAK-I-IA calorimeter, and the standard heat of solution at infinite dilution was estimated. The temperature dependence of the heat capacity of SS was studied over the range 173–348 K. The heats of combustion and fusion, and the standard heat of formation of liquid (molten) and crystalline SS were estimated by indirect methods. 相似文献
36.
A. L. Soldatenkov L. N. Kuleshova T. K. Mandal V. N. Nesterov Zh. A. Mamyrbekova Yu. T. Struchkov 《Chemistry of Heterocyclic Compounds》1996,32(2):233-237
10,11-Dimethyl-9-(coumarin-3 -yl)-12-ethoxycarbonyl-8-oxa-10-azatricyclo[7,3,1.02.7]trideca-2,4,6-11-tetraene was isolated from the mixture of products from the condensation of salicyl aldehyde with acetoacetic ester and methylamine. Its molecular structure has been established by x-ray crystallography.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 259–264, February, 1996. 相似文献
37.
A. S. Tatikolov Kh. S. Dzhulibekov Zh. A. Krasnaya V. A. Kuz'min 《Russian Chemical Bulletin》1993,42(4):682-688
The effect of solvent polarity and ion pair formation oncis-trans-isomerization of cationic-anionic polymethine dyes and of related simple cationic and anionic dyes is studied by flash photolysis. The change in the rate constant for reversecis-trans- isomerization of photoisomers due to the interaction of a cation with an anion in an ion pair is observed in nonpolar solvents. A drop in the yield of the photoisomers to zero is observed for a number of cationic-anionic dyes in weakly polar and nonpolar solvents which is possibly due to steric hindrances in the photoisomerization process in ion pairs.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 719–724, April, 1993. 相似文献
38.
Summary Three sesquiterpene hydrocarbons, muurolene-1, muurolene-2, and muurolene-3, have been isolated from the oleoresin ofPinus sibirica R. Mayr.Muurolene-3 is D--muurolene and has the structure (VIII).Khimiya Prirodnykh Soedinenii, Vol. 2, No. 3, pp. 173–176, 1966 相似文献
39.
Electronic, IR and UV spectroscopy has shown that 2-(N-isatinomethylene)-3(2H)-benzo[b]thiophenone in solution displays photo- and solvatochromism as a result of reversible E Z isomerization, and it readily undergoes alcoholysis of the lactam bond. The resulting aminovinyl ketones exist as mixtures of the thermodynamically stable E- and Z-isomers.For Communication 45, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1217–1220, September, 1989. 相似文献
40.
V. A. Raldugin V. A. Hang Zh. V. Dubovenko V. A. Pentegova 《Chemistry of Natural Compounds》1977,12(3):266-269
Summary 1. The composition of the acid fraction of the oleresin ofPinus pumila (Pall.) Regel. has been studied, and from it has been isolated, in addition to known compounds, the methyl ester of a new labdane acetoxy acid.2. In the hydrocarbon fraction of the oleoresin 11 monoterpenes and 26 sesquiterpenes have been found (and 17 of the latter have been identified).3. The composition of the fraction of neutral oxygen-containing diterpenoids fromP. pumila differs considerably in its diterpenoid components from the corresponding fractions of the oleoresins of botanically related species-P. sibirica andP. koraiensis.
Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 299–302, May–June, 1976. 相似文献