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71.
72.
A short review of the fundamental investigations in the fields of synthesis, properties and application of alumoxanes for the last thirties years is given. 相似文献
73.
Nikolai Tyutyulkov Fritz Dietz Martin Baumgarten Klaus Müllen 《Macromolecular theory and simulations》1995,4(5):991-1000
The energy spectra of two types of non-helical carbon nanotubes are investigated theoretically. It is shown that either the topological or the correlational contributions determine the width of the band gap. In some cases (for nanotubes with diameter < 1 nm) the electron correlation changes qualitatively the results for the width of the energy gap ΔE: if in the one-electron approximation the band width ΔE = 0, the contribution of the electron correlation becomes dominant and increases the band gap ΔE > 0. At small diameter of the nanotubes (D > 1 nm) the ground state of the tubes corresponds to semiconductors with moderate or narrow energy gap, while at D > 1 nm ΔE decreases monotonously. The energy spectra of the planar ribbon polymers are compared with those of the iso-electronic nanotubes. 相似文献
74.
Mass analysis in islands of stability with linear quadrupoles with added octopole fields 总被引:1,自引:0,他引:1
Konenkov N Zhao X Xiao Z Douglas DJ 《Journal of the American Society for Mass Spectrometry》2007,18(5):826-834
Mass analysis with linear quadrupole mass filters is possible by forming "islands" in the stability diagram with auxiliary quadrupole excitation. In this work, computer simulations are used to calculate stability boundaries, island positions, and peak shapes and ion transmission for mass analysis with linear quadrupole mass filters that have added octopole fields of about 2 to 4%. Rod sets with exact geometries that have quadrupole and octopole fields only in the potential, and round rod sets, with multipoles up to N = 10 (the twenty pole term) included in the calculations, show the same stability boundaries, island positions, and peak shapes. With the DC voltage applied to the rods so that the Mathieu parameter a < 0, conventional mass analysis is possible without the use of an island. With the DC polarity reversed so that a > 0, the resolution and transmission are poor preventing conventional mass analysis. In principle, mass analysis in an island is possible with operation at either of two tips. Provided the correct island tip is chosen for mass analysis, peak shapes comparable to those with a > 0 and no excitation are possible, both with a > 0 and with a < 0. In the latter case, the use of an island of stability allows mass analysis when the added octopole otherwise prevents conventional mass analysis. 相似文献
75.
Nikolai V. Tsvetkov Mariya E. Mikhailova Nina G. Mikusheva Alexey A. Lezov Alexander S. Gubarev Elena V. Lebedeva 《International Journal of Polymer Analysis and Characterization》2017,22(1):27-34
Conformational and dynamo-optical properties of a homologous series of poly(cetyltrimethylammonium 2-acrylamido-2-methylpropane sulfonates) with molecular masses ranging from 80 to 700?kDa were studied in chloroform solutions by viscometry, dynamic light scattering, sedimentation, and flow birefringence. The Mark–Kuhn–Houwink Equations for this polymer in chloroform were obtained; the values of hydrodynamic diameter and the Kuhn segment length as well as the value of intrinsic anisotropy of polarizability of the monomer unit were defined. 相似文献
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Controllable Electronic Structures and Photoinduced Processes of Bay‐Linked Perylenediimide Dimers and a Ferrocene‐Linked Triad 下载免费PDF全文
Haruki Horinouchi Dr. Hayato Sakai Prof. Yasuyuki Araki Prof. Tomo Sakanoue Prof. Taishi Takenobu Prof. Takehiko Wada Prof. Nikolai V. Tkachenko Prof. Taku Hasobe 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(28):9631-9641
A series of perylene‐3,4,9,10‐bis(dicarboximide) (PDI) dimers linked through the bay regions was systematically synthesized to examine the electronic structures and photophysical properties in dependence on the distance and orientation between the two PDI units. The spectroscopic and electrochemical measurements suggested that the coupling value of a directly linked PDI dimer (PDI)2 is much larger than those of para‐ and meta‐phenylene‐bridged PDI dimers p‐(PDI)2 and m‐(PDI)2. The width of Davydov splitting was quantitatively evaluated to compare the coupling values between the two PDI units in these dimers by absorption spectroscopy in frozen 2‐methyl‐THF. Excimer formation of PDI dimers induced the strong fluorescence quenching and large red‐shifts. Femtosecond transient absorption revealed a broad absorption derived from an excimer in the range from about 600 nm to the near‐IR region. The rate constants of formation and decay of the excimer are strongly dependent on the coupling values. Time‐resolved measurements on ferrocene‐linked p‐(PDI)2 revealed a competition between the photoinduced processes of electron transfer and excimer formation in PhCN, which is in sharp contrast with the sole electron‐transfer process in toluene. 相似文献
80.
Jordanka Petrova Nikolai G. Vassilev Marko Kirilov 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4):457-463
Abstract The reaction of the lithium derivative of diethyl ester of phenylmethanephosphonic acid (1-Li) with alkanones, cycloalkanones, alkylaryl and diarylketones 2s-b is studied at -70°C in THF. The corresponding adducts-diethyl esters of l-phenyl-2,2-dialkyl(phenyl)-2-hydroxyethanephosphonic acids 3s-h are isolated, their yields being usually higher at short reaction time. The olefination of 3-Li as well as of 3 (both by thermolysis or in acidic media) proceeds in low degree, while in the case of 3-Na the yields of alkenes 4 are good. The relative configurations of 3b. 31 and 3g are determined by IR and NMR-spectra, as well as by their stereospecific olefination. “Threo”-stereoselectivity of the addition stage of the reaction of 1-Li with 2b, 21 and 2g is observed, the “threo”/“erythro” ratio remaining independent on the reaction time. 相似文献