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991.
Photoabsorption and photofragmentation of isolated cationic silver cluster-tryptophan hybrid systems
Mitrić R Petersen J Kulesza A Bonacić-Koutecký V Tabarin T Compagnon I Antoine R Broyer M Dugourd P 《The Journal of chemical physics》2007,127(13):134301
We present a theoretical study of the size and structure selective absorption properties of cationic silver cluster-tryptophan Trp-Ag(n)(+) (n = 2-5,9) hybrid systems supported by photofragmentation experiments. Our time-dependent density functional theory calculations provide insight into the nature of excitations in interacting nanoparticle-biomolecule subunits and allow to determine characteristic spectral features as fingerprints of two different classes of structures: charge solvated and zwitterionic. Moreover, different types of charge transfer transitions have been identified. Charge transfer from pi system of tryptophan to silver cluster occurs for charge solvated structures while charge transfer from silver to the NH(3) (+) group takes place for zwitterionic structures. This has been confirmed by experimentally measured photofragmentation channels and molecular dynamics simulations. Our findings provide fundamental insight into the structure- and size-dependent mechanism responsible for the enhanced absorption and emission in nanoparticle-biomolecular hybrid systems. 相似文献
992.
Schoefberger W Smrecki V Vikić-Topić D Müller N 《Magnetic resonance in chemistry : MRC》2007,45(7):583-589
We present a new application of covariance nuclear magnetic resonance processing based on 1H--13C-HMBC experiments which provides an effective way for establishing indirect 1H--1H and 13C--13C nuclear spin connectivity at natural isotope abundance. The method, which identifies correlated spin networks in terms of covariance between one-dimensional traces from a single decoupled HMBC experiment, derives 13C--13C as well as 1H--1H spin connectivity maps from the two-dimensional frequency domain heteronuclear long-range correlation data matrix. The potential and limitations of this novel covariance NMR application are demonstrated on two compounds: eugenyl-beta-D-glucopyranoside and an emodin-derivative. 相似文献
993.
On Weakly Formulated Sylvester Equations and Applications 总被引:1,自引:0,他引:1
We use a “weakly formulated” Sylvester equation
to obtain new bounds for the rotation of spectral subspaces of a nonnegative selfadjoint operator in a Hilbert space. Our
bound extends the known results of Davis and Kahan. Another application is a bound for the square root of a positive selfadjoint
operator which extends the known rule: “The relative error in the square root is bounded by the one half of the relative error
in the radicand”. Both bounds are illustrated on differential operators which are defined via quadratic forms. 相似文献
994.
Let G(k, n) be the set of connected graphs without multiple edges or loops which have n vertices and the minimum degree of vertices is k. The Randi? index χ = χ(G) of a graph G is defined by χ(G)=∑(uv)(δuδv)-1/2, where δu is the degree of vertex u and the summation extends over all edges (uv) of G. Caporossi et al. [G. Caporossi, I. Gutman, P. Hansen, Variable neighborhood search for extremal graphs IV: Chemical trees with extremal connectivity index, Computers and Chemistry 23 (1999) 469–477] proposed the use of linear programming as one of the tools for finding the extremal graphs. In this paper we introduce a new approach based on quadratic programming for finding the extremal graphs in G(k, n) for this index. We found the extremal graphs or gave good bounds for this index when the number nk of vertices of degree k is between n − k and n. We also tried to find the graphs for which the Randi? index attained its minimum value with given k (k ? n/2) and n. We have solved this problem partially, that is, we have showed that the extremal graphs must have the number nk of vertices of degree k less or equal n − k and the number of vertices of degree n − 1 less or equal k. 相似文献
995.
In this paper we consider the difference equation $$x_{n + 1} = \frac{{a + bx_{n - k} - cx_{n - m} }}{{1 + g(x_{n - 1} )}},$$ wherea, b, c are nonegative real numbers,k, l, m are nonnegative integers andg(x) is a nonegative real function. The oscillatory and periodic character, the boundedness and the stability of positive solutions of the equation is investigated. The existence and nonexistence of two-period positive solutions are investigated in details. In the last section of the paper we consider a generalization of the equation. 相似文献
996.
Dražen Adamović 《Communications in Mathematical Physics》2007,270(1):141-161
We introduce the infinite-dimensional Lie superalgebra and construct a family of mappings from a certain category of –modules to the category of –modules at the critical level. Using this approach, we prove the irreducibility of a large family of –modules at the critical level parameterized by . As a consequence, we present a new proof of irreducibility of certain Wakimoto modules. We also give natural realizations
of irreducible quotients of relaxed Verma modules and calculate characters of these representations.
Partially supported by the MZOS grant 0037125 of the Republic of Croatia 相似文献
997.
D. Dobčnik M. Kolar J. Komljenović Nj. Radić 《Analytical and bioanalytical chemistry》1999,365(4):314-319
The preparation of an ion-selective electrode by chemical treatment of copper wire and its application for the measurements of copper (II) and iodide ions is described. The proposed reaction mechanism at the sensing surface, which explains the response of the electrode to Cu2+ and iodide ions, is discussed. The prepared electrode was suitable for direct potentiometric measurements of iodide and copper (II) in batch experiments down to concentrations of 1 × 10–5 mol L–1. A tubular electrode, prepared in the same way, may be used as a potentiometric sensor in a flow-injection analysis for Cu (II) and/or iodide determinations. 相似文献
998.
999.
MJ Singh DO Kataria N Madhavan P Sugathan JJ Das DK Awasthi AK Sinha R Shanker 《Pramana》1999,53(4):743-764
A projectile ion-recoil ion coincidence technique has been employed to study the multiple ionization and the charge transfer
processes in collisions of 60–120 MeV Si
q+ (q = 4−14) ions with neutral argon atoms. The relative contribution of different ionization channels, namely; direct ionization,
electron capture and electron loss leading to the production of slow moving multiply charged argon recoil ions have been investigated.
The data reported on the present collision system result from a direct measurement in the considered impact energy for the
first time. The total ionization cross-sections for the recoil ions are shown to scale as q
1.7/E
p
0.5
, where E
p is the energy in MeV of the projectile and q its charge state. The recoil fractions for the cases of total- and direct ionizations are found to decrease with increasing
recoil charge state j. The total ionization fractions of the recoils are seen to depend on q and to show the presence of a ‘shell-effect’ of the target. Further, the fractions are found to vary as 1/j
2 upto j = 8+. The average recoil charge state 〈j〉 increases slowly with q and with the number of lost or captured electrons from or into the projectile respectively. The projectile charge changing
cross-sections σ
qq′ are found to decrease with increasing q for loss ionization and to increase with q for direct-and capture ionization processes respectively. The physics behind various scaling rules that are found to follow
our data for different ionization processes is reviewed and discussed. 相似文献
1000.