全文获取类型
收费全文 | 754篇 |
免费 | 40篇 |
国内免费 | 2篇 |
专业分类
化学 | 554篇 |
晶体学 | 1篇 |
力学 | 23篇 |
数学 | 80篇 |
物理学 | 138篇 |
出版年
2023年 | 9篇 |
2022年 | 9篇 |
2021年 | 11篇 |
2020年 | 20篇 |
2019年 | 13篇 |
2018年 | 23篇 |
2017年 | 5篇 |
2016年 | 38篇 |
2015年 | 22篇 |
2014年 | 28篇 |
2013年 | 35篇 |
2012年 | 60篇 |
2011年 | 81篇 |
2010年 | 41篇 |
2009年 | 48篇 |
2008年 | 64篇 |
2007年 | 70篇 |
2006年 | 57篇 |
2005年 | 54篇 |
2004年 | 24篇 |
2003年 | 27篇 |
2002年 | 24篇 |
2001年 | 6篇 |
2000年 | 5篇 |
1999年 | 4篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有796条查询结果,搜索用时 15 毫秒
791.
792.
Fatima Tamtam Fabien Mercier Joëlle Eurin Marc Chevreuil Barbara Le Bot 《Analytical and bioanalytical chemistry》2009,393(6-7):1709-1718
An ultra performance liquid chromatography electrospray tandem mass spectrometry (UPLC/MS/MS) method was developed and validated for the determination of 17 antibiotics in natural waters in one single extraction and chromatographic procedure. Gradient separation conditions were optimised for 17 compounds belonging to five different antibiotic groups: quinolones (oxolinic acid, nalidixic acid, pipemidic acid, flumequine), fluoroquinolones (enoxacin, ciprofloxacin, norfloxacin, ofloxacin, enrofloxacin, sarafloxacin, danofloxacin, difloxacin, lomefloxacin), sulphonamides (sulphamethoxazole, sulphamethazine), nitro-imidazole (ornidazole) and diaminopyrimidine (trimethoprim). The separation of all compounds, obtained using a 1.7 μm particle size column (100 mm?×?2.1 mm), was achieved within 10 min time. Water samples were adjusted to pH 7 and extracted using Oasis hydrophilic–lipophilic balance (HLB) solid phase extraction cartridges. After elution with methanol and concentration, extracts were injected in a C18 column (Acquity UPLC BEH C18) and detected by tandem mass spectrometry. Average recovery from 100 ng L?1 fortified samples was higher than 70% for most of the compounds, with relative standard deviations below 20%. Performances of the method (recoveries, detection limit, quantification limit and relative standard deviation) and matrix effects were studied, and results obtained showed that method was suitable for routine analysis of antibiotics in surface water. Samples analysis from Seine River (France) confirmed the interest of antibiotic contamination evaluation in that area. Fig. a
UPLC/MS/MS extracted ion chromatograms of a standard solution containing 17 analytes 相似文献
793.
794.
Werner Jaeger Mathias Hahn Antje Lieske Arvid Zimmermann Fabien Brand 《Macromolecular Symposia》1996,111(1):95-106
This paper summarizes investigations on the radical polymerization of cationic vinyl monomers with respect to the peculiarities of the reaction in aqueous solution, the synthesis of model polymers and polyelectrolytes with regular structure as well as to a new process of stabilized precipitation polymerization. The rate of polymerization depends on the ionic strength of the solution. Random copolymers of diallyldimethylammonium chloride and acrylamide with variable charge density but equal molecular weight were synthesized by a feeding technique. Block copolymers consisting of charged and uncharged monomelic units with different hydrophilicity are available using macroazoinitiators. The novel polymers are powerful stabilizers in the precipitation polymerization of water soluble cationic vinyl monomers in aqueous salt solution leading to a dispersion of fine polymer particles. Polyampholytes with alternating positively and negatively charged monomelic units in the backbone were obtained by cyclocopolymerization of diallylanmine compounds and derivatives of maleic acid. 相似文献
795.
796.
Irén Simkó Christoph Schran Fabien Brieuc Csaba Fábri Oskar Asvany Stephan Schlemmer Dominik Marx Attila G. Császár 《Angewandte Chemie (International ed. in English)》2023,62(41):e202306744
Quantum mechanics dictates that nuclei must undergo some delocalization. In this work, emergence of quantum nuclear delocalization and its rovibrational fingerprints are discussed for the case of the van der Waals complex . The equilibrium structure of is planar and T-shaped, one He atom solvating the quasi-linear He−H+−He core. The dynamical structure of , in all of its bound states, is fundamentally different. As revealed by spatial distribution functions and nuclear densities, during the vibrations of the molecule the solvating He is not restricted to be in the plane defined by the instantaneously bent chomophore, but freely orbits the central proton, forming a three-dimensional torus around the chromophore. This quantum delocalization is observed for all vibrational states, the type of vibrational excitation being reflected in the topology of the nodal surfaces in the nuclear densities, showing, for example, that intramolecular bending involves excitation along the circumference of the torus. 相似文献