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201.
James K. Boon 《Waves in Random and Complex Media》2004,14(3):199-216
Traditionally, in moment-method analyses of electromagnetic scattering, the elements of the impedance matrix are calculated as convolutions of the basis elements with the appropriate dyadic Green's function. However, for scattering in the half-space, the vertical and azimuthal copolar terms of the Green's function require evaluation of Sommerfeld integrals which are computationally burdensome. In this paper, it is shown that, in populating the impedance matrix for the half-space problem, evaluation of Sommerfeld integrals is, in fact, not necessary. For monochromatic excitation, the plane-wave expansion of the scattered field constitutes a Fourier transform, in the horizontal plane, of a vector spectral function. This vector function results from the convolution, in the vertical dimension, of the respective angular spectra of the Green's function and the equivalent current. On application of the moment method, through the Weyl identity, the impedance-matrix elements corresponding to the singular terms of the Green's function are convolutions in the horizontal plane of spherical potentials, and Fourier transforms of scalar spectral functions. These scalar functions are derived from the basis elements and, with a judicious choice of basis, they are well behaved and of compact support, and consequently their Fourier transforms can be computed as FFTs. 相似文献
202.
203.
J. Boon G. Challa D. W. Van Krevelen 《Journal of Polymer Science.Polymer Physics》1968,6(10):1791-1801
The spherulitic growth rate of isotactic polystyrene has been measured in a wide range of temperature by means of a polarizing microscope provided with a hot stage. It was possible to fit the experimental data to theory by choosing a value of 75 for the constant C2 of the WLF equation. The growth rate parameters were compared with those of polyethylene and polychlorotrifluoroethylene. The slowness of crystallization of isotactic polystyrene is mainly a consequence of the lower mobility of the molecules caused by the bulky phenyl groups. 相似文献
204.
Thomas S.A. Heugebaert Simon De Corte Tom Sabbe Tom Hennebel Willy Verstraete Nico Boon Christian V. Stevens 《Tetrahedron letters》2012,53(11):1410-1412
The use of two nanoparticulate palladium based catalysts in the Suzuki reaction is described. One monometallic (Pd) and one bimetallic (Pd/Au) catalyst were prepared by the environmentally benign method of bioreductive precipitation by Shewanella oneidensis. Both catalysts successfully mediated the Suzuki coupling, however, the Au doped catalyst was shown to deliver more reproducible results with a broader reaction scope. 相似文献
205.
206.
207.
DRAMATIC IMPROVEMENTS IN VIRAL INACTIVATION WITH BROMINATED PSORALENS, NAPHTHALENES AND ANTHRACENES 总被引:1,自引:0,他引:1
Saroj Rai Chandrika Kasturi Jennifer Grayzar Matthew S. Platz Raymond P. Goodrich Nagender R. Yerram Victoria Wong Boon H. Tay-Goodrich 《Photochemistry and photobiology》1993,58(1):59-65
Amino or polyamino derivatives of naphthalene (N-H), anthracene (A-H) and 8-alkoxypsoralen (PSR-H) were prepared along with their monobrominatcd analogs (N-Br, A-Br and PSR-Br). The ammonium salts of these compounds are all water soluble and bind strongly to calf thymus DNA and to λ phage, a double-helical DNA, protein-coated virus. Binding of the sensitizer to DNA occurs, presumably by a mixture of hydrophobic, intercalative and electrostatic interactions. Relative binding constants to calf thymus DNA and to λ phage were measured by the cthidium bromide fluorescence quenching assay. In general the brominated analogs bind more tightly to calf thymus DNA and to the virus than to the nonhalogenated analogs. It is demonstrated that the brominated aromatics are much more effective at inactivating λ phage upon photoactivation (λ 310 or 350 nm) than are their nonbrominated analogs. At identical sensitizer concentrations (by weight) and light flux N-Br, A-Br, and PSR-Br produce 5–6 more logs of viral inactivation than their nonbrominated counterparts (N-H, A-H and PSR-H, respectively). The bromine effect may originate from light-induced electron transfer and subsequent cleavage of the C-Br bond of the sensitizer radical anion bonds to form aryl radicals. Singlet oxygen cannot be responsible for the viral inactivation because the brominated sensitizers are equally effective in the presence and absence of oxygen. Dithiothreitol does not protect λ phage from light-induced inactivation by the brominated sensitizer thereby demonstrating that the photogenerated reactive intermediates responsible for the effect are complcxed to the virus and are not generated free in solution. 相似文献
208.
