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Turan Neslihan Oruç Pınar Demirölmez Yeşim Seçkin Ayten Çağırtekin Ali Orkun Cavdar Sukru Koralay Haluk Tuğluoğlu Nihat 《Journal of Sol-Gel Science and Technology》2021,100(1):147-159
Journal of Sol-Gel Science and Technology - Zn0.95Co0.05O was synthesized by sol-gel method and then Zn0.95Co0.05O pellet was prepared to investigate its structural, morphological, electrical, and... 相似文献
84.
We introduce a class of differential equations on variable time scales with a transition condition between two consecutive parts of the scale. Conditions for existence and uniqueness of solutions are obtained. Periodicity, boundedness and stability of solutions are considered. The method of investigation is by means of two successive reductions: B-equivalence of the system [E. Akalín, M.U. Akhmet, The principles of B-smooth discontinuous flows, Computers and Mathematics with Applications 49 (2005) 981–995; M.U. Akhmet, Perturbations and Hopf bifurcation of the planar discontinuous dynamical system, Nonlinear Analysis 60 (2005) 163–178; M.U. Akhmet, N.A. Perestyuk, The comparison method for differential equations with impulse action, Differential Equations 26 (9) (1990) 1079–1086] on a variable time scale to a system on a time scale, a reduction to an impulsive differential equation [M.U. Akhmet, Perturbations and Hopf bifurcation of the planar discontinuous dynamical system, Nonlinear Analysis 60 (2005) 163–178; M.U. Akhmet, M. Turan, The differential equations on time scales through impulsive differential equations, Nonlinear Analysis 65 (2006) 2043–2060]. Appropriate examples are constructed to illustrate the theory. 相似文献
85.
Turan Kaya Yazıcılar Evrim Yılmaz Gürkan İbrahim Uçar Canan Kazak 《Transition Metal Chemistry》2009,34(6):669-676
Four novel transition metal benzenesulfonate (BS) complexes of imidazole (im) with a general formula [M(imH)3(H2O)3]·(BS)2 [M=Mn(II) (1), Ni(II) (2), Co(II) (3)] and [Cu(BS)(imH)3]·(BS) (4) have been synthesized and characterized by physicochemical and spectroscopic methods. The complexes 2 and 3 have also been characterized by single X-ray diffraction technique. The BS anion in complexes 1–3 acts as a counter anion, while in complex 4, it acts as both ligand and counter anion. The Ni and Co complexes are isomorphous, crystallizing in the monoclinic crystal
system with C2/c space group. Each metal(II) atom in 2 and 3 is octahedrally coordinated by three imidazole and three aqua ligands, adopting a mer-coordination mode with Ni(II) or Co(II) centers. In both 2 and 3, the H2C atom has bifurcated donor (O3 and O5) atoms, forming a bifurcated hydrogen bond. This hydrogen bond links the complex
cation and BS anion, forming one-dimensional hydrogen-bonded supramolecular chains. The complexes exhibit different decomposition
characteristics. Magnetic susceptibility measurement shows that complex 3 has orbital interactions. 相似文献
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In this study, two novel Schiff base ligands (L1 and L2) derived from condensation of methyl 2-amino-6-methyl-4,5,6,7-tetrahydrothieno[2,3-c]pyridine-3-carboxylate and methyl 2-amino-6-phenyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate, both starting matter with 5-bromo-salicylaldehyde, and their Zn(II) and Ni(II) metal complexes have been prepared using a molar ratio of ligand:metal as 1:1 except the Ru(II) complexes 1:0.5. The structures of the obtained ligands and their metal complexes were characterized by elemental analysis, FT-IR, 1H NMR, 13C NMR, UV–vis, thermal analysis methods, mass spectrometry, and magnetic susceptibility measurements. Antioxidant and antiradical activity of Schiff base ligands and their metal complexes were been evaluated in vitro tests. Antioxidant activities of metal complexes generally were more effectives than free Schiff bases. 1c and 2c were used as catalysts for the transfer hydrogenation (TH) of ketones. 1c, 2c complexes were found to be efficient catalyst for transfer hydrogenation reactions. 相似文献
88.
Aykutlu Dna mran Aka Orun Ergun Atilla Aydnl Rait Turan Terje G. Finstad 《Physica E: Low-dimensional Systems and Nanostructures》2007,38(1-2):94
Understanding charging mechanisms and charge retention dynamics of nanocrystal (NC) memory devices is important in optimization of device design. Capacitance spectroscopy on PECVD grown germanium NCs embedded in a silicon oxide matrix was performed. Dynamic measurements of discharge dynamics are carried out. Charge decay is modelled by assuming storage of carriers in the ground states of NCs and that the decay is dominated by direct tunnelling. Discharge rates are calculated using the theoretical model for different NC sizes and densities and are compared with experimental data. Experimental results agree well with the proposed model and suggest that charge is indeed stored in the quantized energy levels of the NCs. 相似文献
89.
Özsin Gamzenur Dermenci Kamil Burak Turan Servet 《Journal of Thermal Analysis and Calorimetry》2021,146(3):1405-1420
Journal of Thermal Analysis and Calorimetry - Solid electrolytes for all-solid-state Li-ion batteries have attracted significant interest with their outstanding safety. But their poor ionic... 相似文献
90.
Nazl Turan Yücel Derya Osmaniye Ümmühan Kandemir Asaf Evrim Evren
zgür Devrim Can Ümide Demir
zkay 《Molecules (Basel, Switzerland)》2021,26(11)
In this study, we aimed to design and synthesize novel molecules carrying both the thiazole and piperazine rings in their structures and to investigate their antinociceptive activity. Targeted compounds were obtained by reacting thiosemicarbazide derivative and appropriate 2-bromoacetophenone in ethanol. The structures of the obtained compounds were determined using data from various spectroscopic methods (IR, 1H-NMR, 13C-NMR, and LCMSMS). Experimental data from in vivo tests showed that test compounds 3a–3c, 3f, and 3g (50 mg/kg) significantly prolonged reaction times of animals in tail-clip and hot-plate tests compared to the controls, indicating that these compounds possess centrally mediated antinociceptive activities. Furthermore, these compounds reduced the number of writhing behaviors in the acetic acid-induced writhing tests, showing that the compounds also possess peripheral antinociceptive activity. In the mechanistic studies, naloxone pre-treatments abolished the antinociceptive activities of compounds 3a–3c, 3f, and 3g, indicating that opioidergic mechanisms were involved in their antinociceptive effects. Molecular docking studies demonstrating significant interactions between the active compounds and µ- and δ-opioid receptor proteins supported the pharmacological findings. This study is the first showing that molecules designed to bear thiazole and piperazine moieties together on their structure exert centrally and peripherally mediated antinociceptive effects by activating the opioid system. 相似文献