全文获取类型
收费全文 | 3029篇 |
免费 | 117篇 |
国内免费 | 36篇 |
专业分类
化学 | 1695篇 |
晶体学 | 13篇 |
力学 | 56篇 |
数学 | 782篇 |
物理学 | 636篇 |
出版年
2023年 | 21篇 |
2022年 | 35篇 |
2021年 | 64篇 |
2020年 | 42篇 |
2019年 | 60篇 |
2018年 | 82篇 |
2017年 | 53篇 |
2016年 | 114篇 |
2015年 | 110篇 |
2014年 | 113篇 |
2013年 | 190篇 |
2012年 | 180篇 |
2011年 | 230篇 |
2010年 | 120篇 |
2009年 | 143篇 |
2008年 | 171篇 |
2007年 | 169篇 |
2006年 | 154篇 |
2005年 | 147篇 |
2004年 | 159篇 |
2003年 | 108篇 |
2002年 | 99篇 |
2001年 | 46篇 |
2000年 | 32篇 |
1999年 | 29篇 |
1998年 | 41篇 |
1997年 | 38篇 |
1996年 | 45篇 |
1995年 | 36篇 |
1994年 | 27篇 |
1993年 | 25篇 |
1992年 | 29篇 |
1991年 | 25篇 |
1990年 | 15篇 |
1989年 | 8篇 |
1988年 | 9篇 |
1986年 | 14篇 |
1985年 | 16篇 |
1984年 | 15篇 |
1983年 | 9篇 |
1982年 | 15篇 |
1981年 | 14篇 |
1980年 | 10篇 |
1979年 | 11篇 |
1978年 | 9篇 |
1977年 | 13篇 |
1976年 | 8篇 |
1975年 | 9篇 |
1971年 | 7篇 |
1967年 | 7篇 |
排序方式: 共有3182条查询结果,搜索用时 0 毫秒
181.
Electronic and atomic structures of different terminations of the (0 0 1) non-polar orientation of BaZrO3 surfaces have been studied using first-principles calculations. We found that surface energies at both possible surface terminations, BaO and ZrO2, were very close. The (0 0 1)-BaO and (0 0 1)-ZrO2 terminated surfaces have bandgap values smaller than that of a bulk BaZrO3 crystal. In addition, the relative surface stability has been analyzed as a function of chemical environment. 相似文献
182.
Le Guennic B Neugebauer J Reiher M Autschbach J 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(5):1677-1686
The experimental 13C NMR chemical shift of the central carbon atom in the octahedral [(Ph3PAu)6C]2+ cluster was investigated on the basis of relativistic density functional calculations. In order to arrive at independent model conclusions regarding the value of the chemical shift, a systematic study of the dependence of the cluster structure on the phosphine ligands, the chosen density functionals, and the basis set size was conducted. The best structures obtained were then used in the NMR calculations. Because of the cage-like cluster structure a pronounced deshielding of the central carbon nucleus could have been expected. However, upon comparison with the 13C NMR properties of the related complex [C{Au[P(C6H5)2(p-C6H4NMe2)]}6]2+, Schmidbaur et al. have assigned a signal at delta=135.2 ppm to the interstitial carbon atom. Our calculations confirm this value in the region of the aromatic carbon atoms of the triphenylphosphine ligands. The close-lying signals of the 108 phenyl carbon atoms can explain the difficulties of assigning them experimentally. 相似文献
183.
A. Yu. Boris 《Fluid Dynamics》1986,21(6):889-894
The motion is considered of a Stokes-like spherical particle in a turbulent nonisothermic gas flow whose viscosity depends
on the temperature. The field of the turbulent velocity is assumed to be homogeneous, isotropic, and steady. It is shown that
if there is a mean temperature gradient in the gas, and, consequently, a heat flow due to turbulent pulsations, then there
may be turbulent migration of particles in a direction collinear with the gradient of the mean temperature. The migration
is due to statistical correlation of turbulent pulsations of velocity and temperature, and is not connected with the phenomenon
of ordinary thermophoresis. Upon the introduction of a number of simplifying assumptions, the rate of migration is calculated
in dependence on the characteristics of the particle and the flow.
Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 53–58, November–December, 1986.
The author is grateful to V. S. Galkin, V. A. Zharov, M. N. Kogan, and V. A. Sabel'nikov for discussions of the study. 相似文献
184.
185.
Svetlana F. Malysheva Natal’ya A. Belogorlova Nina K. Gusarova Alexander V. Artem’ev Alexander I. Albanov Boris A. Trofimov 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8):1688-1693
Abstract Red phosphorus reacts with allylbenzene in the superbase system KOH-DMSO (130°C, 3 h, Ar) to give a mixture of bis(1-methyl-2-phenylethyl)phosphane (1), bis(1-methyl-2-phenylethyl)phosphane oxide (2), and 1-methyl-2-phenylethylphosphinic acid (3). Secondary phosphane oxide 2 and phosphinic acid 3 have been isolated from this mixture in 35% and 32% yield, respectively. Microwave activation of the reaction (200 W, 30 min) affords secondary phosphane 1 as the main product in 48% yield. GRAPHICAL ABSTRACT 相似文献
186.