Structure/activity study of tris(2-aminoethyl)amine-derived translocases for phosphatidylcholine 总被引:1,自引:0,他引:1
Boon JM Lambert TN Smith BD Beatty AM Ugrinova V Brown SN 《The Journal of organic chemistry》2002,67(7):2168-2174
Sulfonamide and amide derivatives of tris(aminoethyl)amine (TREN) are known to facilitate phospholipid translocation across vesicle and erythrocyte membranes; that is, they act as synthetic translocases. In this report, a number of new TREN-based translocases are evaluated for their abilities to bind phosphatidylcholine and translocate a fluorescent phosphatidylcholine probe. Association constants were determined from (1)H NMR titration experiments, and translocation half-lives were determined via 7-nitrobenz-2-oxa-1,3-diazol-4-yl (NBD)/dithionite quenching assays. A rough correlation exists between translocase/phosphatidylcholine association constants and translocation half-lives. The tris-sulfonamide translocases are superior to the tris-amide versions because they associate more strongly with the phospholipid headgroup. The stronger association is due to the increased acidity of the sulfonamide NHs as well as a molecular geometry (as shown by X-ray crystallography) that is able to form tridentate complexes with one of the phosphate oxygens. Two fluorescent translocase analogues were synthesized and used to characterize membrane partitioning properties. The results indicate that the facilitated translocation of phospholipids by TREN-derived translocases is due to the formation of hydrogen-bonded complexes with the phospholipid headgroups. In the case of zwitterionic phosphatidylcholine, it is the neutral form of the translocases that rapidly associates with the phosphate portion of the phosphocholine headgroup. Complexation masks the headgroup polarity and promotes diffusion of the phospholipid-translocase complex across the lipophilic interior of the membrane. 相似文献
209.
Henry S. Ashbaugh Kathleen Boon Robert K. Prud'homme 《Colloid and polymer science》2002,280(9):783-788
The gelation of mixed cationic/anionic surfactant vesicles of sodium dodecyl sulfate/didodecyldimethylammonium bromide and sodium dodecylbenzenesulfonate/cetyltrimethylammonium tosylate by hydrophobically modified sodium polyacrylate is studied rheologically. When the vesicles are cationically charged, mixtures with this anionic polyelectrolyte form precipitates. When the vesicles are anionically charged, however, these mixtures display a progression from a Maxwell fluid to a critical gel to a solidlike gel with increasing vesicle and/or polyelectrolyte concentration. Consideration of the viscous behavior with increasing vesicle and polymer volume fraction indicates that the gel network is formed by the bridging of the hydrophobically modified polymer between vesicles. The similarity between the gelation results for the two anionic systems suggests the results can be generalized to other similarly charged mixtures. 相似文献
210.
The conventional type of magnetic well is formed by superposition of two types of magnetic field, axial bumpy field and radial
multipole field. It is used to contain plasma that consists of neutrals, ions and electrons. These particles are in constant
motion in the well and energetic electrons create plasma by violent collisions with neutrals and ions. The confined electrons
are constantly heated by ECR technique in the presence of magnetic field. In this paper it has been shown theoretically that
how the electron motion is influenced in terms of heating, containment and azimuthal uniformity of plasma, by the axial rotation
of the multipole magnetic field [1,2]. Afterwards, the feasibility of achieving a rotating magnetic multipole field is discussed
to some extent. And it is seen that it is not beyond the capability of the scientific community in the present scenario of
the advanced technology. Presently, it can be achieved for lesser field and slightly larger size of the multipole electromagnet
and can be used for improvement of the ECR ion source (ECRIS). 相似文献