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41.
42.
Pierre-Yves Roger Fabien Blondeau David Bensa Thierry Constantieux Jean Rodriguez 《Molecular diversity》2009,13(4):469-473
A new one-pot domino reaction for a general entry to functionalised bridged bicyclo[n.2.1] ring systems from α ,α’-diactivated cyclic ketones and trans-1,4-dihalides is described. The sequence combines a base promoted C–O cycloalkylation reaction leading to fused polycyclic
enol ethers and their in situ palladium-catalysed isomerisation. 相似文献
43.
When certain trivalent rare-earth ions (Ln's) are co-doped in CaGa2S4:Mn2+ as sensitizers, the Mn red emission of the compound is strikingly enhanced. In this work, efficiency of each lanthanide is studied. The best efficiencies are achieved with La3+-, Pr3+-, and Tb3+- co-doped compounds, for each of which the effects of concentrations of the co-doped ions on the Mn2+ emission are investigated. The energy-transfer mechanisms and the location of electronic energy levels of both the trivalent and the divalent lanthanides in the energy band gap of the host material are discussed. Depending on Ln's, charge transfer or cross-relaxation should be taken into account. 相似文献
44.
[reaction: see text] The readily available N-(O-ethyl thiocarbonylsulfanyl)amides are powerful amidyl radical precursors that undergo 5-exo cyclization to give pyrrolidinone derivatives via a radical-chain reaction initiated by a small amount of lauroyl peroxide. 相似文献
45.
Impurity profiles of 3,4-methylenedioxymethylamphetamine (MDMA) tablets seized in France have been examined. The samples were extracted with methylene chloride under basic conditions and then analyzed by capillary gas chromatography. Almost 30 compounds were identified as precursors, intermediates and by-products. Palmitic and stearic acid were also found as tableting materials. The comparison of the different profiles obtained by the reported procedure provided very useful information about the synthetic processes used by clandestine laboratories and enabled a classification into several groups of profiles. According to these results, the reductive amination route appears to be the most common synthetic pathway in Western Europe. Furthermore, 3,4-methylenedioxyphenyl-2-propanone seems to be the most used precursor in clandestine laboratories. 相似文献
46.
We predict the existence of a new pulsed-laser operation regime, when the phases and polarizations of the two coupled cold-cavity eigenstates of a monomode solid-state laser are taken into account in the derivation of the Maxwell-Bloch equations. This monomode pulsed regime is experimentally observed, without any normal mode locking or Q switching occurring inside the cavity. We obtain close agreement between experiments and theory, even in the simple case of a Nd:YAG microchip laser, for which sech(2) pulses at nearly megahertz repetition rates are readily observed. 相似文献
47.
We study the nature of the ground state of the two-dimensional extended boson Hubbard model on a square lattice by quantum Monte Carlo methods. We demonstrate that strong but finite on-site interaction U along with a comparable nearest-neighbor repulsion V result in a thermodynamically stable supersolid ground state for densities larger than 1/2, in contrast to fillings less than 1/2 or for very large U, where the checkerboard supersolid is unstable towards phase separation. We discuss the relevance of our results to realizations of supersolids using cold bosonic atoms in optical lattices. 相似文献
48.
The second-order partial derivative of the Stokes signal with respect to frequency and position shows a maximum or minimum at the boundary between two different strained sections. This idea is used to locate the boundary of different stress regions. Knowing the boundaries, we then fit the Brillouin spectrum at the middle between them to get the strain value. This allows a location accuracy of between 5 and 10 cm, which is shorter than the pulse length of 20 cm used in the experiment. The lowest detectable Brillouin frequency difference between two strain sections is 1.2 MHz. 相似文献
49.
We reformulate a recent result of Arason and
Elman by giving a very simple presentation of the
powers of the fundamental ideal of the Witt ring of a field
of characteristic 2.
Sur les puissances de lidéal fondamental de lanneau de Witt
Nous reformulons un résultat récent de Arason et Elman en donnant une présentation très simple des puissances de lidéal fondamental de lanneau de Witt dun corps de caractéristique 2.相似文献
50.
We investigate correlations of the intensity fluctuations of two-dimensional arrays of nonidentical, locally coupled lasers, numerically and experimentally. We find evidence of a power-law dependence of spatial correlations as a function of laser pair distance (or coupling strength) near the phase-locking threshold. 相似文献