In two dimensional electron systems with Coulomb or dipolar interactions, a direct transition, whether first or second order, from a liquid to a crystalline state is forbidden. As a result, between these phases there must be other (micro-emulsion) phases which can be viewed as a meso-scale mixture of the liquid and crystalline phases. We investigate the transport properties of these new electronic phases and present arguments that they are responsible for the various transport anomalies that have been seen in experiments on the strongly correlated 2DEG in high mobility semiconductor devices with low electron densities. 相似文献
187.
Yoav Linzon Boris A. Malomed Michael Zaezjev Roberto Morandotti Maite Volatier Vincent Aimez Richard Ares Shimshon Bar-Ad 《Central European Journal of Physics》2008,6(3):555-562
We study nonlinear interactions between discrete optical solitons that propagate in different regimes of diffraction, and
the nonlinear scattering of dispersive waves by local optical potentials. It is well known in optics that when linear coherent
waves meet, they interfere without interactions. Linear waves also scatter through local optical structures not exchanging
any power with the guided modes of these structures. As a focusing Kerr nonlinearity is present, such linearly-inhibited phenomena
can exist. Our studies are performed in silica and AlGaAs nonlinear waveguides, excited by ultra-short pulses in the near
infrared.
Presented at 9-th International Workshop on Nonlinear Optics Applications, NOA 2007, May 17–20, 2007, Świnoujście, Poland 相似文献
188.
Jelena Vasiljević Brigita Tomšič Ivan Jerman Boris Orel Gregor Jakša Barbara Simončič 《Cellulose (London, England)》2014,21(4):2611-2623
This research aimed to prepare cotton fibres with novel multifunctional water- and oil-repellent, antibacterial, and flame-retardant properties. A three-component equimolar sol mixture, which included 1H,1H,2H,2H-perfluorooctyltriethoxysilane, 3-(trimethoxysilyl)-propyldimethyloctadecyl ammonium chloride, and P,P-diphenyl-N-(3-(trimethoxysilyl)propyl) phosphinic amide, was applied to the cotton fabric using the sol–gel process. The presence of the coating on the cotton fibres was confirmed by Fourier transform-infrared spectroscopy and X-ray photoelectron spectroscopy. The functional properties of the coated cotton fabric were determined from liquid contact angle measurements and antibacterial activity, burning behaviour, and thermo-oxidative stability studies. The results demonstrate that a unique, compatible, and uniform organic-inorganic hybrid polymer network was formed on the fabric surface, which preserved its simultaneous hydrophobic (water contact angle of 135 ± 2°), oleophobic (n-hexadecane contact angle of 117 ± 1°), and bactericidal (bacterial reduction of 100 %) properties and incorporated the enhanced thermo-oxidative stability of the modified cellulose fibres. 相似文献
189.
Marcel Turkensteen Diptesh Ghosh Boris Goldengorin Gerard Sierksma 《Discrete Optimization》2006,3(1):63
Although Branch-and-Bound (BnB) methods are among the most widely used techniques for solving hard problems, it is still a challenge to make these methods smarter. In this paper, we investigate iterative patching, a technique in which a fixed patching procedure is applied at each node of the BnB search tree for the Asymmetric Traveling Salesman Problem. Computational experiments show that iterative patching results in general in search trees that are smaller than the classical BnB trees, and that solution times are lower for usual random and sparse instances. Furthermore, it turns out that, on average, iterative patching with the Contract-or-Patch procedure of Glover, Gutin, Yeo and Zverovich (2001) and the Karp–Steele procedure are the fastest, and that ‘iterative’ Modified Karp–Steele patching generates the smallest search trees. 相似文献
190.
Boris A. Trofimov Elena Yu. Schmidt Igor A. Ushakov Elena Yu. Senotrusova Grigorii G. Aleksandrov 《Tetrahedron letters》2009,50(26):3314-3775
A new three-component reaction between alkyl aryl(hetaryl)ketoximes, acetylene, and aliphatic ketones in the superbasic systems KOH/DMSO and LiOH/CsF/DMSO (70-90 °C, initial acetylene pressure 13-15 atm, 5-60 min) affords novel 4-methylene-3-oxa-1-azabicyclo[3.1.0]hexanes in yields of up to 75%. Using KOH/DMSO, the side products of the reaction are O-vinylketoximes and 2-aryl(hetaryl)pyrroles, while with LiOH/CsF/DMSO, the reaction proves to be selective, only minor amounts of the corresponding alkyl aryl(hetaryl) ketones being detectable. 相似文献