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81.
Electromigration of hydrogen in YH(3-delta) is studied by exploiting the H concentration dependence of the optical transmission of YH(3-delta). We find the effective valence Z* of H in YH(3-delta) to be negative. Its value is dominated by a huge wind-force-like term, i.e., Z* approximately K/rho, with K approximately -60 mOmega cm. This value is 3 orders of magnitude larger than typical for H in metals. In an Arrhenius plot, the ratio of hydrogen and electron fluxes extrapolates to unity at infinite temperature, suggesting a one-to-one correlation of hydrogen and electron hopping. We discuss our results in the light of strong electron correlation theories which predict each proton to bind two electrons in a sort of Zhang-Rice singlet. 相似文献
82.
Chen YC Afanasev A Brodsky SJ Carlson CE Vanderhaeghen M 《Physical review letters》2004,93(12):122301
We estimate the two-photon exchange contribution to elastic electron-proton scattering at large momentum transfer through the scattering off a parton in the proton. We relate the two-photon exchange amplitude to the generalized parton distributions which appear in hard exclusive processes. We find that when taking the polarization transfer determinations of the form factors as input, adding in the 2-photon correction does reproduce the Rosenbluth cross sections. 相似文献
83.
Using single electron capacitance spectroscopy, we study electron additions in quantum dots containing two potential minima separated by a shallow barrier. Analysis of the addition spectra in the magnetic field allows us to distinguish between electrons delocalized over the entire dot and those localized in either of the potential minima. We demonstrate that a high magnetic field abruptly splits up a low-density droplet into two smaller fragments, each residing in a potential minimum. An unexplained cancellation of electron repulsion between electrons in these fragments gives rise to paired electron additions. 相似文献
84.
We characterize the joint two-time statistics of the polarization-mode dispersion (PMD) vector. Good agreement with experimental PMD measurements taken on an installed system is achieved. The results can be used to obtain the temporal evolution of the average penalty of a system close to an outage condition. 相似文献
85.
IA Simpson R Bol ID Bull RP Evershed K Petzke SJ Dockrill 《Rapid communications in mass spectrometry : RCM》1999,13(13):1315-1319
Compound specific stable isotope analyses of managed soils using isotope ratio mass spectrometry have been undertaken as a means of determining early land use practices. delta (15)N amino acid signals demonstrate differences between manured grassland, unmanured grassland and continuous cereal cultivation under long-term experimental land use control conditions, with delta (15)N in hydrophobic amino acids providing the most distinctive signals. Analysis of early modern/medieval and of Bronze age anthropogenic soils from Orkney demonstrates that such signals are retained in archaeological contexts. delta (13)C analyses of n- alkanoic acid components of the fossil, Bronze Age, anthropogenic soils suggest a major terrestrial input to these soils, with uniform composition of formation materials. Surficial soils demonstrate the assimilation of isotopically lighter carbon, providing a means of assessing the mobility of the n- alkanoic acids within soils and sediments. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
86.
A. B. Terentiev T. T. Vasilieva N. A. Kuz'mina O. V. Chakhovskaya E. S. Brodsky Yu. N. Belokon' 《Russian Chemical Bulletin》2000,49(4):722-723
The use of complex-forming solvents and variations in the reaction temperature made it possible to prepare α-halogeno β-hydroxy
carboxylic esters upon addition of halogenoacetic esters to aldehydes and ketones promoted by iron pentacarbonyl.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 718–720, April, 2000. 相似文献
87.
Light-front Hamiltonian theory, derived from the quantization of the QCD Lagrangian at fixed light-front time x + = x 0 + x 3, provides a rigorous frame-independent framework for solving nonperturbative QCD. The eigenvalues of the light-front QCD Hamiltonian H LF predict the hadronic mass spectrum, and the corresponding eigensolutions provide the light-front wavefunctions which describe hadron structure, providing a direct connection to the QCD Lagrangian. In the semiclassical approximation the valence Fock-state wavefunctions of the light-front QCD Hamiltonian satisfy a single-variable relativistic equation of motion, analogous to the nonrelativistic radial Schrödinger equation, with an effective confining potential U which systematically incorporates the effects of higher quark and gluon Fock states. Remarkably, the potential U has a unique form of a harmonic oscillator potential if one requires that the chiral QCD action remains conformally invariant. A mass gap and the color confinement scale also arises when one extends the formalism of de Alfaro, Fubini and Furlan to light-front Hamiltonian theory. In the case of mesons, the valence Fock-state wavefunctions of H LF for zero quark mass satisfy a single-variable relativistic equation of motion in the invariant variable \({\zeta^2=b^2_\perp x(1-x)}\) , which is conjugate to the invariant mass squared \({{M^2_{q\bar q}}}\) . The result is a nonperturbative relativistic light-front quantum mechanical wave equation which incorporates color confinement and other essential spectroscopic and dynamical features of hadron physics, including a massless pion for zero quark mass and linear Regge trajectories \({M^2(n, L, S) = 4\kappa^2( n+L +S/2)}\) with the same slope in the radial quantum number n and orbital angular momentum L. Only one mass parameter \({\kappa}\) appears. The corresponding light-front Dirac equation provides a dynamical and spectroscopic model of nucleons. The same light-front equations arise from the holographic mapping of the soft-wall model modification of AdS5 space with a unique dilaton profile to QCD (3 + 1) at fixed light-front time. Light-front holography thus provides a precise relation between the bound-state amplitudes in the fifth dimension of AdS space and the boost-invariant light-front wavefunctions describing the internal structure of hadrons in physical space-time. We also discuss the implications of the underlying conformal template of QCD for renormalization scale-setting and the implications of light-front quantization for the value of the cosmological constant. 相似文献
88.
We have performed extensive small-angle neutron scattering (SANS) diffraction studies of the vortex lattice in single crystal
YNi2B2C for B‖c. High-resolution SANS, combined with a field-oscillation vortex lattice preparation technique, allows us to separate Bragg
scattered intensities from two orthogonal domains and accurately determine the unit cell angle, β. The data suggest that upon increasing field there is a finite transition width where both low- and high-field distorted
hexagonal vortex lattice phases, mutually rotated by 45°, coexist. The smooth variation of diffracted intensity from each
phase through the transition corresponds to a redistribution of populations between the two types of domains. 相似文献
89.
The formulation of statistical physics using light-front quantization, instead of conventional equal-time boundary conditions, has important advantages for describing relativistic statistical systems, such as heavy ion collisions. We develop light-front field theory at finite temperature and density with special attention to quantum chromodynamics. First, we construct the most general form of the statistical operator allowed by the Poincaré algebra. In light-front quantization, the Green’s functions of a quark in a medium can be defined in terms of just two-component spinors and do not lead to doublers in the transverse directions. Since the theory is non-local along the light cone, we use causality arguments to construct a solution to the related zero-mode problem. A seminal property of light-front Green’s functions is that they are related to parton densities in coordinate space. Namely, the diagonal and off-diagonal parton distributions measured in hard scattering experiments can be interpreted as light-front density matrices. 相似文献
90.
New first- and high-order centred methods for conservation lawsare presented. Convenient TVD conditions for constructing centredTVD schemes are then formulated and some useful results areproved. Two families of centred TVD schemes are constructedand extended to nonlinear systems. Some numerical results arealso presented. 相似文献