On f-Linearity and f-Orthomorphisms

Let A be an f-algebra with unit and L,M be two f-modules on A. We define f-orthomorphisms from L into M and show that these operators coincide with the f-linear operators whenever M is topologically full with respect to A. We show that f-orthomorphisms enjoy many of the properties of orthomorphisms.     

On Two-dimensional Predictions of Turbulent Cross-flow Induced Vibration: Forces on a Cylinder and Wake Interaction

In this paper a typical fluid-structure interaction scenario is investigated for a turbulent flow past a circular cylinder at a relatively low subcritical Reynolds number. Numerous experimental and numerical studies have been undertaken for a baseline Reynolds number of 4,000 involving a stationary cylinder to study in detail the near wake mean flow and turbulence characteristics. These studies conclusively show that the turbulent wake displays significant coherent periodic structures of large eddies that could be adequately and profitably resolved by “low order modelling” of turbulence. In this study, an unsteady numerical framework is employed for the simulations, incorporating an Arbitrary Lagrangian–Eulerian (ALE) method for the associated grid deformation to simulate the coupled motion of the circular cylinder with a single degree of freedom in the initial zone in a typical cylinder-flow response map or what is called “initial regime”. Particular attention is paid towards resolving the large scales of the fluid motion and the inherent coupling of the cylinder’s motion towards the associated evolution of the time averaged flow field. The flow-induced vibration effects regarding the kinetic energy exchange between the mean flow and the coherent periodic scales are investigated further. The predictions discussed and analyzed in detail in the paper display reasonable agreement with the chosen benchmark tests of the stationary cylinder and suggest that the conclusions outlined regarding the coupled flow-cylinder system potentially provides a valuable contribution to the state of the art.     

Excitation intensity and temperature‐dependent photoluminescence and optical absorption in Tl4Ga3InSe8 layered crystals

Photoluminescence (PL) spectra of Tl₄Ga₃InSe₈ layered crystals grown by Bridgman method have been studied in the wavelength region of 600‐750 nm and in the temperature range of 17‐68 K. A broad PL band centered at 652 nm (1.90 eV) was observed at T = 17 K. Variations of emission band has been studied as a function of excitation laser intensity in the 0.13 to 55.73 mW cm^‐2 range. Radiative transitions from donor level located at 0.19 eV below the bottom of conduction band to shallow acceptor level located at 0.03 eV above the top of the valence band were suggested to be responsible for the observed PL band. From X‐ray powder diffraction and optical absorption study, the parameters of monoclinic unit cell and the energy of indirect band gap were determined, respectively. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Kinetic modeling of Fischer–Tropsch-to-olefins process via advanced optimization

The reaction kinetics of a Fischer–Tropsch (FT) process to produce lower olefins was modeled utilizing the experimental data produced using an in-house synthesized iron-based catalyst. Along with FT chain growth reaction that is assumed to follow alkyl mechanism, water–gas shift reaction was also taken into consideration due to its significance. Not only the rate constants but also apparent activation energies were obtained via an integrated approach utilizing multiobjective and constrained nonlinear minimization methods in order to define a model valid at a temperature range instead of a single point. The adaption of a hybrid optimization method utilizing both population- and individual-based techniques enhanced prediction accuracy compared with the case where only multiobjective genetic algorithm is used. Thanks to the developed model, the effect of process parameters on product distribution was investigated. Finally, the kinetic model was compared with Anderson–Schulz–Flory model and the deviations observed were discussed.     

Annealing effect on electrical and photoconductive properties of Si implanted GaSe single crystal

GaSe single crystals grown by Bridgman method have been doped by ion implantation technique. The samples were bombarded in the direction parallel to c‐axis by Si ion beam of about 100 keV to doses of 1 × 10¹⁶ ions/cm² at room temperature. The effects of Si implantation with annealing at 500 and 600 °C on the electrical properties have been studied by measuring the temperature dependent conductivity and photoconductivity under different illumination intensities in the temperature range of 100–320 K. It is observed that Si implantation increases the room temperature conductivity 10⁻⁷ to 10⁻³ (Ω‐cm)⁻¹ depending on the post annealing temperature. The analysis of temperature dependent conductivity shows that at high temperature region above 200 K, the transport mechanism is dominated by thermal excitation in the doped and undoped GaSe samples. At lower temperatures, the conduction of carriers is dominated by variable range hopping mechanism in the implanted samples. Annealing of the samples at and above 600 °C weakens the temperature dependence of the conductivity and photoconductivity. This indicates that annealing of the implanted samples activates Si‐atoms and increases structural deformations and stacking faults. The same behavior was observed from photoconductivity measurements. Hence, photocurrent‐illumination intensity dependence in the implanted samples obeys the power low I_pc ∝ Φⁿ with n between 1 and 2 which is an indication of continuous distribution of localized states in the band gap. (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

New copolymers with thieno[3,2‐b]thiophene or dithieno[3,2‐b:2′,3′‐d]thiophene units possessing electron‐withdrawing 4‐cyanophenyl groups: Synthesis and photophysical,electrochemical, and electroluminescent properties

