Anisotropic diffusion in confined colloidal dispersions: the evanescent diffusivity

We employ an analogy to traditional dynamic light scattering to describe the inhomogeneous and anisotropic diffusion of colloid particles near a solid boundary measured via evanescent wave dynamic light scattering. Following this approach, we generate new expressions for the short-time self- and collective diffusivities of colloidal dispersions with arbitrary volume fraction. We use these expressions in combination with accelerated Stokesian dynamics simulations to calculate the diffusivities in the limit of large and small scattering wave numbers for evanescent penetration depths ranging from four particle radii to one-fifth of a particle radius and volume fractions from 10% to 40%. We show that at high volume fractions, and larger penetration depths, the boundaries have little effect on the dynamics of the suspension parallel to the wall since, to a first approximation, the boundary acts hydrodynamically much as another nearby particle. However, near and normal to the wall, the diffusivity shows a strong dependence on penetration depth for all volume fractions. This is due to the lubrication interactions between the particles and the boundary as the particle moves relative to the wall. These results are novel and comprehensive with respect to the range of penetration depth and volume fraction and provide a complete determination of the effect of hydrodynamic interactions on colloidal diffusion adjacent to a rigid boundary.     

Compressive Mass Analysis on Quadrupole Ion Trap Systems

Conventionally, quadrupole ion trap mass spectrometers eject ions of different mass-to-charge ratio (m/z) in a sequential fashion by performing a scan of the rf trapping voltage amplitude. Due to the inherent sparsity of most mass spectra, the detector measures no signal for much of the scan time. By exploiting this sparsity property, we propose a new compressive and multiplexed mass analysis approach—multi Resonant Frequency Excitation (mRFE) ejection. This new approach divides the mass spectrum into several mass subranges and detects all the subrange spectra in parallel for increased mass analysis speed. Mathematical estimation of standard mass spectrum is demonstrated while statistical classification on the parallel measurements remains viable because of the sparse nature of the mass spectra. This method can reduce mass analysis time by a factor of 3–6 and increase system duty cycle by 2×. The combination of reduced analysis time and accurate compound classification is demonstrated in a commercial quadrupole ion trap (QIT) system.

Benzofurans. Ketene intermediates in the perkin reaction

The intermediacy of ketenes in the intramolecular reaction of ketoacids with sodium acetate in acetic anhydride to form benzofurans is demonstrated. The Perkin reaction conditions are superior to the classical ketene generation method of triethylamine dehydrochlorination of the acid chloride.     

N-d backward scattering and virtual states of the trinucleon

The 180° nucleon-deutron elastic cross section exhibits a peak as a function of nucleon energy which has been interpreted as due to a virtual state of the trinucleon. This interpretation is examined within the context of the Amado model.