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131.
S. E. Jarman J. Pinchin J. M. Brushwood T. McCarthy M. Bray P. A. Beeley 《Journal of Radioanalytical and Nuclear Chemistry》2007,271(1):47-53
The potential for using a small, sealed tube, DT neutron generator for neutron activation analysis has been well documented
but not well demonstrated, except for 14 MeV activation analysis. This paper describes the design, construction and characterization
of a neutron irradiation facility incorporating a small sealed tube DT neutron generator producing 14 MeV neutrons with fluence
rates of 2·108 s−1 in 4π (steady state) and 1011 s−1 in 4π (pulsed). Monte Carlo modeling using MCNP4c and McBend9 has been used to optimize the design of this facility, including
the location of a thermal irradiation facility for conventional neutron activation analysis. A significant factor in designing
the facility has been the requirement to conform with Ionising Radiation Regulations and the design has been optimized to
keep potential radiation doses to less that 1 μSv/h at the external walls of the facility. Activation of gold foils has been
used for flux characterization and the experimental results agree well with the modeling. 相似文献
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Synthesis, spectroscopy, and theoretical calculations for a series of push-pull [14]-pyridoannulenes
Lauer MG Leslie JW Mynar A Stamper SA Martinez AD Bray AJ Negassi S McDonald K Ferraris E Muzny A McAvoy S Miller CP Walters KA Russell KC Wang E Nuez B Parish C 《The Journal of organic chemistry》2008,73(2):474-484
Three new isomeric dipyridoannulenes were synthesized and characterized. These molecules possess differing conjugation pathways between the substituent alkoxy donating groups and the pyridyl acceptor groups. Optical absorption and emission properties of the dipyridoannulenes and their corresponding acyclic precursors were measured and correlated to structural differences and used to evaluate conjugation effectiveness and charge-transfer pathways. Optical properties of protonated dipyridoannulenes were also measured and found to be somewhat insensitive to the degree of protonation. Density functional studies of these systems at the B3LYP/6-31G* level provided insight into their stabilities, polarities, and quinoidal character. An analysis of the HOMO and LUMO molecular orbitals provided further information regarding charge-transfer behavior. These systems are good metal binding candidates, as the pyridine moiety can act as both an electron-acceptor and a site for metal coordination. 相似文献
137.
In the Kourovka notebook, Deaconescu asks whether |AutG|(|G|)for all finite groups G, where denotes the Euler totient function,and whether G is cyclic whenever |AutG|. Both questions areanswered in the negative in this paper. Moreover, |AutG|/(|G|)can be made arbitrarily small. 2000 Mathematics Subject Classification20E36 (primary), 20F28 (secondary). 相似文献
138.
Bray DJ Liao LL Antonioli B Gloe K Lindoy LF McMurtrie JC Wei G Zhang XY 《Dalton transactions (Cambridge, England : 2003)》2005,(12):2082-2083
A trinuclear metallo-capsule has been assembled from a new tripodal pyridyl ligand and three silver(I) ions; the X-ray structure shows the presence of a Ag-Ag interaction in the solid state giving rise to a non-symmetric capsule arrangement while NMR evidence indicates that the structure in solution is symmetrical. 相似文献
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