New monomers containing 4‐cyanophenyl (–PhCN) groups attached to a thieno[3,2‐b]thiophene (TT) or dithieno[3,2‐b:2′,3′‐d]thiophene (DTT) structure were synthesized and characterized as 4‐(2,5‐dibromothieno[3,2‐b]thiophen‐3‐yl)benzonitrile (Br–TT–PhCN) or 4,4′‐(2,6‐dibromodithieno[3,2‐b:2′,3′‐d]thiophene‐3,5‐diyl)dibenzonitrile (Br–DTT–PhCN). The Suzuki coupling of 9,9‐dioctylfluorene‐2,7‐diboronic acid bis(1,3‐propanediol)ester and the Br–TT–PhCN or Br–DTT–PhCN monomer was utilized for the syntheses of novel copolymers poly{9,9‐dioctylfluorene‐2,7‐diyl‐alt‐3‐(4′‐cyanophenyl)thieno[3,2‐b]thiophene‐2,5‐diyl} (PFTT–PhCN) and poly{9,9‐dioctylfluorene‐2,7‐diyl‐alt‐3,5‐bis(4′‐cyanophenyl)dithieno[3,2‐b:2′,3′‐d]thiophene‐2,6‐diyl} (PFDTT–PhCN), respectively. The photophysical, electrochemical, and electroluminescent (EL) properties of these novel copolymers were studied. Their photoluminescence (PL) exhibited the same emission maximum for both copolymers in solution. Red‐shifted PL emissions were observed in the thin films. The PL emission maximum of PFTT–PhCN was more significantly redshifted than that of PFDTT–PhCN, indicating more pronounced excimer or aggregate formation in PFTT–PhCN. The ionization potential (HOMO level) and electron affinity (LUMO level) values were 5.54 and 2.81 eV, respectively, for PFTT–PhCN and were 5.57 and 2.92 eV, respectively, for PFDTT–PhCN. Polymer light‐emitting diodes (LEDs) with copolymer active layers were fabricated and studied. Anomalous behavior and memory effects were observed from the current–voltage characteristics of the LEDs for both copolymers. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 2629–2638     

Near‐IR Absorbing BODIPY Derivatives as Glutathione‐Activated Photosensitizers for Selective Photodynamic Action

Enhanced spatiotemporal selectivity in photonic sensitization of dissolved molecular oxygen is an important target for improving the potential and the practical applications of photodynamic therapy. Considering the high intracellular glutathione concentrations within cancer cells, a series of BODIPY‐based sensitizers that can generate cytotoxic singlet oxygen only after glutathione‐mediated cleavage of the electron‐sink module were designed and synthesized. Cell culture studies not only validate our design, but also suggest an additional role for the relatively hydrophobic quencher module in the internalization of the photosensitizer.     

Computational Investigation of Flow through a Rotating Square Duct by Means of Advanced Second-moment Closure

The paper presents the application of an advanced second moment closure (SMC) to the prediction of the flow field within stationary and rotating square cross-sectioned ducts. The rotation number is 0.1 and the Reynolds number is 100,000. The SMC used satisfies the two-component-limit and has been reported in literature to produce improvements in the prediction of a wide range of flows. The computations were initially validated against existing experimental data, then used to obtain the various budget terms for the Reynolds stresses. The aims of this work are to judge the performance of the advanced SMC and to gain insight into the physics of rotation and its interaction with secondary flows based on the predicted Reynolds stress budgets for high Reynolds number flows. It was found that the advanced SMC performs slightly better than a basic SMC, although neither model predicts the flow on the suction side of the rotating duct well. On the pressure side computed budgets are similar to those obtained in a significantly higher aspect ratio duct. On the suction side, however, the effects of the secondary flows are clearly seen through a significant decrease of various budget terms, a feature not seen in a higher aspect ratio duct, and it thus appears that the models do not entirely capture the interaction between the stabilizing rotation and secondary flow effects.     

Implementation of FPGA-based real time novel chaotic oscillator

Currently, chaotic systems and chaos-based applications are commonly used in the engineering fields. One of the main structures used in these applications is the chaos-based signal generators. Chaotic signal generators have an important role, particularly in chaotic communication and cryptology. In this study, the Pehlivan-Wei chaotic system, which is a recently developed chaotic system, has been implemented with FPGA using three distinct algorithms (the Euler, Heun, and RK4) for the first time in literature. Numerical and HDL approaches are implemented by these three algorithms to compare the performance of each model for use in chaotic generators. In addition, the Lyapunov exponents and phase portraits of the system have been extracted for chaos analysis. RMSE analysis has been conducted on the chaotic generators, which are modeled using the Euler, Heun, and RK4 algorithms in order to observe error rates of each numerical algorithm in a comparative aspect. The performance of new chaotic system with various data sets has been analyzed. The operation frequency of the chaotic oscillators synthesized and tested for the Virtex-6 FPGA chip has been able to reach up to 463.688 MHz and the chaotic system has been able to calculate 300,000 data sets in 0.0284 s. However, PC-based algorithm having highest performance score can calculate 300,000 data sets in a period of 75.363 s. A comparison study has been performed on the performance of the FPGA-based and PC-based solutions to evaluate each approach.